Questions tagged [solid-state-chemistry]
Study of chemical species that are in solid phase, either in cases of their properties, or about ways of synthesizing them.
278
questions
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0answers
21 views
How is the height between two non consecutive layers of Face Centred Cubic not equal to two times the side length?
In my textbook it says that the height between two consecutive layers of face centred cubic is 2*side length * root 0.6666 which also happens to be the height between two non consecutive layers of a ...
1
vote
3answers
129 views
Why water cools from outside to inside?
It is a well-known fact that
Water kept in a container, on cooling, results in freezing with initially at the circumference of surface
(1D), then on the surface (2D) and then throughout the volume (...
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0answers
33 views
Can we determine if a compound is stoichiometric or non-stoichiometric from the chemical formula?
I often see alloyed perovskites are written in the format of $\ce{A'_xA''_{(1-x)}B'_xB''_{(1-x)}X_3}$. I am confused, if mole fractions of elements in A-site and B-site add up to 1 separately (E.g. $\...
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0answers
27 views
“e and a” as combinations of pi bonds
I am trying to get a better intuition on solid-state physics but I am a chemist by degree. I came across this article that attempts to bridge the gap between solid-state physics and molecular ...
4
votes
0answers
22 views
How is the Born-Lande equation modified when the structure is not NaCl?
Often the Born-Lande equation is quoted (alongwith the calculation of the Madelung constant and Born exponent) with reference to rock-salt structure. But what if we take some other crystal, like ...
0
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1answer
20 views
Doping of a solid with impurities [closed]
This question is a continuation of the previous question of mine:press me if you wish
And my question is how can I dope a solid with impurities and if the process can be understood with basic ...
0
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2answers
80 views
How to identify if a material is perovskite or not?
This is more of a materials science question, but I believe many of you have referred NIST Inorganic Crystal Structure Database (ICSD) database.
I am collecting a database of perovskite materials and ...
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1answer
49 views
Are HCP and Primitive Hexagonal Unit Cell the same thing? [closed]
In HCP, the [2D] Hexagonal packed layers are arranged in ABAB form. The same happens in Primitive Hexagonal Unit Cell. So does that mean they are the same? If not what differentiates one from the ...
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2answers
54 views
Why rutile structure have primitive unit cell instead of body centered?
In the literature (Wikipedia), I read that $\ce{MgH2}$ have a structure of rutile. Then, I looked at its space group which is $P4_2/mnm$. From this notation, I understood that it possesses a (...
0
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0answers
39 views
Do all metals expand on heating? [duplicate]
This question came up when I was reading about substances with negative thermal expansion. The article by Takenaka [1] gives a good list of materials displaying negative thermal expansion. I noticed ...
0
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0answers
44 views
How can fluorite structure exist?
From the information from Google the radius of $\ce{Ca^2+}$ cation is $100 \,\pu{pm}$ and of $\ce{F-}$ anion is $132\, \pu{pm}$, so essentially $\ce{F-}$ ion should form the Bravais lattice (FCC/CCP) ...
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41 views
Reason behind more prioritising of normal spinels
According to my textbook:
In normal spinels $\ce{A^{II}}$ should have occupied octahedral voids, but this factor is outweighed by greater lattice energy or smaller cation $\ce{B^{III}}$.
Later,
...
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votes
2answers
138 views
Change in the number of ions due to exchanging ions [closed]
If the position of Na+ and Cl- are interchanged in NaCl having FCC arrangement of Cl- ions then what change we can observe in the unit cell of NaCl.
I am confused as how the contribution will change ...
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votes
1answer
62 views
Calculate third and fourth nearest neighbours in fcc packing [closed]
My textbook has given data for third and fourth nearest neighbours to be 6 and 8 with distancesĀ Ā a andĀ ā(3/2)a.
I have been able to calculate for the first and second nearest neighbour but it has ...
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1answer
23 views
Effect of pressure on transition temperature
I was wondering if someone can explain why the answer to the following question is volume instead of the others.
If pressure has no effect on the transition temperature between two crystalline forms ...
2
votes
1answer
234 views
Is the number of tetrahedral voids always equal to double the number of octahedral voids in any crystal?
I came accross the question whether the number of tetrahedal voids is always equal to twice the number of octahedral voids (in the case where both the voids are present). The key was given as the ...
0
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0answers
16 views
Is the alloy of Fe, Si substitution alloy or interstitial alloy?
When atoms of the solute in a solid solution occupy positions
normally occupied by a solvent atom, we have a substitutional alloy. When the sol-
ute atoms occupy interstitial positions in the āholesā ...
