Questions tagged [solutions]

This tag should be applied to questions dealing with solutions of any kind. A solution is a liquid or solid phase containing more than one substance where, for convenience, one (or more) substance(s) called the solvent is treated differently from the other substances, which are called solutes. If water is the solvent, then the more appropriate 'aqueous-solution' tag should (also) be specified.

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32 views

Discussion about Warren-Cowely Parameter

The Warren-Cowely Parameter (WCP) for short range solution order is defined as: $$\mathrm{WCP}_{ij} = 1 - \frac{Z_{ij}}{x_j \cdot Z_i}$$ where $Z_{ij}$ is the partial Coordination Number (CN) of ...
3
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1answer
1k views

What does (sol) in a chemical equation mean?

I'm reading Shrivers Inorganic Chemistry book and some of the equations have a (sol) state on them. I'm sure the book has already defined this but I cannot find where. Examples: \begin{align} \ce{[...
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42 views

Vanadium Ions from Vanadium Pentoxide (V2O5)

I'm working on a project that needs vanadium (+5) ions. I have 18m sulfuric acid (though I've been diluting it to around 2m) and V2O5. I know that the +5 ion is soluble in sulfuric acid, but how do I ...
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1answer
38 views

If I dissolve 0.1M of CaCl2.2H2O in water, do I get a 0.1M CaCl2 solution? [closed]

If I dissolve $\pu{0.1 M}$ of $\ce{CaCl2.2H2O}$ in water, do I get a $\pu{0.1 M}$ $\ce{CaCl2}$ solution?
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3answers
48 views

Molarity of two solutions

Question: Two solutions of ethanol marked as X and Y are labeled as 25% ethanol by mass and 25% ethanol by volume respectively. If the density of solution Y is 0.789 g/mL and that of solution X is 0....
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2answers
74 views

How much of Sodium dichloro-s-triazinetrione dihydrate should I use to replace bleach? [closed]

I am trying to determine how much sodium dichloro-s-triazinetrione dihydrate powder I should add to water to create a dilution that can be injected into my water supply to react with the Hydrogen ...
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1answer
20 views

Difference between a species and a phase in a solution? [closed]

Overview: As of my knowledge from metallurgical thermodynamics a phase is a thermodynamically stable and homogeneous entity made up of different species of a given concentration. e.g = 'Austenite' ...
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26 views

Why does changing the salt of the salt bridge effect the voltage produced in a galvanic cell?

My experiments results showed that the voltage decreases down $\pu{Group 1}$: $\ce{Cl-}$ salts in the salt bridge. All other variables were kept constant. $\ce{Zn}$ and $\ce{Cu}$ rods were used. ...
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2answers
100 views

Will NaF + CaCO3 precipitate much CaF2?

If I mix sodium fluoride, calcium carbonate powder, and water, under what conditions (if any) would there be an equilibrium? I.e. assume we start out with fully dissociated $\ce{Na+(aq) + F-(aq)}$, ...
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20 views

Can Methylene Blue Detect Spoilage in Food?

Initially, there is already a product which is a sensor based on Methylene Blue, which can detect changes in oxygen levels in a packaging. However, as our thesis project, we decided to take on this ...
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12 views

Is Raoults Law valid if the solute is non volatile but have less vapour pressure than pure solvent?

We know that on adding a non-volatile solute to a pure solvent its vapour pressure increases because of the reluctance of solute to evaporate(i.e. strong intermolecular forces of attraction) Instead ...
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1answer
37 views

Is the solution isotonic, hypertonic, or hypotonic?

The problem is shown below. I don't understand how can the tonicity of a solution be determined if the solution has multiple solutes dissolved in it. Do I take the total sum of the mass of solutes ...
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2answers
92 views

Can you dissolve iodine without potassium iodide? [closed]

I don't have a sufficient amount of potassium iodide, so I wanted to know if there is other way which I can use to dissolve iodine without using potassium iodide.
2
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1answer
59 views

Effect of impurities on Enthalpy of vapourization

How does the Enthalpy of vapourization change when impurities are added? I know that the boiling point of a substance increases on addition of impurities, but how does the Enthalpy of vapourization ...
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36 views

Derivation of freezing-point depression equation

Can anyone provide me the real derivation of depression in freezing point? In almost all of the books and online articles that I have read, it says $\Delta T_\mathrm{f}$ is directly proportional to ...
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1answer
48 views

Can ascorbic acid be neutralized and keep it's elastic properties in dough?

