Questions tagged [solutions]

This tag should be applied to questions dealing with solutions of any kind. A solution is a liquid or solid phase containing more than one substance where, for convenience, one (or more) substance(s) called the solvent is treated differently from the other substances, which are called solutes. If water is the solvent, then the more appropriate 'aqueous-solution' tag should (also) be specified.

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1answer
57 views

Creating a chemical solution with water and chlorine

I bought a swimming pool for my kids and also a measurement instrument for measuring the amount of chlorid in the pool in mg/l. The problem is now that you have to calibrate the instrument before ...
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25 views

How to make zinc acetate solution [closed]

Please, I got 1 kilogram Zinc Acetate Dihydrate. I tried to make a solution with 1 liter boil water in 1 teaspoon (5-6 gram) of that zinc acetate powder. As this powder has about 30% elemental zinc so ...
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27 views

Partial molar volume of binary mixture

A 2% (weight %) solution of a salt with Mr = 190.6 g mol-1 was prepared at 25 0C. The density of the prepared solution was 1.00926 g cm-3. The density of water at 25 0C is 0.99707 g cm-3, and the ...
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1answer
30 views

Deposition of saturated solution and affect of evaporated water

20g of water is evaporated from 200g of saturated solution of KNO3(aq) at 60°C by heating and the solution was cooled to 20°C. How many grams of KNO3 were deposited? The solubility of KNO3 in 100g of ...
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1answer
76 views

In what solvents does ionic association occur?

When a ionic compound like $\ce{NaCl}$ dissolves, it doesn't always full dissociate due to ionic pairing. This is measured by the van 't Hoff factor. Now, this is what I'm looking at for my chem ...
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2answers
22 views

Effect of water vaporation on saturated solution

At a high temperature, water is evaporated from the saturated solution by heating. What is the solution losing exactly by the fact that the water left the saturated solution? Does it affect its ...
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27 views

How does solutions of two liquids work?

I'll start by establishing my potentially flawed understanding of solutions: A solution is a completely homogenous mixture. That means that the two (or more) substances are evenly distributed ...
2
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0answers
26 views

Colligative properties: why does the size of solute not matter?

Colligative properties are defined as the "properties of solutions that depend on the ratio of the number of solute particles to the number of solvent molecules in a solution, and not on the ...
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2answers
360 views

Apparent contradiction in the type of deviation of an ethanol-water mixture

For a mixture of $\ce{EtOH}$ and $\ce{H2O}$: $\Delta H_{\text{mix}} < 0$ (exothermic) and $\Delta V_{\text{mix}} < 0$ (volume contraction). This means that the unlike interactions are stronger ...
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1answer
48 views

I need help finding several immiscible liquids [closed]

I am trying to fill a vial with as many immiscible liquids as possible so that they form many separate layers. I want to do this as a way to visualise how liquids with different refractive indexes ...
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1answer
26 views

opening valve separating two volatile solutions [closed]

Let there be two containers A and B containing two volatile solutions (ideal) of pure liquids P and Q respectively. The containers are connected by a tube such that only vapours can travel through ...
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What is it meant by “preparing solutions on a blister”?

I was recently looking into an aspirin hydrolysis preparation lab and noticed the following: (This preparation was taken from http://www.kii3.ntf.uni-lj.si/analchemvoc2/file.php/1/HTML/SPEKTRA/...
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45 views

Confusion on when to use mass of entire solution when performing q=mc∆T

I hope you are having a good day. I am studying for the AP Chemistry exam in May 2020. While studying, I encountered a doubt. In Problem 1 (the question on the top), the educator saw that the ...
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2answers
16 views

Why is water transferred from a beaker of pure water to a beaker of sugar solution when placed in the a closed container?

I know that there is something to do with the vapour pressure of pure water being higher than the vapour pressure of the sugar solution, but I still can’t really explain what happens on a molecular ...
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3answers
48 views

Why does Vapor Pressure decrease on addition of solute? [duplicate]

Consider a vessel with a volatile liquid in it. Let's say it has a vapor pressure $P^0$ when it is pure. Now a non-volatile solute is added to it. Its vapor pressure decreases as $P^0\chi_{solvent}$. ...
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1answer
22 views

Hydrogen and Hydrogen ion

Is it correct that a hydrogen atom only has 1 electron and 1 proton since the atomic mass is 1? Also, is the hydrogen ion composed of a single proton and no electrons? In an ionization process we know ...
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2answers
71 views

Copper anode dissolves in electrolysis of copper sulfate solution [closed]

I did an experiment with copper sulfate where you place two copper rods in an aqueous solution of copper sulfate. You apply an electric current and copper metal builds up on the cathode. I noticed ...
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2answers
112 views

How does a shock, such as the snap of the disk in a reusable hand warmer, trigger the re-crystalization of a supersaturated solution?

