# Questions tagged [physical-chemistry]

The study of chemical systems using the laws and concepts of physics. This usually requires the techniques of thermodynamics, statistical mechanics and quantum mechanics.

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### Relationship between Gibbs free energy and potential energy (related to reaction coordinate diagrams)

For a rate law, the rate constant $k$ is given by the equation $$\ln k = \ln A - \frac{E_\mathrm{a}}{RT}\tag{1}$$ If $k_\mathrm{fwd}$ is the forward rate constant and $k_\mathrm{rev}$ is the reverse ...
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### Is the cathode and anode on the cell notation of an Electrolytic cell on the same side as if how you will write it for a Galvanic cell?

I was reading an online material then I came upon a cell notation for an electrolytic cell (I determined that it was an electrolytic cell because of the absence of a salt bridge). Usually, I will ...
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### How can I calculate for the theoritical potential needed to precipitate a metal in an electrolytic cell?

We were given a problem where we are to calculate the theoretical potential needed to initiate the deposition of $\ce{Cu^2+}$ in a solution buffered to $\mathrm{pH} = 4.00$ and the IR drop associated ...
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### Long term composition of matter [closed]

If I have an igneous rock shown by geologic study to be 10,000 years old, approximately what percentage of the atoms (or protons, etc) in the rock might be the same ones that were in it 10,000 years ...
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### Cathode ray discharge tube

I am learning about 'cathode ray discharge tube'. I know when electrons are given out from cathode, they travel to anode, because anode being positively charged attract those electrons and continue to ...
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### Book reference for chemical equilibriums [duplicate]

I need to practice more chemistry equilibrium questions but most of the books contain only theory parts and not enough questions. so can please recommend me a question book.
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### How do I determine molality from mole fraction without knowing how much of the solution I have?

What is the value of $x$ if $x$ molal solution of a compound in benzene has a mole fraction of solute equal to 0.2? I tried calculating the moles of $x$ through the value given but there are two ...
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### Does exotic potassium exist?

I was reading a book called 'Hundred and Seven Stories of Chemistry'. There is a chapter about how the attributes of different elements can change in presence of enormous pressure and temperature. ...
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### Relationship Atmospheric Gases and Ocean Gases [closed]

If this question is better suited for the Earth Science StackExchange or another StackExchange please let me know. Edit 1: Modified for clarity and brevity. Something that's unclear to me is the ...
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### Can precipitation reactions attain equilibrium?

While studying about the characteristics of Chemical Equilibrium, I came across a point in my book which read A chemical equilibrium can be established only if none of the products is allowed to ...
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### What are the magnetic quantum numbers for the three real p orbitals?

The form of the p orbitals that we are familiar with are the $\mathrm{p}_x$, $\mathrm{p}_y$, and $\mathrm{p}_z$ orbitals: (source: ChemTube 3D) I also know that the p subshells have the quantum ...
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### Catalyzing the breakdown of Si-O bonds

What catalysts can catalyze the breakdown of (Si-O) bond ? Can you mention some books(ebooks or hard cover) or websites that cover a lot of information about (Si-O) bond characteristics? I have ...
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### Why do we use Ḡ (“G bar”) as a notation for partial molar free energy?

For partial molar entropy there is a bar that is positioned above the $G$ with a subscript I that is sometimes added to the $G~(\bar{G}).$ The bar I read sometimes denote the "partial nature of the $G$...
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### Determine the velocity of the O fragment after the dissociation

A $\ce{SO3}$ molecule is radiated with light with a wavelength of $\pu{193 nm}$, which results in photodissociation. $\ce{SO3} + \text{photon}(\lambda=\pu{193nm})\ce{-> SO2 + O}$ It is ...
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### Does the speed of an ion affect the current that can flow through a solution?

Typically, when a cathode and anode are inserted into a solution that allows current to flow, the ions are moving with a certain kinetic energy. If the ions were to gain kinetic energy (through ...