Ascorbic acid (C6H8O6) is commonly used in dough to give it strength and elasticity. However, I need this dough to be alkaline, or at the very least neutral. I've used sodium carbonate (Na2CO3) before ...
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1answer
21 views

How is Henry's constant affected by change in temperature

According to me Henry's constant $K_h$ should be directly proportional to the effect of temperature. It is because $K_h$ is inversely proportional to solubility and as we increase temperature ...
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2answers
44 views

How would I separate a solution of sodium iodide and water in order to obtain the sodium [closed]

I am an amateur in this field of science and I am trying to separate a solution of Sodium Iodide and water. How would I separate the solution so I can obtain sodium?
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25 views

Ion exchange resins

My problem is explained quite easily: I have no experience with ion exchange resins but I would like to test something out in order to exchange my sulfate ions in solution for nitrate (can also be ...
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1answer
55 views

Is there any non-toxic and non-solvable-in-air liquid? [closed]

I want to heat the air with non-aqueous, non-toxic and non-solvable-in-air liquid (with very low relative pressure in air). Is there any such liquid exists? It would be great if the boiling point of ...
2
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1answer
49 views

Methods to increase the speed of dissolving potassium sulfate in water apart from heating, grinding or shaking

I bought potassium sulfate to be used as a fertilizer. The fertilizer comes in the form of small pebbles 1-2mm in diameter. Wikipedia states that the solubility is around 111g/liter at 20°C. I ...
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0answers
28 views

Is it possible to remove sugar from a sweetened drink but without boiling it? [duplicate]

Is it possible to remove sugar from a sweetened drink without boiling it? This might not be a good question but I'm wondering if you could separate sugar from a sweetened drink and replace the sugar ...
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1answer
33 views

What formula allows adjusting balance of (Ethyl Alcohol / Water / Caffeine powder) to know concentration for the Caffeine solution?

I am experimenting with different levels of concentrated caffeine solution. The solution has a small percentage of ethyl alcohol, in the $\ce{H2O}$. Problems encountered too much ethyl alcohol ...
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1answer
59 views

If volatility depends on intermolecular forces, then why in Raoult's law, two substances have different volatility?

I have a doubt, Ideal solutions are solutions where intermolecular forces between solute-solute and solvent-solvent are nearly equal to solute-solvent. Since intermolecular forces between A-A = B-B, ...
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3answers
119 views

Dynamic equilibrium in unsaturated solutions

One standard definition of equilibrium in beginner chemistry is that for a reversible reaction, (dynamic) equilibrium has been achieved when the rate of the forward and backward reactions are equal. ...
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1answer
95 views

Is it possible to prepare a 0.1 N solution of HCl and methanol? [closed]

In my lab guide I read: "Use a $\pu{0.1 N}$ solution of methanol-chloridic acid $(9:1)$ for the anthocyanin extraction", so I tried to calculate the volume of $\ce{CH3OH}$ and $\ce{HCl}$ to prepare it,...
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1answer
56 views

Can compounds dissolved in different miscible solvents react?

For example, can crystal iodine dissolved in ethanol react with sodium thiosulfate dissolved in water when mixed together?
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1answer
26 views

Can there be a compound which stops the pesticide from entering into the fruit or vegetable? [closed]

Can there be a compound which stops the pesticide from entering into the fruit or vegetable? For example, a solution which is sprayed before pesticides and somehow blocks pesticides from entering into ...
2
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1answer
380 views

Kohlrausch Law and conductivity

Im writing up a lab report at the minute and part of it concerns ions in solution and how they affect conductivity. I've been doing lots of reading and I think ive got the grasp of most of it, but its ...
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2answers
125 views

Freezing Point Depression and Temperature Decrease

I don't have a problem understanding the chemical mechanisms underlying freezing point depression or colligative properties in general, but what I cannot seem to grasp is how if you add salt to ice ...
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0answers
18 views

How can I make a reference humidity environment with NaOH pellets? [duplicate]

I have NaOH pellets at my disposal. Some of the pellets are degraded, but most are not, and I can provide a new batch if needed. I would like to test several humidity sensors in an environment with a ...
2
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1answer
62 views

What is the interaction between dissolved ions of opposite valence in a solution at rest?

NaCl is dissolved in water. Ions sodium and chloride are sufficiently free from each other so that they may occupy different regions of the solution after an active transport process through a ...
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2answers
476 views

Phenolphthalein Indicator mixed with base that first turns pink and then clear

What occurs in the following situation: After adding 2 drops of Phenolphthalein Indicator (an indicator that turns bases pink and stays clear for acids,) into a unknown solution, the solution turns ...
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1answer
96 views

Finding original concentration w%/w%

A question from a grade 9 admission exam: When 1 kg of salt is added to a solution of salt and water, the solution becomes 33 1/3% salt by mass. When 1 kg of water is added to the new solution, the ...
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1answer
605 views

Why does concentration of solutions of alkali metals in liquid ammonia change the magnetic properties?

