Questions tagged [metallurgy]

Chemical and physical characteristics of metals and alloys.

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25 views

Which fluorescence indicators can differentiate between the usual surface of steel and the different kinds of its impurities?

Corrosion sensing with fluorescence indicators (metal indicators, pH-indicators, redox indicators) is already known. But which fluorescence dyes (fluorescence indicators) can differentiate between the ...
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1answer
157 views

Why are rare earth metals and platinum group metals are often found clustered together in ores

Rare earth and platinum group metals are often found clustered together in the earth's crust. Mining for platinum, for instance, also yields Rhodium and Ruthenium belonging to the same group. Likewise,...
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Gold CIL/CIP Leach Circuit

Could anyone explain why the adsorption tanks are being fed twice, with one input from the top of the tank (Strong and weak slurry), while also another input from the bottom (Fresh Carbon). Why does ...
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1answer
47 views

Roasting of galena

In the metallurgy of $\ce{Pb}$, Galena is first concentrated by froth floatation process. It is then partially roasted to and self reduced to obtain $\ce{Pb}$. Why is galena only partially roasted(...
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34 views

Calculating change in Gibbs Free Energy for a specific type of problem

Can anyone describe what is going on here? $$Si(liq.)=Si_{(1 weight percentFe)}$$ I have come across this statement quite a few times in Metallurgical Thermodynamics.All that they ask for is change in ...
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1answer
42 views

Properties of inconel [closed]

I am doing a project on the physics of the spaceX raptor engine. I believe it is made out of a certain type of inconel alloy. I want to understand why this alloy has the properties that it does, but I ...
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2answers
321 views

How to refine manganese metal from manganese(IV) oxide found in batteries? [closed]

I opened up some lantern batteries, and inside there's $\ce{MnO2}$ powder, carbon rods, and zinc casings, and other stuff that I don't know what it is exactly. I scraped out $\ce{MnO2}$-containing ...
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1answer
77 views

Thinking of reducing aluminum hydroxide with magnesium

Is it possible to reduce aluminum hydroxide to aluminum metal by using a sacrificial magnesium electrode in a single displacement reaction? I checked my revision of redox charts and it looks like it ...
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1answer
90 views

Origin of the 15% difference limit between solute and solvent atom radii in the Hume-Rothery rules

According to the Hume-Rothery rules for the substitutional solid solutions the atomic sizes of the the solute and solvent must not differ by more than 15%. Why should it be so?
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1answer
54 views

Are there any sulfides, sulfates, carbonates that cannot be dissolved by aqua regia? [closed]

I was looking into these specific minerals: arsenopyrite, pyrite, chalcopyrite, barite, calcite, dolomite. I investigate issues with tellurides not showing expected gold concentrations.
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34 views

Are Alloy Compositions Given in Weight Percent or Atom Percent

Often times I see alloys described like this, Lockalloy is an alloy that consists of 62% beryllium and 38% aluminum Are the precentages mentioned here in weight percent or atom percent? Is there a ...
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2answers
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Thermal properties of aluminium alloy 6063 [closed]

I am looking for the operating temperature range both in a cold and hot environments (minimum and maximum operating temperatures) for aluminium alloy 6063. I'm new to finding this kind of information ...
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1answer
31 views

Can a metal which contains impurity of another metal that is more reactive than itself be electrorefined?

So I know that cathode is made of pure metal and anode of impure. For example take Cu. Cu will be oxidised to Cu+2 at anode and will deposit at cathode. But now if it contains impurity of , let's say, ...
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1answer
86 views

What's the difference between Zinc Ascorbate and Zinc Gluconate?

I've been looking at a dental product for pets, called MAXI/GUARD Oral Cleansing Gel and it states it uses zinc ascorbate/taurine, however in the ingredients I found elsewhere it instead lists zinc ...
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1answer
35 views

Manufacture an artifact with compression

Room-temperature superconductivity has finally been demonstrated, as reported by Quanta (and others), with the caveat that it requires compression of the substrate at nearly 2 Mbar. Obviously, this ...
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1answer
46 views

Why is there carbon lining on the steel vessel in Hall Heroults process?

I read This answer, and completely understand that why graphite anode is used , but I have read that the vessel acts as the steel cathode but with lining of carbon. What is the need of this carbon ...
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1answer
78 views

What explains the case hardening color effect?

