Questions tagged [ionic-compounds]

Compounds in which at least some of bonds have ionic character stronger than covalent or metallic. Many compounds called salts are ionic compounds but not all of them.

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Identity of an element A, which form an oxide A2O when reacts with oxygen [closed]

An element $\ce{A}$ reacts with oxygen to give an oxide $\ce{A2O}$. The oxide $\ce{A2O}$ is electrically conducting. The valency of $\ce{A}$ is clearly 1, and it reacts with halogens and ...
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Produce CuCl2 from CuSO4

I have a large amount of copper sulfate available and I am interested in obtaining copper chloride from it. What is the easiest way to do so? I have considered mixing an aqueous solution of copper ...
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Why are alkali metal compounds like sodium hydride or sodium amide strong bases but weak nucleophiles?

I understand why compounds such as $\ce{NaH}$ or $\ce{NaNH2}$ are weak nucleophiles: as they aren't very soluble in organic solvents, they react only on the clusters' surface. But why are they strong ...
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Does the salinity in seawater affect the process of alkaline hydrolysis?

I am an architecture student doing a project on crematorium spaces. I am looking at resomation or alkaline hydrolysis as an alternative method of disposition of a body. From what I gather from ...
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300 views

Why does covalent nature in ionic solids increase the lattice energy?

I have observed in my textbooks that ionic solid that have a greater covalent character tend to have higher lattice energy. Can this be generalised as fact?
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Is beryllium difluoride covalent or ionic?

My textbook says that despite the large electronegativity difference $\ce{BeF2}$ is covalent since the beryllium ion will have too much charge density and it will attract the fluorine electron cloud ...
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Why do different elements form different types of carbides?

What property of the elements make them form different types of carbides like: $\ce{Be}$ and $\ce{Al}$ - $\ce{Be2C}$ and $\ce{Al4C3}$ (Methanides) contains $\ce{C^4-}$ ion $\ce{Na}$ and $\ce{Ca}$ - $...
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Degree of dissociation of weak electrolyte at infinite dilution

Why the degree of dissociation of weak electrolyte is 1 at infinite dilution and how do we get the result? Like I know that at infinite dilution the concentration of solution is 0 but what does that ...
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Clarifying question about chloride ions, water softening & corrosion

I have a question regarding the use of NaCl as a water softener. Recently i was asked to comment on a series of test results from a water softening device were a lot of corrosion had occurred post ...
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What does higher electron gain enthalpy mean here?

While talking about ionic bonds my book states : Higher the value of electron gain enthalpy of the atom, greater the ease of formation of the anion from it, i.e., other atom should have high value ...
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X-ray bombardment of CaCl2 and its resultant chemical changes

If one were to take $\pu{1 mol}$ of pure liquid Calcium Chloride (at $\pu{600 ^\circ C}$) and bombard it with $\pu{7.65 \times 10^{14} Ci}$ ($\pu{2.83 \times 10^25 particles}$) of x-rays ($\pu{75 keV}$...
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The “nose” of the periodic table [closed]

My teacher said that on the periodic table there is a "nose" formed by Al, Zn, Ag, and Cd. She said that they are all fixed charged (+3, +2, +1, and +2 respectively), and said that if I write them in ...
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Why do non-polar covalent compounds dissolve in non-polar covalent compounds only?

My textbook says that electrovalent and polar covalent compounds dissolve in electrovalent compounds and polar covalent compounds but not in non-polar covalent compounds. I understand the reason for ...
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What is dielectric constant and how does it explain the reason why water is one of the best solvents

When i was reading solublity of ionic compounds,they mentioned that polar compunds are fairly soluble in polar solvents and water is better solvent due its high dielectric constant.Can anybody explain ...
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Calculating the Ionic strength of sodium acetylsalicylate

With the addition of aqueous NaOH to an aspirin solutions in water the reaction will yield products of sodium acetylsalicylate and water. I would like to measure the amount of sodium apsirin formed ...
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Why does adding salt to water reduce the pH?

