Questions tagged [reagents]
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13
questions
-1
votes
1answer
37 views
Why don't we use silver hydroxide instead of Tollen's reagent for test of aldehydes? [closed]
AgNO3+NH4OH=AgOH+NH4NO3
AgOH is used for the reaction with aldehyde. But why can't we use silver hydroxide directly?
3
votes
1answer
121 views
Labware to handle hot aqueous NaOH
This question regarding appropriate handling of hot concentrated aqueous $\ce{NaOH}$ - with particular concern for avoiding dissolution of borosilicate glassware and contamination of the $\ce{NaOH}$ ...
6
votes
1answer
114 views
Can I make a mirror on PET plastic using Tollen's reaction?
I want to make a very shiny surface, like a mirror. I tried to use chrome paint but it's barely shiny. It's more like gray even though I bought one of the most expensive crom looking paint.
I know ...
-2
votes
1answer
57 views
1000 mg/L alkalinity as CaCO3 standard preparation [closed]
How do I prepare a 1000 mg/L alkalinity as CaCO3 standard? I found a method that says to dissolve 1.06 g of sodium carbonate (Na2CO3) in 1L of water but I'm not sure why I can't use 1g instead? ...
0
votes
2answers
433 views
How tartaric acid gives Tollen's test?
I wanted to know how Tollen's test is given by tartaric acid. Google searches say that it belongs to some "Hydroxyl" group. I know that it oxidises aliphatic and aromatic aldehydes along with α-...
0
votes
0answers
53 views
Should I use MCPBA here?
I came across a question that asked for a method to convert propene to glycerol. I used the method in the pic, but I'm worried about two steps-
Step-2, This reaction is just made up by myself! I'm ...
0
votes
0answers
38 views
My problem with Tollen's reagent [duplicate]
The formula of Tollen's reagent is $\ce{[Ag(NH3)2]+}$. What is the bond existing between the silver(I) atom and the ammonia groups? Because ammonia is stable, it doesn't need to gain or donate any ...
2
votes
0answers
625 views
Detecting alkaloids - Dragendorff's reagent
I am writing a book and as part of the plot one of the characters has a plant that contains alkaloids in tincture form. They want to do a test to detect for the alkaloids so they use the Dragendorff's ...
0
votes
2answers
70 views
Wetting agent for H2O2 solution
I need to increase the wetting of an $\ce{H2O2}$ solution on ceramic surfaces. Does anyone know of a common chemical I can use for this?
The properties it would ideally have are:
Increases wetting ...
4
votes
1answer
279 views
Salt used in Perkin Reaction
The Perkin reaction gives an α,β-unsaturated aromatic acid by the aldol condensation of an aromatic aldehyde and an acid anhydride, in the presence of an alkali salt of the acid. Here is an a diagram ...
-1
votes
1answer
236 views
Why does 3-hydroxy-butan-2-one give positive Tollens' test?
Why does 3-hydroxy-butan-2-one give a positive Tollens' test despite the absence of an aldehyde group? What is the mechanism?
1
vote
0answers
571 views
Safest and easiest method to neutralize nitric acid
I would like to know the safest method for neutralizing 70% ACS Reagent Nitric Acid that is used in small amounts of 1-5 ml, for an electronics process in which there will be small traces of silicone ...
6
votes
0answers
1k views
Is hydronium an electrophile, nucleophile, both or neither?
Is hydronium an electrophile or a nucleophile? I expected $\ce{H3O+}$ to be a nucleophile due to the presence of electrons in the $\ce{2p}$ orbitals of $\ce{O}$. But the answer key of the test states ...