Year 11 chemistry student here. I'm curious about how the case hardening effect works on metals. I know that when the electrons gain an energy 'level' or lose an energy 'level' they emit light at ...
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2answers
92 views

What lab equipment did Marie Curie use to isolate radium?

My experience in growing crystals for condensed matter physics has been sealing grams of material in ampoules which get heated in laboratory furnaces, so I don't have the experience to understand how ...
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1answer
285 views

How does liquid gallium interact with a gold leaf

I would like to know what happens when gold leaf comes into contact with liquid gallium. Will the gold dissolve into (alloy with) the gallium, wet the gallium or have no reaction with gallium? The ...
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52 views

What is the minimum thickness for stainless steel crucible to melt aluminum

I am planning to make a stainless steel crucible (air-tight) to melt aluminum. Aluminum is known to oxidize in presence of air. I therefore want to create a custom crucible made with sheet metal ...
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1answer
44 views

Home foundry — melting aluminum, mitigating undesirables

I am going to be melting aluminum cylinder head and some soda cans in the home foundry. I am aware the sulphur and the hydrogen present in the melt can make aluminum prone to cracks and brittle. Are ...
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67 views

Is melting aluminium in the presence of carbon dioxide desirable?

So aluminium cans melting is prone to formation of aluminium oxide due to presence of oxgygen and thin sheet of aluminium (large surface area). To mitigate this I can design a cruicible which is ...
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2answers
213 views

Why does an mercury ore exist as HgS?

Cinnabar($\ce{HgS}$) is one of the most common ores of mercury. Why does it not exist at $\ce{HgO}$ or some other such compound? Is there any reason for why it is so prevalent? Does it react less ...
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1answer
38 views

Side product obtained in reduction of cuprous oxide with carbon

So my book sates that in the extraction of cuprous oxide, the following reaction takes place. $$\ce{Cu2O + C -> 2 Cu + CO}$$ This makes sense to me, if it is seen as the following two reactions ...
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21 views

Can metal matrix composites be alloyed after their creation?

I've done a little research on metal matrix composites (MMCs), purely for fun and out of interest. Different types of metal powders are combined with reinforcement materials, to produce a reinforced ...
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Why does 'softening' of lead oxidise only elements other than lead?

In a flowchart describing the steps to refine lead obtained after the reduction step, my book1 gives a short note on the process 'Softening of lead' where the crude lead is melted in the presence of ...
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1answer
67 views

How many kilograms of graphite are consumed while producing 4 kg of Al through Hall-Heroult process?

How many kilograms of graphite are consumed while producing 4 kg of $\ce{Al}$ through Hall-Heroult process? This looks like a simple stoichiometry problem: $$\ce{4Al^3+ + 12e- -> 4Al} \; \; \; \; \...
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How can a minor constituent of an alloy, like carbon in steel have such a profound effect? [closed]

In steel that is 0.65% carbon by weight, barely one in 34 atoms is carbon (assuming no other additives/impurities). How can such an outnumbered constituent make such a big difference? Surely many of ...
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56 views

Are platinum metal whiskers very unusual?

Over 20 years ago I pulled my first set of platinum spark plugs out of a car because the engine was missing badly. Two of the six plugs each had one whisker in the gap between electrodes. One crossed ...
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1answer
437 views

Electrolytic Refining of Silver Nitrate

I read that the electrolytic refining of Silver is done using dilute silver nitrate as an electrolyte and a small percentage of free $\ce{HNO3}$. The following reactions are possible at the anode: $$\...
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1answer
71 views

What is the naming convention for Sn and Pb in inter-metallic compounds?

How would one go about naming inter-metallic (specifically, transition post-transition) compounds containing tin and lead? It is usually easy figuring out the naming of such compounds as they follow ...
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2answers
335 views

Why is Na+ reduced instead of H+ in the electrolysis of dilute NaCl(aq) with Mercury cathode?

