Stack Exchange Network

Stack Exchange network consists of 174 Q&A communities including Stack Overflow, the largest, most trusted online community for developers to learn, share their knowledge, and build their careers.

Visit Stack Exchange

Questions tagged [solubility]

For questions related to the solubility of compounds in various solvents, especially in water. Do not confuse with [solutions] or [aqueous-solution].

11
votes
0answers
172 views

Why is Diiron nonacarbonyl so exceptional?

My textbooks says: With exception of $\ce{Fe2(CO)9}$, all other metal carbonyls are soluble in hydrocarbon solvents. Weller, M.; Overton, T.; Rourke, J.; Armstrong, F. Inorganic Chemistry, 6th ed. ...
8
votes
0answers
898 views

How to make pyramid-shaped NaCl salt crystals

I'm attempting to make sea salt pyramids like the one below. I understand this needs to be evaporated at a reasonable speed to stop the crystals forming a cube, as the when formed quickly, the edges ...
6
votes
0answers
918 views

Yellow precipitate in SnCl2 solution

I have a few small bottles of 0.5M $\ce{SnCl2}$ solution, however solution was prepared about 4 months ago, and there is a yellow precipitate on the bottom of each bottle. Working hypothesis is that ...
6
votes
0answers
146 views

What factors contribute most to solubility of ionic substances in highly polar solvents, esp. ionic liquids and DES?

I am trying to determine a method to dissolve a mineral salt with a lattice energy of ≈18000 kJ/mol. I know that lattice energy is the most significant factor affecting solubility of an ionic ...
6
votes
0answers
108 views

Alkali Metal Rosinates Solubility in Acetone

In violin finishing technology alkali metal Rosinates are used in varnish synthesis. Usually this alkali metal Rosinates are soluble in Turpentine. I also know that Copper, Zinc Rosinates are soluble ...
6
votes
0answers
831 views

What substance has the lowest Ksp value?

What substance has the lowest $K_{sp}$? What is the value of its $K_{sp}$? The lowest I could find is $2.6*10^{-124}$ for cobalt(III) sulfide.
5
votes
0answers
129 views

Why isn't orthoboric acid soluble in cold water even though it has polar B-OH bonds?

This is the information I found regarding orthoboric acid's solubility: Textbook (NCERT India): Sparingly soluble in water (didn't say what temperature - presumably cold) and highly soluble in hot ...
4
votes
0answers
568 views

Why is potassium bitartrate so insoluble?

The solubility of potassium bitartrate in water at 20°C is given by Wikipedia as 0.57 g per 100 ml, which is considerably lower than that of sodium bitartrate. Generally, a potassium salt is more ...
4
votes
0answers
411 views

Theory of volume contraction in solution

When a solid is dissolved into a liquid, or two solids are amalgamated, their mutual volume will contract. For example, a crystal of sugar having a volume of one cubic inch dissolved into 10 cubic ...
4
votes
0answers
1k views

How to break down soap and detergents?

I am building a greywater harvesting system. It is a 3-stage system: The 1st stage breaks down soap and detergents. The 2nd stage filters the water. The 3rd stage pumps water out of system. What ...
3
votes
0answers
132 views

is syringaldazine soluble in water?

Would it be better to use water or ethanol as a solvent for syringaldazine? Why? Would water interfere with the oxidation of syringaldazine if laccase enzyme was added?
3
votes
0answers
469 views

Is there a simple way to memorize/reason out the solubility rules?

Normally, to determine if a compound is soluble, I would just apply the solubility rules, which can be found here. The problem is, these are not fun to memorize as there are often loads of exceptions ...
3
votes
0answers
38 views

Why is this scintillator component turning into a milky-white emulsion?

I am a chemistry and physics double major doing some chemistry work in a nuclear physics lab. My mentor is a physicist, so his area of expertise is occasionally mismatched with what I need for my ...
3
votes
0answers
46 views

Transfer of odor molecules from oil to water

I brew beer, I'm not a chemist. I want to add natural peanut aroma to a beer. The most common way this is being done by brewers is the addition of peanut powder, which is essentially the product ...
3
votes
0answers
51 views

How do salts of a weak acid + weak base behave in solution?

Say you have Ammonium Formate in solution, the salt formed by the reaction of Formic Acid and Ammonia. Would both the Formate ion and Ammonium ion protonate and deprotonate, respectively, to form ...
3
votes
0answers
41 views

How to determine concentration limits of a buffer that's limited by solubility?

I need to maintain a certain range of % of ionisation from a buffer. For e.g. Histidine buffer. When making high concentration of this buffer at (say) pH 7.2, 25'C, [concentration] is limited to 75mM ...
3
votes
0answers
149 views

The behaviour of Ag3PO4 in solution

To a 1L flask, we add $4.1900\mathrm{g}$ ($0.01001\ \mathrm{moles}$) of $\ce{Ag3PO4}$, then fill it up with water. Knowing the following constants, we are asked to find the concentration of all ...
3
votes
0answers
86 views

Poor aqueous solubility of chloroazodin

Below is the structure of chloroazodin: Why is chloroazodin poorly soluble in water? It has multiple amine and imine nitrogens, all of which appear to be available for hydrogen bonding, and thus it ...
3
votes
0answers
85 views

Why are critical micelle concentrations so large?

