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2 votes
0 answers
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How do the spin-matrices change in systems without spherical symmetry?

The (non-relativistic) spin matrices of a free electron, with $z$ as the quantization axis, read: $$ \boldsymbol{S}_{x}=\frac{\hbar}{2}\left[\begin{array}{ll} 0 & 1 \\ 1 & 0 \end{array}\right],...
Logi's user avatar
  • 181
5 votes
1 answer
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Does Bent's Rule only apply to molecules where there is hybridisation?

I would just like to ask if the pre-requisite for using Bent's Rule is that the bonding in the molecule involves hybridised orbitals. I was thinking of why the bond angle in hydrogen sulfide (~ 92 ...
Tan Yong Boon's user avatar