Questions tagged [physical-chemistry]

The study of chemical systems using the laws and concepts of physics. This usually requires the techniques of thermodynamics, statistical mechanics and quantum mechanics.

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How to prove it mathematically that either rhombic or the monoclinic sulfur is denser?

For the transition, rhombic sulfur → monoclinic sulfur, the value of $ΔS$ is positive. The transition temperature increases with increase in pressure. Which is denser, the rhombic or the monoclinic ...
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Will mixing hydrogen and oxygen without a spark result in combustion? [duplicate]

I plan to do the electrolysis of dilute sulphuric acid. This will produce hydrogen gas and oxygen gas at the anodes. I do not plan to collect these gases, but to simply let it form and release into ...
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Zero-filling Fourier Transform in NMR [duplicate]

I understand zero-filling increases the resolution of an NMR signal in the frequency domain, but I fail to comprehend how. Why do the artifical points appear between the real points in the frequency ...
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What is the cause of decrease in volume of gaseous mixture in the following problem? [closed]

I am studying Gaseous State. The problem says: A mixture of gas contains $\ce{N2}$ and $\ce{C2H2}$. $\pu{20 \\mL}$ of this mixture is added to $\pu{70\\mL}$ of $\ce{O2}$ and combustion is allowed to ...
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What happens when two galvanic cells are placed in series

I understand how a single galvanic cell works, and the relation of equilibrium and the Nernst equation. But this appears to contradict the higher voltage in a series configuration because it ...
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What is the equation that describes the variation in concentration of an inhibitor in an heterogeneous catalysis?

I find myself in quite a pinch: I have to sustain a Chemical Physics exam, and I know for a fact that the professor often asks this particular question: Suppose that we have both a reacting species ...
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Why is the equilibrium constant unitless?

I read that the equilibrium constant is unitless because the molar activities of each of the species are used in the equilibrium expression, not the actual concentrations themselves. I understand that....
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How to explain Gibbs free energy is a pressure-dependent state function?

I'm aware that through deriving Gibbs free energy to infinitesimal changes, we could get the formula: $\mathrm dG = V\,\mathrm dp - S\,\mathrm dT$, giving that Gibbs free energy is pressure-dependent. ...
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Arrhenius equation using concentration

I've been conducting some experiments to determine the temperature dependence of a reaction. To do this, I've been conducting the experiments at different temperatures and generated a graph of \$\ln{[\...