Dissolving a non-polar molecule in water incurs a free energy cost of about $10 kJ/(mol \cdot nm^2)$ (source: http://bionumbers.hms.harvard.edu/bionumber.aspx?&id=101826) The entropy gained from ...
3
votes
0answers
1k views

Lithium chloride is soluble in pyridine while other lithium halides are not. Why?

Lithium chloride is soluble in pyridine while other lithium halides are not. Why? I know that lithium chloride is deliquescent like magnesium chloride. Lithium halides are covalent and thus are ...
3
votes
0answers
119 views

Solubility of Silver Nanoparticles

(i) What happens when you put $\ce{Ag_{10}}$ and $\ce{Ag_5}$ clusters into an aqueous solution of pH = $13$ (ii) What happens when you put $\ce{Ag_{10}}$ and $\ce{Ag_5}$ clusters into an aqueous ...
3
votes
0answers
682 views

Polarity and Solubility of Tetracyclone

In one of my organic chemistry experiments, I synthesized tetracyclone (Tetraphenylcyclopentadienone), and we were supposed to dissolve it in DCM to do our TLC. DCM is polar and looking at the ...
3
votes
0answers
271 views

Brewing tea with deionized water

I am wondering what efect brewing tea (let us assume for the sake of simplicity it is green tea, brewed at about 80 °C) in deionized water might have on the product. Will the lack of ions in the ...
3
votes
0answers
79 views

How could I find the solubility of hydrocarbons such as iso- and n-Butane in liquid Methane?

I am trying to figure out the dissolution capacity of iso and normal butane in methane at very low temperatures (110K). This would allow me to make compositions that prevent freeze out of these ...
3
votes
0answers
1k views

Purity of precipitate in selective precipitation

An aqueous effluent contains $12\ \mathrm{mol\ l^{-1}}$ $\ce{Cd^2+}$ and $10\ \mathrm{mol\ l^{-1}}$ $\ce{Mg^2+}$ as solution of nitrates. Current practice is use $\ce{NaOH}$ to selectively precipitate ...
3
votes
0answers
79 views

UV curable adhesive

I'm looking for a UV curable adhesive that can be removed without peeling or burning. Ideal removal would be some kind of solvent over a relatively short period of time. I also need it to have a ...
3
votes
0answers
363 views

Galvanic Element: Silver Iodide and Standard Hydrogen cell

I have to calculate the $\mathrm{p}\ce{H}$ of the $\ce{H+}$ solution with the following info: $\ce{Ag(s) | AgI(s) || H2(g)(1atm) | H+(aq) (X mol/L) | Pt(s)}$ $E=0.1\:\mathrm{V}$ Temperature $T=25^\...
2
votes
0answers
123 views

Varying data about solubility of sodium acetate trihydrate

I recently looked up the solubility of sodium acetate trihydrate in water at 20°C and found surprisingly diverse values such as: 613g/l (GESTIS-Stoffdatenbank) 762g/l (TU Freiberg) 1250g/l (applichem, ...
2
votes
0answers
242 views

Solubility of Calcium Oxalate in Aqueous Alcohol?

In searching through the literature for the solubility of calcium oxalate, I came across this post https://www.researchgate.net/post/Are_there_any_organic_inorganic_solvents_for_dissolving_Ca-oxalate ...
2
votes
0answers
72 views

Other liquids for collecting gas by displacement method for SO2

I am looking for a low cost method of quantifying gases evolved from a reaction. The gas mixture is expected to have $\ce{H2}$, $\ce{SO2}$ and $\ce{CO2}$ but likely others too. I am considering using ...
2
votes
0answers
93 views

How can I decrease the Krafft temperature of an hexadecyl sulfate surfactant?

I need to prepare an anionic surfactant from a treatment of cetyl alcohol (hexadecanol) and $\ce{H2SO4}$, and then neutralize it using $\ce{NaOH}$ or $\ce{NH3}$; but sodium hexadecyl sulfate has a ...
2
votes
0answers
450 views

How does increasing ionic strength affect the pH of solution?

I'm having trouble interpreting the data for an experiment. With increasing ionic strength, I found lower solubility but also lower pH of the solution. What is the effect of the ionic strength on the ...
2
votes
0answers
74 views

Chemical theory, formula(s) that predict final *volume* of a solution?

I asked this question a couple years back regarding the volume of a mixture being less than the volume of the original solute and solvent, but this question asks if there is theory and/or formulation ...
2
votes
0answers
373 views

Does water acidity affect sugar solubility?