0
votes
1answer
34 views
Melting point of crystalline solids
Why crystalline solids have sharp melting points but melting point of amorphous solids vary within a range?
Is it because the interaction energy is equal between atoms of crystalline solids so they ...
0
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1answer
47 views
Why are crystalline solids anisotropic? [closed]
Why crystalline solids are anisotropic whereas amorphous solids are isotropic?
Is it because in crystalline solids, X, Y and Z dimensions vary, but so does in amorphous.
Please write as simple as ...
0
votes
1answer
70 views
Are clathrates and interstitial compounds the same thing?
In the book$\ce{^{[1]}}$, it's given that clathrates are compounds in which gases are entrapped within cavities of crystal lattices of certain organic or inorganic compounds. Interstitial compounds ...
1
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0answers
17 views
Unit cell in a hexagonal closed pack structure
My textbook says that there are only 14 possible 3D lattices(Bravais Lattices).
One of these 14 lattices is a hexagonal lattice in which only a primitive variation is given to be possible.
But then I ...
0
votes
1answer
52 views
Cation-anion radius ratio of manganese difluoride
How to determine the cation-anion radius ratio for $\ce{MnF2}?$
I tried to calculate the $r_\mathrm{c}/r_\mathrm{a}$ ratio using the relationships:
$$2r_\mathrm{c} = c$$
and
$$(2r_\mathrm{c} + 4r_\...
1
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0answers
28 views
Sphalerite type structure
There are binary diamond type structures for example S and Zn form sphalerite. I thought the reason this formed was because of the big difference in the radii of the atoms that allows the smaller atom ...
1
vote
1answer
60 views
Is there a crystal structure of ammonia in ionic form?
Like solid $\ce{PCl5}$, does solid $\ce{NH3}$ exist as $\ce{[NH4+][NH2-]}$ (i.e. ammonium amide)?
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0answers
54 views
Why is liquid germanium denser than solid germanium?
Why are some elements like Ge and Si have liquids denser than their solids? In water it is explainable by H bonding, but no H bonds or such are there in Ge and Si.
Well, I want an explanation about ...
1
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1answer
98 views
Does a unit cell have to contain a whole number of atoms?
I was given this problem recently to compute the number of ions in a unit cell of ferrous oxide $\ce{FeO}$. The data given was:
Side length $a = \pu{5 Ć
}$
Density $d = \pu{4 g/cc}$
Using the formula ...
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votes
1answer
106 views
Why does Xenon Hexafluoride exist as [XeF5+][F-] and not [XeF5+][XeF2-] in the solid state [closed]
I already referred to this similar question but it yielded no explanation for the reason. Cations and anions of similar sizes stabilize each other through lattice energy effects in the solid state. ...
4
votes
1answer
85 views
Fractional index in a chemical formula of metal oxide
I have just read an article in which they used $\ce{WO3}$ and $\ce{WO_{2.9}}$ as precursors, whose objective was to form $\ce{WS2}$, in an atmosphere of argon by CVD. In one boat there is the powder ...
1
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0answers
53 views
Data-processing pipeline for protein x-ray crystallography: uncertain of terminology and order of procedures [closed]
Background: I am trying to get an overview of the data-processing pipeline for solving protein structures by x-ray crystallography, and in a very simple way understand what mathematical procedures are ...
0
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0answers
15 views
The Limitation of Solid Phase Peptide Synthesis In Case of Polyglycine
I was wondering if I could use your experience and all the precautions you would like to recommend for a long peptide synthesis via SPPS.
I've already got a low loading resin so this way I'll minimize ...
0
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2answers
283 views
How to determine the chemical state of a reactant or product in a chemical equation?
I am asked this question:
Write a balanced equation, including state symbols, for this reaction:
$\ce{calcium + hydrochloric acid -> calcium chloride + hydrogen}$
I answered this:
$\ce{Ca(s) + ...
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0answers
65 views
Violation of Fajans' rule
According to Fajans' rules, greater charge in an ionic compound results in more covalent character. But why is it that sodium oxide is more covalent than magnesium oxide? Google says boiling point of ...
3
votes
1answer
137 views
Does the Fermi level correspond to the highest occupied energy level?
I know that, in the band structure of a solid, the Fermi level is the energy level at which there is a 50% probability of finding an electron (at thermodynamic equilibrium), and that it doesn't have ...