Reusable handwarmers are made of something dissolved nearly to its saturation point in hot water (Sodium Acetate in the case of HotSnapz) at a high temperature, and then cooled to a temperature at ...
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1answer
26 views

When is Raoult's Law valid for solid-liquid solution?

Raoult's Law for solid-liquid solution is stated as such in my books that it is applicable for all non-volatile solutes. However different solutes must have different attractive or repulsive forces ...
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1answer
57 views

Suitable safe cleaning solution for aliphatic urethane

I am looking for a suitable cleaning solution for a sprayed on coating that is an acrylic aliphatic urethane. My end goal would ideally be something that can neutralize rust, whiten and brighten the ...
3
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1answer
66 views

What is the temperature needed for a reflux using a mix of solvents as the reaction medium? [closed]

I had a quick query regarding the setup of a reaction. The procedure that I am working from states that I need to put my reaction mixture under reflux for 3 hours. The solvents used are diethyl ether (...
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3answers
1k views

What does washing and drying a solution mean?

After combining two solutions, a direction in a 1970s British chemistry book says to wash the new solution with a mixture of baking soda, table salt, and water. Then it says to dry it with anhydrous ...
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1answer
300 views

Does the rate of movement of ions in a salt bridge affect the total voltage produced by a Galvanic cell?

I was thinking that different salts used in a salt bridge in a voltaic cell may have different rates of flow of ions in them (perhaps ionic radius or some other property affects the rate?) I was ...
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1answer
910 views

How to calculate the depression in freezing point of a solution in which there are multiple solutes being added?

In just about every problem I've encountered earlier, all such questions describe the process for calculating the depression in freezing point for a solution wherein there is only one solute. However, ...
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1answer
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Electrode Potential at Equilibrium

At each electrode-electrolyte interface there is a tendency of metal ions from the solution to deposit on the metal electrode trying to make it positively charged. At the same time, metal atoms of the ...
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1answer
321 views

Detailed kinetic explanation for vapor pressure reduction by dissolved solute?

The following problem was asked in JEE Mains 2020 (Sept 2, Shift 1), An open beaker of water in equilibrium with water vapor is in a sealed container. When a few grams of glucose are added to the ...
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1answer
101 views

What happens to depression when two solutions are mixed? [closed]

Equal volumes of $\pu{1.0 M}$ $\ce{KCl (aq)}$ and $\pu{1.0 M}$ $\ce{AgNO3 (aq)}$ solutions are mixed. The depression of freezing point of the resulting solution (with respect to water) will be (assume ...
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1answer
2k views

How to derive van 't Hoff equation for Henry's law constant?

While studying about Henry's law, I encountered this equation: $$\frac{\mathrm d\ln H}{\mathrm d(1/T)}= \frac{-\Delta_\text{sol}H }{R},$$ where $\displaystyle\mathrm d(1/T) = -\frac{\mathrm dT}{T^2}$ ...
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3answers
11k views

Does solute add to volume of solution?

I have to calculate the concentration of sucrose in water just by knowing their masses (and their temperature). Now, if the volume doesn't change when the sugar is being dissolved, I can do that quite ...
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4answers
2k views

Is vapour pressure of a liquid solution constant at a given temperature, no matter the size of closed container and amount of liquid taken?

Does vapour pressure of a liquid solution depend on the size of closed container, amount of solution taken, given that, temperature is kept constant? Or will it change, if some extra gas is added to ...
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1answer
93 views

Who came up with C1V1 = C2V2? [closed]

I was wondering if there is an original scientific publication showing why $C_1V_1 = C_2V_2$ works. Or perhaps, who described/used it first?
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19 views

Solubility Product, and it's relation to solubility

In order to remove temporary hardness of water, it is boiled. On boiling, while Ca(HCO3)2 gives CaCo3(ppt.) , Mg(HCO3)2 gives Mg(OH)2(ppt.). According to my book precipitation of Mg(OH)2 occurs due to ...
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2answers
235 views

How to calculate the pH of a redox reaction between nickel(IV) oxide and silver?

For the following reaction: \begin{gather} \ce{NiO2(s) + 4 H+(aq) + 2 Ag(s) -> Ni^2+(aq) + 2H2O(l) + 2Ag+(aq)}\\ E^\circ = \pu{2.48 V} \end{gather} Calculate the $\mathrm{pH}$ of the solution if $E ...
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1answer
2k views

How to calculate the amount of substance of sodium that are in 10 mL of 30% sodium chloride?