For example, when making lemonade: will mixing sugar in water after adding lemon juice lead to a slower sugar dissolving rate, than if sugar were mixed in before adding lemon juice?
2
votes
0answers
76 views

pH and solute solubility in waste mixed water

I was reading a module on waste management. There were two interesting points. High pH results in higher solubility of $\ce{CN-}$. I understand that for HCN: $$\ce{HCN ->H+ + CN-}$$ Higher pH ...
2
votes
0answers
423 views

Why add specifically hot solvent during recrystallization procedures instead of heating it up after?

Recrystallization methods that I have seen online and in manuals involve adding a minimum amount hot solvent to the solid mixture. Is there a reason I should do this instead of adding an equivalent ...
2
votes
0answers
52 views

Looking for solubility kinetics of zinc chloride hydroxide monohydrate

$\ce{Zn5(OH)8Cl2.H2O}$ is a crystalline solid insoluble in water. Often used as nutritional supplement. Preparation and chemistry of zinc chloride hydroxide monohydrate is known. I am looking for some ...
2
votes
0answers
404 views

solubility of silver benzoate

The ionisation constant of benzoic acid is $6.46*10^{-5}$ and Ksp of silver benzoate is $2.5*10^{-13}$. How many times is silver benzoate more soluble in a buffer solution of pH-3.19 as compared to ...
2
votes
0answers
180 views

Why do some insoluble salts undergo slow chemical reaction instead of dissociation in water?

$$\ce{PbCl2 + H2O ->[\Delta] Pb(OH)Cl + HCl}\tag{1}$$ $$\ce{2ZnCO3 + H2O ->[\Delta] Zn2(OH)2CO3 + CO2}\tag{2}$$ $$\ce{2NiS + 2H2O → Ni2(OH)2S + H2S}\tag{3}$$ $$\ce{Hg2SO4 + H2O → HgO + Hg + ...
2
votes
0answers
137 views

Alternative to water as solvent for lithium metaborate?

I want to prepare a sample of lithium metaborate ($\ce{LiBO2}$) and need to dissolve it for this purpose. The only solvents I found so far are water and ethanol. In ethanol, one cannot dissolve ...
2
votes
0answers
429 views

How to find the standard enthalpy and entropy for the dissolution of silver chloride?

A maximum of $1.89~\mathrm{mg}$ of $\ce{AgCl}$ will dissolve in $1.00~\mathrm{L}$ of solution at $25.00~^\circ\mathrm{C}$. A maximum of $5.26~\mathrm{mg}$ of $\ce{AgCl}$ will dissolve in $1.00~\...
2
votes
0answers
137 views

Why don't plus one oxidation state metals form stable complexes with hydroxide ion?

For example, why doesn't AgOH exist as a stable compound? I read that it rapidly decomposes to silver oxide and water. $\ce{2AgOH -> Ag2O + H2O}$ $~~~~~~~~~pK_{decomposition}= 2.875$ http://...
2
votes
0answers
1k views

Prediction of solubility (from chemical structure) at different pHs

I would like to know What is the best method for predicting the water solubility (and in other solvents) of a compound given its molecular structure at different pHs. What I know now is based on the ...
1
vote
0answers
27 views

Would boiling distilled water in a kettle full of limescale increase the hardness of the water?

If I had a kettle which had limescale on it (due to several episodes of boiling hard water), and I would use it to boil distilled water, would that mean that some of the precipate dissolve into the ...
1
vote
0answers
487 views

Explain the effect of intramolecular hydrogen bonding on solubilities in cold and hot water?

There is a statement given in my textbook (Cengage, Organic Chemistry (Part 1), page 4.33) which is as follows: (I edited the statement to make it simpler) One can account for the solubilities of ...
1
vote
0answers
19 views

The Salt Effect stops working in extreme cases?

I and three friends did an experiment where we investigate the salt effect, also known as the uncommon ion effect. The specifics are that we made a $\pu{1L}$ solution saturated with $\ce{CaCO3}$ and $...
1
vote
0answers
51 views

Can a molecular sieve be used increase the saturation of a fructose solution?

The Problem: Let's say we have an experiment where we are attempting to grow rock candy crystals by letting a solution of sugar crystalize on a wooden dowel. However, an error may have been made in ...
1
vote
0answers
64 views

Will ferric nitrate or nitric acid dissolve polylactic acid?

Will ferric nitrate dissolve 3D printed items? I wish to etch some sterling silver, for which we use either ferric nitrate or nitric acid, and wonder about 3d printing the design straight onto the ...
1
vote
0answers
676 views

What is the difference between dissolution and absorption?

Let us first look at the definitions from Gold Book: Absorption: The process of one material (absorbate) being retained by another (absorbent); this may be the physical solution of a gas, liquid, ...
1
vote
0answers
568 views

Polarity of Acetic Acid, Ethanol and 1-Propanol

In order to compare acetic acid, ethanol and 1-propanol in terms of solubility in hexane, I would like to order them in terms of (a)polarity. By looking up the dipole moments, I found that these ...