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14 votes
3 answers
3k views

In a perfect vacuum, shouldn't every solid be above its sublimation point, since its vapor pressure must exceed the atmospheric pressure?

If the sublimation point of a substance is the point where its equilibrium vapor pressure exceeds the pressure of the atmosphere upon it, and if every solid above absolute zero has some vapor pressure ...
Jacob's user avatar
  • 157
1 vote
1 answer
116 views

What is the exact definition of isotonic solutions?

Background of the Question I am a high school student so maybe my understanding of this topic is quite less, so apologies in case I have asked an elementary question. My chemistry sir taught that :- ...
Adhway's user avatar
  • 185
-1 votes
1 answer
158 views

Why is the relationship between vapour pressure and boiling point of water non-linear?

From my rudimentary understanding of chemistry, pressure should be directly proportional to temperature for a constant mass of gas under the same volume (Charles’s law). However, in the diagram above,...
Yitian Chen's user avatar
1 vote
1 answer
135 views

How do I go about calculating final temperature of tank draining at saturation?

I am working on calculating pressure in a tank where the fluid is sitting at its vapor pressure. For example, imagine a 12 in diameter 100 L tank of nitrous oxide at room temperature (745 psi vapor ...
Alexander Patrus's user avatar
4 votes
2 answers
1k views

Why does the vapour pressure not depend on the surface area and volume of a liquid?

My teacher said that vapour pressure is independent of the surface area and volume of a liquid. But I think it should be dependent, because surface area is directly proportional to the evaporation ...
Rohan Singh's user avatar
-3 votes
1 answer
135 views

Understanding how evaporation works [closed]

I am struggling to grasp the concept of partial pressure and vapor pressure. Consider a sealed container filled with water and a bit of air that is sufficiently dry placed in a room of temperature 25 ...
Ray Siplao's user avatar
0 votes
1 answer
44 views

What happens to the air pressure above water as its heated to and past boiling?

If I put a pressure sensor inside an airtight container half-filled with water, and heat the water, what will the pressure sensor read as the temperature increases? Would it linearly increase (black ...
Oliver Walters's user avatar
10 votes
1 answer
430 views

In a liquid-in-glass thermometer, how does the gas pressure over the liquid affect the linearity of measurement?

In a common ethanol thermometer, the space above the alcohol column is filled with nitrogen. It also contains varying amounts of the alcohol in the gas phase. Source: http://www.aashtoresource.org/...
Karsten's user avatar
  • 42.3k
1 vote
0 answers
135 views

Saturation of air within isolated system with water and ethanol

I am planning an experiment in an isolated system that contains two droplets. One droplet is water and the other one is a 40% ethanol-water mixture. The isolated compartment is filled with air at 20°C....
schnoedroeboenick's user avatar
2 votes
1 answer
343 views

Does the vapor pressure of a substance depend on the presence of other gases?

The Clausius-Clapeyron equation (CC equation) can be used to find the (saturated) vapor pressure of a substance ie. the gas pressure at which the two phases (vapor + liquid or vapor + solid) reach ...
Physics2718's user avatar
2 votes
1 answer
625 views

Variation of vapour pressure with application of external pressure

Many times study of fact that with pressure of a substance only depends on the temperature and nature of the substance recently I study about dew point and bubble point. Then I came up with this ...
user avatar
3 votes
1 answer
620 views

Relative humidity and vapor-pressure in equilibrium

I have quite an unclear understanding of relative humidity. I am writing my understanding on the topic and please correct me wherever I'm wrong: What I understood: Let's say $\ce{H2O}$ has a (...
Soumil Gupta's user avatar
-1 votes
1 answer
145 views

Latent Heat, Vapor pressure and Equilibrium [duplicate]

So after reading about this topic i wanted to share what i learned and i wanted you guys to tell me if what i am writting is correct: A pressure vessel has propane inside and it is pressurized. The ...
pedro vaz's user avatar
2 votes
0 answers
175 views

Measuring vapour pressure in a closed system

My experiment requires the determination of vapour pressure from which I will calculate the number density (or number of moles of the molecule) later, for a closed system. Here's my setup : Liquid ...
ankit7540's user avatar
  • 1,582
1 vote
2 answers
142 views

Shouldn't the pressure of gas above a liquid slightly decrease when some of its molecules dissolves in the liquid? [closed]

Lets say a liquid and gas above are in equilibrium. (1) Now if I suddenly increase the pressure of the gas it will take some time for some molecules of the gas to enter the liquid and get dissolved. ...
Shyam's user avatar
  • 21
-2 votes
1 answer
91 views

Doubt about definition of boiling point [duplicate]

The definition of boiling point says boiling point is the temperature at which the vapour pressure of liquid becomes equal to vapour pressure of atmosphere. But how does the vapour pressure of the ...
user12076043's user avatar
1 vote
2 answers
228 views

What is the vapor pressure of a liquid if it is not in a sealed container(i.e., a river or lake)? Is it just the atmospheric pressure? [closed]

From what I understand, the boiling point of a liquid is when its surrounding pressure is equal to its vapor pressure. The vapor pressure is the pressure of the gas form of the liquid in a container ...
Ethan Ye's user avatar
-2 votes
2 answers
699 views

How do you manage to liquefy a gas by applying only pressure? [closed]

How can you liquefy a gas by applying only pressure? To increase the pressure of a gas you need a compressor, and when the compressor does work on the gas , it will increase his pressure but at the ...
pedro vaz's user avatar
2 votes
1 answer
82 views

Why is so different the temperatures of a compressed gas compared to a liquid/gas mixture of the same fluid and they are both at the same pressure?