I recently heard someone claim that adding table salt to vinegar caused HCl to form which helped them clean coins - clearly not the case - however I thought I'd disprove it by doing an experiment. So ...
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Feasibility of using ionic liquid fuels in an MHD type reactor

First off I would like to say that my knowledge on chemistry, even general chemistry, is basic if not poor. That said, I have some intuituions on this matter. I haven´t found any paper regarding ...
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Measurement of the lattice energy

The lattice energy of a solid ionic compound is the energy released when one mole of the solid compound is formed from its constituent gaseous ions at $\ce {298 K}$ and $\ce {1 bar}$. However, gaseous ...
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The impossibility of 100% ionic bond

Recently, I read the definition of oxidation state on Wikipedia. It read that a 100% ionic bond is impossible. So what does a 75% ionic and 25% covalent bond mean at all?
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Is KF the most ionic compound?

I saw somewhere (can't recall where) that KF is the most ionic compound. I expected CsF. Does the greater polarizability of Cs allow it to more easily form covalent bonds compared to K? Does this ...
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Determining which compound is more 'ionic'

I was going through my chemistry textbook (IB Pearson), and it explicitly stated that the higher the absolute difference between the electronegativity of elements in a binary compound, the more 'ionic'...
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Why does moving from left to right on the periodic table result in higher conductivity?

Question is in the title. I understand that the metals towards the left form stronger bonds with other chemicals compared to metals towards the right, and that the ones with weaker bonds break down ...
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Is it possible to burn things in a halogen atmosphere?

Fires can burn in oxygen. But, can they burn in halogen atmospheres (fluorine and chlorine only)? I am wondering this because combustion reactions involve oxygen and carbon and other elements. But, ...
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Sulfate and carbonate ions as ligands

The pentahydrate salt of copper (II) sulfate exists as a blue solid while the anhydrous and monohydrate salts appear as white solids. The structures of these salts are discussed here. The blue colour ...
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Why is the product of the reaction “Bi + O2” Bi2O3 instead of Bi2O5?

I am stuck on a homework question that states: A piece of solid bismuth is heated strongly in oxygen. The answer key states the answer as $\ce{Bi + O2 → Bi2O3}$. However, it is to my understanding ...
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Calculating valence of oxides

Learning about Oxides. Basically when oxygen is combined with a metal. $$\ce{FeO}$$ This is called "Iron Oxide (II)" according to my book. Apparently, the II represents the valence. But how come? ...
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How to measure saturated salinity and mineral levels for flaked sea salt?

I am a sea salt enthusiast looking to make the perfect flakey sea salt. I start with sea water and boil it down to a thick brine. Then with less heat I reduce the brine more slowly and inverted salt ...
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Lattice Energy of MX2 type

While finding the solution to the question that which among BaO and BaCl2 has hi that is energy I found that it was BaO whose lattice energy is high and there were explaining it just with charges. So ...
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Are all NO3- salts soluble in water? If so, why?

All the examples of $\ce{NO3-}$ salts are soluble in water (all that I know about). Is it always so or there is some salt which doesn't dissolve in water? If so what is the reason behind it?
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Why does magnesium oxide not react with water?

There is a question in my textbook which asks "which of the reactions are not possible to occur". The right answer is $\ce{MgO + H2O}$ and my chemistry teacher confirmed it. Why is that so? I thought ...
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How many valence electrons does the azide ion have?

We had a test and and we had a question asking the number of valence electrons in an azide ion, $\ce{N3^{-}}$. I find out that the answer is 16 but I could not understand how. I saw the structure. ...
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What is the structural formula of alkali hypohalite: MOX or MXO?

Recently I came across this question and in the comment section, there was an argument regarding the formula of sodium hypoiodite which kept me wandering: what is the actual formula of alkali ...
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Why don't ionic compounds show stereoisomerism?

When I was reading about crystalline nature of ionic compounds, I came across the statement that ionic compound doesn't show stereoisomerism. What does that mean and can anybody explain the reason ...
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Which has a greater dominance: hydration enthalpy or lattice energy?

When I was reading my notes I came up with a problem. I read that for the s block element salts, when checking the solubility, we consider the hydration enthalpy so we decide their stability in water. ...
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In the Lewis structure for barium fluoride, why does barium lose its valence electrons?

