Questions tagged [inorganic-chemistry]

Inorganic compounds generally do not have C-H bonds, while organic compounds do have such bonds. The distinction between inorganic and organic chemistry, however, is far from absolute.

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An unknown glassware piece from our cupboard

We have multiple of these. It is a small glass funnel with splits into 3 spouts from it. Now, we are thinking it might be similar to a cow receiver, however, I have never seen one this small or ...
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Unknown possibly handmade glassware- description in information below

Okay, Another random item from the cupboard (unknown users or discipline of life sciences unknown) could be anything up to 40 years old.... This appears to be a 2 neck quickfit adapter (B19 and B14) ...
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Solubility of PbSO4

The solubility of $\ce{PbSO4(s)}$ increase with the addition of $\ce{H2SO4}.$ Why? I don't quite understand this. When dissolving $\ce{PbSO4(s)}$ we get the equilibrium equation: $$\ce{PbSO4(s) <=...
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Changing of UV-Vis peak absorption after heating Ni(en)2(NO2)2

(c) The trans-isomer of $\ce{Ni(en)2(NO2)2}$ D is red $(λ_\mathrm{max} = \pu{500 nm}).$ It can be heated to give a new trans-isomer E, which is violet $(λ_\mathrm{max} = \pu{560 nm}).$ Assume that, ...
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Gap in ionic radii

The above picture was shown in a presentation by my prof in inorganic chem as we were discussing ionic radii more in depth (all in pm). These are all isoelectronic radii. Notice the sudden leap in ...
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Analytics of a paramagnetic complexes

I am working with salophene iron[III] complexes. Unfortunately, my 5th ligand cannot be determined via MS. I performed a 1H-NMR in methanol, but it's not a suitable method for a paramagnetic compound. ...
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539 views

Why is gunpowder urinated on in Blood Meridian?

An interesting section of Blood Meridian (1985) by Cormac McCarthy has the gang of "Indian fighters" surrounded and out of powder, so one of them manages to make it from scratch, making charcoal from ...
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498 views

Help understanding the pi-properties of the NCS- ligand

Course knowledge When considering the NCS- ion, I take all atoms to be sp hybridized. This means that there are 8 electrons that are accommodated in the $\pi$-system. There are two orthogonal 3-...
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816 views

Considering the d-d transition how, does tetracyanidonickelate(II) ion exist as a colored complex?

As I refer on google, the resources indicated that, the d block elements which have unpaired electrons as in their ions, when they are making complexes with ligands, they can absorb different ...
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274 views

What's the hybridization in diphosphorus molecule?

I read that diphosphorus has 2 phosphorus atoms joined by a triple bond (ie) it has one sigma bond and 2 pi bonds with 2 lone pairs ( 1 lone pair on each atom). I'm confused about the hybridization of ...
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Which reagents can directly oxidize ammonium ion into gaseous dinitrogen?

I have a simple question. I've looked on the internet and the only thing I found was the Anammox process - Anaerobic Ammonium Oxidation. Wikipedia lists the reaction as: $$\ce{NH4+} +\ce{NO2-}\...
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Sense of radii quotient to determine coordination number in crystals?

Every common textbook explains the method of the radii quotient between the cation and anion of a selected salt to determine to coordination number(s) in that salt. For example deduce "Inorganic ...
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Effect of temperature and pressure on structure of solids

What is the effect of these conditions on the structure of solids? My book has the answer that confuses me. I got nothing about it. Can you please explain? The answer of the book is With the ...
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Can someone help me finish this reaction?

This question revolves around sodium percarbonate (https://en.m.wikipedia.org/wiki/Sodium_percarbonate) and its reaction with sulfuric acid. I didn't find anything, so I tried assembling it myself. ...
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Briggs-Rauscher numerical model

I want to use the Briggs-Rauscher experiment to demonstrate oscillating reactions, and then explain it using a numerical model. How much is known about this reaction? Is it possible to write down a ...
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What will happen if ligand orientation is changed?

How we came to know ligand should approach from t2g orbitals in d5 configuration for tetrahedral complexes? What will be the difference in energy if ligand approach from eg? As far as I can think, ...
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Can the decompistion of one carbonate inhibt the decomposition of another carbonate?

If two different carbonates of Group II, are mixed in equal amounts and then heated could one of the carbonates decomposition inhibt the other ones decomposition? I don't understand how it would ...
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Trends in pi backbonding for main group elements across a period

Recently, I have been re-reading some undergraduate notes and found that there's a period trend in pi backbonding of main group elements (i.e. no transition metals involved) but no explanation were ...
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908 views

Can two solids form in a double displacement reaction?

