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2 votes
2 answers
4k views

How does water sublimate at normal atmospheric pressures/conditions (i.e., without a phase boundary between solid and gas)?

I remember my high school chemistry teacher stating that water could sublime under normal atmospheric conditions that would exist in e.g., Lancaster County, PA, where Amish would hang clothes to dry ...
bvargo's user avatar
  • 121
3 votes
0 answers
159 views

What is the difference between sublimation and instantaneous fusion+vaporisation?

Sublimation is defined by the IUPAC as The direct transition of a solid to a vapour without passing through a liquid phase. A sublimation equilibrium can occur in two sets of conditions: at a ...
Thomas Jungers's user avatar
2 votes
2 answers
870 views

Internal energy for Phase Transitions

Can we justify that "For sublimation of a solid at 1 atm $\Delta U>0$ at low temperature and $\Delta U<0$ at high temperature?" I read several answers and came to know that $U=f(T)$ ...
user69608's user avatar
  • 168
1 vote
0 answers
323 views

Why does CO2 only exist in gaseous and solid state under STP/SATP?

Why does carbon dioxide only exist in gas and solid state under STP/SATP conditions? $\ce{CO2}$ pressurized to $\pu{5.1 atm}$ can exist in all 3 states: solid, gas, and liquid. However, why couldn't ...
George Jones's user avatar
6 votes
3 answers
5k views

Does naphthalene in moth balls really sublimate or does it evaporate?

The triple point of naphthalene is $\pu{-56 °C}, \pu{1.05 kPa}$ (which is much less than $\pu{1 atm}$). So how can a naphthalene ball sublimate at $\pu{1 atm}$, when considering that its melting point ...
Vaibhav Jain's user avatar
0 votes
1 answer
161 views

Vacuum at different altitude

I have tried to find this searching the internet and I am not sure if I understand it. I want to turn water from solid to gas without going into the liquid phase - Sublimation. The altitude above sea ...
Rohan000's user avatar
1 vote
0 answers
51 views

Equilibrium saturation/depostion rate calculation

I found the Knudsen/Langmuir equation for calculating the sublimation rate of a solid. If I have a closed system, once the vapor reaches the saturation pressure, the solid will continue sublimating ...
ericksonla's user avatar
  • 1,690
1 vote
3 answers
26k views

Sublimation of Iodine

Why does iodine sublime? I have researched it myself and I have got the same answer; it sublimes because it directly converts from solid to gas. But why don't bromine or chlorine also sublime?
user247833's user avatar
5 votes
1 answer
3k views

Which elements have no liquid form at atmospheric pressure?

Carbon has no liquid form at atmospheric pressure. Is this unique amongst naturally occurring elements? The more interesting and vague question is, is this property somehow important or related to ...
marshall's user avatar
  • 739