Why does $\ce{C3H6}$ gas when compressed (in a centrifugal compressor) comes out with a pressure of $\pu{16 bar}$ and $\pu{90 °C},$ and when it is a mixture of $\ce{C3H6}$ liquid/gas stored inside of ...
pedro vaz's user avatar
4 votes
1 answer
802 views

Vapor pressure vs. ambient pressure

I've managed to get myself thoroughly confused in thinking about the vapor pressure of a substance at a particular temperature $T$, and how it relates to the pressure of the substance if it is in a ...
Michael Seifert's user avatar
-1 votes
2 answers
933 views

Is vapour pressure a surface phenomenon?

As a fact, I know that vapour pressure doesn't depend on surface area. Does this imply it is not a surface phenomenon also? It shouldn't be as then it would depend on surface area of molecules and ...
user226375's user avatar
1 vote
0 answers
2k views

Volume of dried gas at STP

A $54.0\ \mathrm{mL}$ sample of oxygen is collected over water at $20\ \mathrm{^\circ C}$ and $770\ \mathrm{Torr}$ pressure. What is the volume of the dry gas at STP? By using the combined gas law, I ...
user75030's user avatar
2 votes
1 answer
692 views

what is actually supercritical fluid? [duplicate]

let’s take an example: if we have a glove-box filled with helium at 5 bars at room temperature which is far beyond its critical point, what actually it would be like ? would it be like a normal gas ? ...
Johnny's user avatar
  • 29
2 votes
2 answers
4k views

Entropy as the driving force for osmosis

How is entropy responsible for osmosis and is movement of solvent possible from its higher concentration to lower concentration? By concentration, I will be referring to the concentration of solvent ...
Archer's user avatar
  • 5,531
9 votes
4 answers
1k views

Is it true that an evaporating molecule has the same kinetic energy as a molecule in a pot of boiling water?

A molecule on the surface of room-temperature water shoots off the surface of said water, or in other words, it "evaporates." It does so because it gained kinetic energy ${x}$, and ${x}$ was great ...
Isaiah Taylor's user avatar
1 vote
1 answer
129 views

Can air inside a high temperature (1300C) Kiln cause an explosion?

I saw many kiln designs that lack an opening for hot\pressurized air to come out , or any pressure valve. But when air is heated to such a high temperature (1300C) inside a closed chamber (the kiln), ...
soundslikefiziks's user avatar
1 vote
0 answers
103 views

What causes both components of a binary gas mix to condensate at the same time for a given composition

Okay, so recently I encountered the temperature - mole fraction diagrams for binary vapour-liquid equilibrium. For now, I only consider two-component systems where the components are very similar and ...
Venter's user avatar
  • 71
0 votes
4 answers
3k views

Is vapour pressure of a liquid solution constant at a given temperature, no matter the size of closed container and amount of liquid taken?

Does vapour pressure of a liquid solution depend on the size of the closed container, the amount of solution taken, given that, the temperature is kept constant? Or will it change if some extra gas is ...
Prajwal Samal's user avatar
0 votes
1 answer
2k views

Osmotic pressure of a solution of a protein?

A small protein molecule, code-named "sloth", has a MM of $\mathrm{1.50 x 10^4}$ g/mol. What is the osmotic pressure exerted at $\mathrm{24.0^oC}$ by 25.0 mL of an aqueous solution that contains $\...
Eric's user avatar
  • 21
1 vote
1 answer
2k views

Vapor pressure lowering

I have got this problem in my text book, Consider these three mercury manometers. One of them has 1 mL of water placed on top of the mercury, another has 1 mL of a 1 m urea solution placed ...
IAmBlake's user avatar
  • 237
2 votes
1 answer
159 views

Determining the amount of water to create a given pressure in a sealed container

I have a sealed container with a volume of 1 liter. I want to go from an initial pressure of $P_{1}=1\ \mathrm{atm}$ and an initial temperature of $T_{1}=298\ \mathrm{K}$ to a final pressure of $P_{2}=...
EMHA's user avatar
  • 21
1 vote
2 answers
6k views

The effect of pressure on boiling point?

My textbook states the following: Qualitatively, I understand why the boiling point of a substance increases when the pressure is increased. However, I learned that if the pressure is increased when ...
user avatar
3 votes
1 answer
220 views

Control the pressure of Hydrogen in a small container without the use of a pressure regulator

I had recently asked this question, and due to the comments and general consensus of safety concerns, I decided to re-ask the question, attacking the problem from another angle. The Problem I need to ...
Nick Pandolfi's user avatar
0 votes
1 answer
2k views

Vapor Pressure - Sealed Vessel

I have read that vapor pressure is only affected by temperature, but all of the examples have been in a sealed vessel. I have also read that pressure does not affect vapor pressure. I am looking for ...
Robert S's user avatar
  • 109
5 votes
2 answers
4k views

When water boils at its boiling point how do we call it as an equilibrium?

On boiling, water becomes a vapor, liquid volume decreases and vapour volume increases. Since volumes are not constant, how do we call it as equilibrium?
Selvaratnam Lavinan's user avatar
1 vote
0 answers
2k views

Why does melting point depend on external pressure?

The melting point of a substance is the temperature at which the solid form's vapor pressure equals the liquid form's vapor pressure. I read that the vapor pressure of something depends ONLY on the ...
carbenoid's user avatar
  • 2,052
4 votes
1 answer
2k views

Total pressure in a chamber calculation

I have a chamber containing two different gases and a liquid which needs to be heated at a certain temperature to bring it to vapor state. I have worked out that we can calculate the total pressure ...
NidhiS's user avatar
  • 43