I am trying to react silver flouride with magnesium chloride. I know it is a double displacement reaction but so far the equation I have gotten is: $$\ce{2AgF (aq) + MgCl2 (aq) -> MgF2 (s) + 2AgCl ...
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Shape of nickel tetracarbonyl

Is nickel tetracarbonyl a square planar complex or a tetrahedral complex? According to the crystal field theory, $\ce{CO}$ is a strong field ligand and should hence cause the $t_{2g}$ electrons of ...
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Can pure elements have different colors?

This question was inspired by this: Are there colorful metals besides gold and copper? I was wondering how the color of a pure element could be changed. I know that it is possible for color to change ...
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How to compare the oxidizing power of perhalate ions

In my book the oxidizing power in descending order of the following is given as: $\ce{BrO4-} > \ce{IO4-} > \ce{ClO4-}$ My doubt is regarding their order of oxidizing tendency. I thought that ...
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Bond angle order of SF2, OF2, HOF

Arrange the following componds in the increasing order of bond angle. $$\ce{HOF,~OF2,~SF2}$$ I know that bond angle of $\ce{SF2}$ will be less than the bond angle of $\ce{OF2}$ because of larger ...
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Theoretical temperature change in lime hydration

Calcium oxide (quicklime) and water have an exothermic reaction $\ce{CaO + H2O \rightarrow Ca(OH)_2} \quad \quad \Delta H^{\circ}_f=-65.3 \; \mathrm{kJ \cdot mol^{-1}}$ Assume that I have 1 kg of ...
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Comparing two oxidizing agents using electron configuration

Which oxidizing agent from the pair $\ce{K_2IrCl_6/K_2PtCl_6}$ is stronger? Explain your answer using their electron configurations. We write the electron configurations for $\ce{Ir/Ir^{4+}}$ and $\...
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239 views

What are the chemical similarities between gallium and barium?

I am analyzing nutrient concentrations in wood, and I have found that in all my samples the distribution of gallium and barium are closely related. As a related phenomenon, the presence of these ...
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998 views

What type of bonding is present in lithium tetrahydridoaluminate?

I can tell that the negative ion has one bond which is a co-ordinate/dative covalent bond. However, overall, would you say that lithium tetrahydridoaluminate (lithium aluminium hydride) is ionic? If ...
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847 views

What happens when two nitrates react with each other?

I have to determine the products of the ammonium nitrate and copper nitrate. Is the below reaction correct? $$\ce{NH4NO3 + Cu(NO3)2 -> Cu(NH3)4(NO3)2}$$ (ammonium nitrate + copper nitrate → ...
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Ratio of rate of diffusion of two gases under constant temperature and pressure

I'm consulting one of higher classes books to study chemistry. I had been studying Graham's Law and question related to rate of diffusion. I came across a question[1] which says: Calculate the ...
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Grease & Thermal resistant cardboard for the foods industry?

I am on the lookout for, preferably, a cardboard (ish), that is both heat & grease resistant, for usage in microwave popcorn. As such, the material must be appropriate for direct contact with food....
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Titanium in HF vs HCl

So we tried the reaction between Titanium metal with hydrochloric acid and hydrofluoric acid at a similar concentration. While boiling temperatures and constant heat over a long period of time are ...
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4k views

What are examples of group 14 elements forming dπ - pπ bonding?

While studying the Group 14 elements, I came across the anomalous behaviour of carbon. In that there was a point: Carbon forms only p$\pi$-p$\pi$ type bonding while other elements in the group form ...
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Why is the Si-F bond one of the strongest single covalent bonds of them all?

I honestly have no clue where to begin explaining why the Si-F bond is one of the strongest single covalent bonds of them all. I would actually predict the bond to be relatively weak on account of ...
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Acidity comparison on R-PO3H2

Question Compare the acidity $(K_\mathrm{a1})$ of the following three acids: $\ce{H3PO4},$ $\ce{Ph-PO(OH)2}$ and $\ce{H3C-PO(OH)2}.$ Thoughts These three acids are of type $\ce{R-PO3H2},$ where ...
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Why is NOₓ conversion low at fuel rich conditions in a three-way catalytic converter?

$$ \begin{align} &\text{Oxidation:} &\quad \ce{2 CO + O2 &-> 2 CO2}\\ & & \ce{``HC" + O2 &-> CO2 + H2O}\\ & & & \\ &\text{Reduction:} &\quad \ce{2 CO +...
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Energy level of molecular orbitals in heteronuclear diatomic compounds

I have been studying the molecular orbital theorem. I read that the energy levels for the $\ce{p}$ orbitals in the first series of $\ce{p}$ block molecules are something to the tune of $$\pi_x=\pi_y&...
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Are Slater’s rule and lanthanide contraction contradictory?