In "NCERT Chemistry for Class XI - Volume II", in chapter "s-block elements", under the topic "Chemical Properties of alkali metals", it is given: (vi) Solutions in liquid ammonia: The alkali ...
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1answer
73 views

Home made dispersion/solution with detectable >0.1μm particles [closed]

Sorry for the possibly wrong terminology. I'm not a chemist and I'm not a native English speaker. Please edit the question as needed. Thank you. Is it possible to buy or prepare a dispersion with the ...
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0answers
76 views

How to dissolve PLA/PCL/PMMA?

I have a research about electrospun membrane synthesis where I dissolve PLA pellets in chloroform:methanol (3:1) for 3 hours and also PCL pellets in chloroform:methanol (3:1) for 3 hours too. Another ...
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1answer
34 views

Separate less volatile component from distilling a mixture [closed]

Is it a strict rule that when we boil a mixture of two liquids, with one being less volatile than the other, the more volatile vapour has to form the greater portion of the total vapours? If it is so,...
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1answer
53 views

How does acetone help to make a liquid cleaner stronger? [closed]

Acetone, as a solvent, seems to behave somewhat different than other solvents. It seems to solve things other unpolar solvents do not. For example, I have two cleaner sprays from the same brand, and ...
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1answer
39 views

Boiling point elevation and liquid solutions

$\pu{1 L}$ of an aqueous solution of urea having density $\pu{1.06 g mL-1}$ is found to have elevation in boiling point $\Delta T_\mathrm{b} = \pu{0.5 °C}.$ If the temperature of this solution is ...
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1answer
53 views

Liquid solutions and vapour pressure

"The vapour pressure of water at 80° C is 355 torr. A 100 mL vessel contained water-saturated oxygen at 80° C, the total gas pressure being 760 torr. The contents of the vessel were pumped into a 50 ...
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1answer
80 views

Applying Raoult's Law in volatile solids–liquid solutions

My textbook explains applying Raoult's Law for the two cases: liquid–liquid solutions, in which the vapour pressure of the solution is due to both the components non-volatile solids–liquid solutions, ...
4
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2answers
109 views

Are hydroxides soluble in each other?

Let's say I have molten potassium hydroxide and then I add some Calcium hydroxide. I imagine, since there are hydroxide groups floating around, it would be energetically neutral for the calcium ions ...
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1answer
63 views

Change in boiling and freezing point

I recently encountered a question while solving previous year question papers for JEE. This is a JEE 2005 question. The question demands to complete this statement: Equimolar solutions in the ...
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1answer
451 views

How do I determine molality from mole fraction without knowing how much of the solution I have?

What is the value of $x$ if $x$ molal solution of a compound in benzene has a mole fraction of solute equal to 0.2? I tried calculating the moles of $x$ through the value given but there are two ...
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43 views

How to calculate the i-value of known NaCl solution, if it is isotonic with known solution of glucose?

How do I calculate the value of $i$ for 1.17% solution of $\ce{NaCl}$, if it is isotonic with 7.2% solution of glucose? I actually do not know where to start in this question. is it possible to ...
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2answers
234 views

Why doesn't the solute settle out of a solution, such as brine or sugar water? [closed]

If I have a solution of salt or sugar dissolved in water, the solute will never settle out or "fall to the bottom", no matter low long I wait. Why is that? Since salt and sugar (in their pure, solid ...
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1answer
40 views

Is adding the word “solution” necessary when listing the materials used in a synthesis?

I am editing a chemistry-related paper and the synthesis procedure described is as follows: Then, 10 mL of the intermediate were mixed with 10 mL of 1% (w/v) VCPL and 2 mL of 0.1% (w/v) KPS. I ...
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0answers
68 views

How to determine the solubility of a Metal Fluoride in liquid Gallium

How do I determine if a Metal Fluoride is soluble in liquid Gallium and under what conditions the Metal Fluoride will stay in solution in the liquid Gallium? I am involved in a project that is ...
2
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3answers
297 views

If Beer's Law appears to apply to a high concentration (>0.01M) of a solute, is it valid to use for concentration calculation?

Internet consensus seems to define "high concentration" for Beer's Law as >0.01M. If one has a solution at higher concentrations than that, but the absorbance vs. concentration is still linear, is it ...

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