I searched for $\ce{BaF2}$ Lewis structure, and found out that the Barium atom loses its 2 valence electrons to form $\ce{F- Ba^2+F-}$. Before seeing it I thought each of $\ce{Ba}$'s valence ...
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Why is there no effective alternative to metal salts in antiperspirants?

Metal salts, especially aluminum compounds are used in antiperspirants to prevent sweating. I found out aluminum chloride hexahydrate, which is found in most antiperspirants, undergoes an acid-base ...
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How to determine the conductivity of different chemical compounds?

I am doing an experiment that involves testing the conductivity of three different chemical compounds dissolved in water. I will be testing Potassium Chloride, Calcium Chloride and Zinc Chloride. All ...
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Is calcium chloride an acidic or basic salt?

What I reason: Calcium chloride is the salt of hydrochloric acid and calcium hydroxide. Calcium hydroxide is usually not considered a strong base, and I believe this is because of it's low solubility. ...
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How is Al2Cl6 covalent and Al2O3 ionic?

I encountered a question where the type of bonding for various oxides are prompted. Two of which are $\ce{Al2Cl6}$ and $\ce{Al2O3}$. I thought that chlorine atoms are more electronegative than oxygen ...
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Can I make an ionic liquid from glycerin and zinc sulfate?

Can I make an ionic liquid (dissolved salt without water) by combining zinc sulfate and glycerin? I've been using 1 M $\ce{ZnSO4}$ as my electrolyte in supercapacitor study. Works very well up to ...
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Calculating the strength of an ionic bond that contains poly-atomic ions

So the bond association enthalpy for ionic compounds like $\ce{NaCl}$ and $\ce{NaBr}$ can be easily calculated from a Born-Haber cycle. But the way a Born-Haber cycle is constructed it uses info that ...
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What happens when an ionic compound is boiled? [duplicate]

Do ionic compounds such as NaCl become individual ions such as one Na ion and one Cl ion or are they hold together by ionic bonds even when they are boiled. Thanks in advance.
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Why does Coca-Cola Zero Sugar Contain Sodium Despite no Sodium Ingredients?

According to the Coca-Cola website and every label I read, Coca-Cola Zero Sugar is a mixture of organic compounds: CARBONATED WATER (OC(OH)₂), CARAMEL COLOR (Various sugars), PHOSPHORIC ACID (H₃PO₄...
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Why is the melting point of magnesium oxide higher than aluminium oxide?

There's a graph of the melting points of period three oxides. The melting point of magnesium oxide is several hundred Kelvin higher than aluminiumoxide. I can't find any explanations for this on the ...
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Unknown salt formed from electrolysis of urine

I am not sure what I was expecting to happen with this but I created a circuit to electrolyze various household liquids. My electrodes are copper — or at least claim to be, I think they might just be ...
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Why is Lithium Chloride (LiCl) soluble in alcohols?

According do J.D. Lee's Concise Inorganic Chemistry, LiCl is soluble in alcohols because it has some covalent nature, althought it is mainly polar. Why would LiCl have covalent character? Why doesn't ...
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Alkali and alkali earth metal carbonates and bicarbonates decomposition

Which of the following can not decompose on heating to give $\ce{CO_2}$? $\ce{Li_2CO_3}$ $\ce{Na_2CO_3}$ $\ce{KHCO_3}$ $\ce{BaCO_3}$ What I have read till now: Lithium carbonate ...
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Ionic equilibrium between multiple ions

This is a question from IIT-JEE 1993: For the reaction $$\ce{[Ag(CN)2]^- -> Ag^+ + 2CN^-}$$ the equilibrium constant at $\pu{298 K}$ is $\pu{4e-10}$. The silver ion concentration in a ...
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Gap in ionic radii

The above picture was shown in a presentation by my prof in inorganic chem as we were discussing ionic radii more in depth (all in pm). These are all isoelectronic radii. Notice the sudden leap in ...
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Which has higher lattice energy: MgO or LiF?

Which has higher lattice energy: MgO or LiF ? A compound has higher lattice energy if it's ions have smaller size and greater charge Li cation is smaller than Mg cation => +1 for (LiF) Fluoride ...