2
votes
1answer
54 views
Is an amorphous solid a single phase? [closed]
Amorphous solid possess short-range order but no long-range order (e.g. amorphous silica, the short-range order is originated from the tetrahedral bonding between Si and O). Is it possible to have ...
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votes
2answers
58 views
Lattice enthalpy and ionic charater
As we move down in sulphates of group 2 their solubility decreases because there is a drastic decrease in hydration enthalpy as compared to decrease in lattice enthalpy.
Does the decrease in lattice ...
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votes
1answer
144 views
Unexpectedly low melting point of Aluminium
According to Wikipedia, the melting point of aluminium is 933.47K (660 oC) while the melting point of magnesium is 923K (650 oC), yet the melting point of sodium is merely 370.87K (98 oC).
With huge ...
2
votes
1answer
275 views
Why does aluminum chloride have a higher lattice energy than aluminum fluoride?
From the table below (source: McMurry's Chemistry [1, p. 212]), it is evident that $\ce{AlCl_3}$ has a higher lattice energy than $\ce{AlF3},$ even though $\ce{F}$ is smaller than $\ce{Cl}$. Why is ...
2
votes
1answer
90 views
Why does the colour of the same compound (e.g. magnesium nitride) differ?
When I am searching the colour of $\ce{Mg3N2}$ I came across photos showing different colours: greenish-yellow on Wikimedia,
and some other just yellow on some Google Images results.
I am eager to ...
3
votes
1answer
238 views
Structure of crystalline boron trioxide
I recently came across the statement
The structure of crystalline $\ce{B2O3}$ consists of $\ce{BO4}$ tetrahedra, two sets of which form two types of interconnected spiral chains, three $\ce{B-O}$ ...
1
vote
1answer
158 views
Why Frenkel defect does not impact the density of the solid?
The following text is from Chemistry Part I - Textbook for Class XII (NCERT), chapter "The Solid State", page 23, topic "1.9 Imperfections in Solids", sub topic "1.9.1 Types ...
3
votes
3answers
215 views
Why cobalt reacts favorably with nitrogen?
I used also iron, nickel, zinc, copper. However, cobalt gives the easiest and straight forward yield of nitrides (XPS and SAED verified).
It is so easy to get cobalt nitride that I don't even have to ...
3
votes
1answer
83 views
Is there a “Comprehensive Solid State” book?
We have Comprehensive Coordination Chemistry, Comprehensive Organometallics, Comprehensive Organic Synthesis and probably few other similar works that aim to do a wide review of recent works at the ...
9
votes
2answers
551 views
Software for generating a lattice from a unit cell for molecular crystals?
I am looking for a software package which can take a unit cell (and lattice parameters, etc.) and from that generate a crystal lattice. Ideally it will have functionality for orthorhombic, hexagonal, ...
0
votes
0answers
46 views
Validity of Maxwell-Boltzmann distribution for solids [duplicate]
Suppose there is a solid made of avogadro number of, say, aluminium atoms. This solid is kept at 273 K. According to Maxwell-Boltzmann distribution, all the particles or atoms will not have the same ...
3
votes
0answers
146 views
Electrical and thermal conductivity of graphite
I was reading about carbon family where it was mentioned that electrical conductivity of graphite increases with temperature while thermal conductivity decreases.
However, I could not find a suitable ...
0
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0answers
27 views
Is silicon-oxygen bond length non-uniform in quartz glass?
In many pictures depicting the molecular structure of quartz glass(In fact, almost every picture that represents amorphous state of any solid that I have seen), the bond lengths are non-uniform (I do ...
1
vote
1answer
47 views
Do solids flow? [duplicate]
I am now confused whether solids flow or not. Some people say solidity is only a time scale notion. Some others say solids do not flow at all. While some authors say there is a threshold stress below ...
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0answers
51 views
Visualization of all hcp voids
There are 12 tetrahedral voids and 6 octahedral voids in hcp unit cell but I can't find any image that can show all tetrahedral voids and all octahedral voids in hcp unit cell (the common picture in ...
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0answers
48 views
Finding ionic radii from solubility data and density
$\pu{5.35 g}$ of a salt $\ce{ACl}$ is dissolved in $\pu{250 ml}$ of solution. The $\mathrm{pH}$ of the resultant solution was found to be $4.85.$ Find the ionic radius of $\ce{A+}$ and $\ce{Cl-}$ if ...
0
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0answers
128 views
Isotropic nature of Amorphous solid
Check the answer given by Divyansh Jain
I am writing this because I am not permitted to comment in that post.
Using Divyansh's idea, How can the physical properties be same in amorphous solid if ...