According to most textbook and the Wikipedia page of lanthanide contraction, the phenomenon is due to poor shielding of nuclear charge by 4f electrons. However, the σ value of 4f electrons to 6s is 1....
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Why doesn't the Pilling-Bedworth ratio of silicon cause issues in silicon technology?

According to Wikipedia, silicon has a Pilling-Bedworth ratio of 2.15. In theory this should mean an SiO2 film on silicon should have a fairly large amount of compressive stress and high probability of ...
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Synthetic approach for precursor 1,1'-(bromomethylene)bis(1H-pyrazole) in ligand synthesis

Relevance During my Bachelor's project I focused on the synthesis of iron(II) complexes comprising a tetrapodal pentadentate ligand from the ligand family $\text{PY5R}_2\ (\text{R = H, Me, OH, OMe})$....
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Bond lengths in P₄O₁₀

According to JD Lee's Concise Inorganic Chemistry: The double bond $\ce{P=O}$ in $\ce{P4O10}$ contains p(π)–d(π) backbonding, where a full p-orbital on oxygen overlaps with an empty d-orbital on $\...
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Is black phosphorous aromatic?

I know that graphite and boron nitride are aromatic in nature. In a similar way, can black phosphorous too exhibit aromaticity? Since it is essentially the same having 6 membered rings with lone ...
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What is reason of stability of metal (Sr and Ba) peroxides?

While studying inorganic chemistry I came across the following chemical equation. $$\ce{M + Air\left(1/2O2 + N2\right) ->[Δ] MO ->[\text{Excess}~O2] MO2 (Stable) + M3N2}$$ $$\ce{M} = \ce{Sr, ...
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Can the Lewis dot structure of SO2 be experimentally verified?

I have just watched 2 different videos on the Lewis dot structure of sulfur dioxide, $\ce{SO2}$. One says it is $$\ce{O=S=O}$$ and the other says $$\ce{^-O-S^+=O <-> O=S^+-O-}$$ The first ...
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What is symmetry of p- and d-orbitals in ${D_{3h}}$?

To identify IR and Raman active, symmetry of p- and d-orbitals are used. If we start since making ${D_{3h}}$ character table, how to match between symmetry of p- and d-orbitals and Mulliken symbol? ...
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Why does standard reduction potential get multiplied by the change in oxidation state and not by the number of electrons transferred?

The whole basis of Frost diagrams is to have a graphical representation of the Gibbs free energy of formation ($\Delta{G}_{f}$) of different oxidation states of an element using the proportional ...
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H-N-H bond angle in ammonia boron trifluoride adduct

In the reaction: $\ce{NH3 + BF3 -> NH3-BF3}$ does the HNH bond angle increase or decrease? Surely, the FBF bond angle decreases because boron changes from $\ce{sp^2 -> sp^3}$. But how can we ...
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Fluoride anion as a strong field ligand

In the case of $\ce{[Fe(H_2O)_6]^{3+}}$ there are $5$ unpaired electrons as water acts as a weak field ligand. But instead of flouride acting as a weak field ion in the $\ce{[MnF_6]^4-}$ , why does it ...
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Inorganic IUPAC for Compounds with bridged ligands?

Can we use bis(tetraammine) instead of octaammine is the 2nd example ? As in the 1st example they used bis(pentaammine) and also in the 3 one the used bis(carbonylcyclopentadienyliron)
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Mechanism of sodium hypochlorite and hydrochloric acid

The overall reaction for the reaction between NaClO and HCl is: $\ce{NaClO + 2HCl -> NaCl + Cl2 + H2O}$ To try and understand how this reaction occurs, I've thought of a simple mechanism for it. ...
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Why AlCl3 more acidic than FeBr3?

In compounds with lone pairs or with charge it is easy to predict acidity of compounds but how to describe acidic nature of such ($\ce{FeBr3}$, $\ce{AlCl3}$) transition element compounds ?

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