In a class of electrolysis, my instructor told me that Hg forms Na-Hg in the electrolysis of dilute NaCl aqueous solution. For this reason, sodium cations are reduced in the cathode instead of ...
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819 views

Fumes by Melting Aluminium Soda Cans [closed]

I am planning to melt and cast aluminium from soda cans. I went to quora page that deals with "burning" aluminium can, which can release toxic gases as the cans are coated with plastic inner lining. ...
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1answer
63 views

What makes metals malleable and ductile? [closed]

Two well-known Physical Properties of metals is that they are malleable and dutile I was just wondering about what causes metals to be malleable and/or ductile and non-metals to be brittle? What ...
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1answer
30 views

Reactions of Depressants

In the froth flotation process, the concentration of a sulphide ore takes place using $\ce{NaCN/KCN}$ as a depressant. It forms a soluble complex with the impurity sulphide. Taking the particular ...
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56 views

Difference between calcination, roasting and pyrolysis

Hie everyone. I have been going through pyrometallurgical processes for recycling lithium-ion batteries and l have been coming across these terms; calcination, pyrolysis and roasting which l need ...
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151 views

Why does copper oxidise if it is considered a “noble metal”?

I'm an electrical engineer and not a chemist, so please excuse me if this is obvious. When soft-soldering electronic parts, we’re normally taught to clean copper of oxides (like using flux and so on) ...
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3answers
9k views

Why isn't the American nickel magnetic?

I never thought that modern American nickels actually contained nickel anymore. However, according to this wiki article, the coins actually do contain 25% nickel, the rest being copper. And yet, no US ...
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Importance of concentration of gold in gold parting

I read following lines about gold parting: Gold is not attacked by $\ce{H2SO4}$ or $\ce{HNO3}$, but copper and silver dissolve in them, when concentration of gold is less than $30\%$. If however, ...
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1answer
95 views

Use of Spiegeleisen in manufacture of steel

I recently read the following statements related to Manufacture of steel via Bessemer Process: When no more $\ce{CO}$ is produced (i.e. blue flame disappears) a calculated amount of Spiegeleisen (...
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1answer
39 views

Could metal hydride storage tanks for hydrogen store helium as well, given their repective atomic radii? [closed]

With atomic radii very similar, could helium dissolve into metallic foam about as well as hydrogen, thus making metal hydrite hydrogen tanks suitable for helium as well?
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In pig iron, from where does carbon in it comes from?

I've read that: "During extraction of iron another impurity appear which is carbon from coke in furnace." However, I don't understand how there will be enough unreacted carbon that would blend ...
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1answer
56 views

Should I be concerned about a galvanic reaction between silver solder and stainless steel?

I would like to solder a drain fitting onto my ultrasonic cleaner's tank. The fitting and the tank are both stainless steel. During its operation, the tank is filled with a cleaning solution and heat ...
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2answers
724 views

What does it mean to 'fuse' ores and why do we use alkali metals in the process?

For the extraction of chromium, fusion of chromite ore with sodium or potassium carbonate in excess of air is done. What exactly happens in this 'fusion' process? According to my textbook (class XII ...
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3answers
652 views

What is Rinman's green used for? [closed]

I can't find any info about it's uses neither in book nor in internet. Any help would be appreciated.
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3answers
170 views

How can Ellingham diagrams be linked to Gibbs energies of formation?

My textbook1 quotes the following as the limitation of Ellingham diagram: The interpretation of $\Delta G_\mathrm{f}^\circ$(standard Gibbs free energy of formation) is based on $K$ ($\Delta G_\...
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1answer
28 views

Difference between a species and a phase in a solution? [closed]

Overview: As of my knowledge from metallurgical thermodynamics a phase is a thermodynamically stable and homogeneous entity made up of different species of a given concentration. e.g = 'Austenite' ...
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Zinc Ink Availability [closed]

does anyone know where I could purchase zinc ink? Sigma Aldrich only sell Zinc Oxide, and I'm struggling to find a method in which I could remove the oxide after I print onto a polymer substrate. ...
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How does sodium borate (Borax) function to promote Fe-Fe bonding?

Borax is used as "flux" during metal forging to help stick two pieces of steel together. I am curious what is happening at the atomic level. How does the addition of borax promote Fe-Fe bond formation?...
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How do carbon content and various heat treatment cycles affect the properties of steel at the micro-level?

I watch a YouTube channel by Alec Steele where a lot of metal forging is done. From this I know that varying the carbon content in steel drastically alters the physical properties of the metal, as ...

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