How much of sodium is there in 10 mL of 30% sodium chloride? $30\%$ of $\ce{10 ml}$ is $\pu{3 g}$ $\ce{NaCl}$. There is $\pu{3000 mg}$ of $\ce{NaCl}$ and would that be divided by the molecular weight ...
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25 views

Is sulfuric acid necessary for Kevlar synthesis?

In the production of Kevlar, the 2 monomers needed for its creation are reacted in a solution. Due to it being water-insoluble, sulfuric acid is used. My question: Can other chemicals be used as well (...
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2answers
7k views

Why would a solution of FeCl2 appear brown/yellow sort of like FeCl3?

If we prepare a solution of $\ce{FeCl2}$ by dissolving solid $\ce{FeCl2}$ powder in water, supposing the bottle of $\ce{FeCl2}$ was left open for sufficient time, is it possible for $\ce{FeCl2}$ to ...
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4answers
1k views

Why does the degree of dissociation change when we dilute a weak acid even though the equilibrium constant is constant?

$K$ represents the ratio of concentrations of molecules in a solution at equilibrium, which means that $Q_\mathrm{r}$ (that ratio at any given point) looks to be identical to $K$. In other words, the ...
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2answers
756 views

How to dissolve cat hair without effecting fabric?

I am wondering if it is possible to create some sort of a solution that will dissolve cat hair (or dog hair), but, is not harmful to the surrounding fabric? I am picturing a solution you would soak a ...
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1answer
34 views

Actual color of colloids [closed]

I have read that the color of colloid depends upon the wavelength of light scattered by the dispersed phase and also in the sense in which the receiver receives the light. If all of this depends on ...
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1answer
3k views

Unit conversion of Molar Conductivity

I know this might be a silly question but I am confused with different answers of internet. My question is: Molar conductivity is given as: Molar conductivity = $\frac{\kappa}{M}$. S.I. unit of : $...
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1answer
5k views

Does glycerin promote bacterial growth the same as water?

A sodium chloride + water solution draws the water out from bacteria through the process of osmosis. Would a sodium chloride + glycerin solution have the same antibacterial effect? If I understand ...
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3answers
4k views

Does freezing a solution with water always cause the water to separate and form the ice lattice?

I'm curious, I was trying to look into the affect of freezing a solution with water even when the solution is completely miscible. I came across something that detailed this regarding salt water and ...
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2answers
201 views

Is there a potentiometric method for monitoring salt formation in organic solvent?

I work in a pharmaceutical R+D lab, and currently aim to develop a validatable potentiometric method for determining the optimal amount of acid to add to a basified small organic molecule for ...
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57 views

Freezing point of solution of Water, Ethanol and Sugar (aka, Limoncello)

I'm looking for a diagram of the freezing point of a water solution depending on its content in sugar and ethanol. More colloquially, I want to know how to balance alcohol and sugar so that my ...
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1answer
69 views

Find volume of ammonia gas required to prepare a solution of given pH [closed]

Calculate the volume of gaseous ammonia $(K_\mathrm{b} = \pu{1.8E-5})$ to dissolve (at NTP) in $\pu{100 mL}$ of water in order to obtain a solution with $\mathrm{pH} = 11.0.$ Consider volume variation ...
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2answers
595 views

Can aluminium form blue-colored solution in liquid ammonia?

I am a high school student and in one class, my inorganic chemistry teacher told group 1 elements with the exception of lithium and group 2 elements with exception of Be form blue-colored solutions ...
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1answer
44 views

Ionisation vs Dissociation

This is a statement given in my book: A strong electrolyte is completely ionised at all dilutions but not completely dissociated. But the book also uses the terms "Ionisation" and "...
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2answers
978 views

Verification of variants of the Ebullioscopic formula

Wikipedia cites the following formula for the ebullioscopic constant $K_{\mathrm{b}}$ regarding the elevation in boiling point of a volatile solvent upon addition of a non volatile solute (https://en....
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28 views

What is vacuum-assisted ultrasonication?

This quote from a methods section of a paper: [samples were] ultrasonicated for approximately 30 min to ensure adequate dispersion of the components throughout the mixture. The solution was then ...
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1answer
86 views

At what composition is Maximum deviation from Raoult's law observed?

Raoult's law states that in an ideal binary solution of two volatile components, the partial vapour pressure of each component is proportional to its mole fraction in the solution. A plot of total ...

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