Questions tagged [inorganic-chemistry]

Inorganic compounds generally do not have C-H bonds, while organic compounds do have such bonds. The distinction between inorganic and organic chemistry, however, is far from absolute.

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Why are palladium and platinum carbonyls unstable at room temperature?

By palladium and platinum carbonyls, I mean the mononuclear, homoleptic, charge-neutral, binary carbonyl complexes of the form $\ce{M(CO)_n}$ and not any heteroleptic complexes like $\ce{Pd(CO)(PPh3)3}...
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Does this binary compound of C and N - isoelectronic with carbon suboxide - exist?

I am a mathematician not a chemist, so my questions are naive and rather combinatorial. I am intrigued by the possibility of the following compound: $$\ce{N- = N+ = C = N+ = N-}$$ which ought to ...
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Can I make Ferrofluid without evaporating Ammonium?

I want to make ferrofluid, which is ferromagnetic particles suspended in a carrier fluid. Three methods I have seen involve using magnetic ink (for MICR codes), cassette tapes, or ferric chloride as ...
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What is this golden looking substance?

I am currently messing around with gallium compromising aluminum. I am using a titalium lock which is just a brand of aluminum padlock and I put a gallium-indium euctic alloy on the surface of it. It’...
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What causes the blackening of light bulbs

in 1878, Thomas Edison (or rather William Joseph Hammer) added an anode in a light bulb in order to catch the flux of electrons coming out from the carbon filament and reduce the phenomenon of ...
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Why does lithium aluminium hydride appear grey?

Commercial lithium aluminium hydride is a grey compound, which loses a lot of reactivity the darker it is. Luckily you can clean it up to get the reactive white compound and the separated grey ...
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How well will molten iron chrysolite (fayalite) react with hydrogen?

The equation balances nicely, but would the reaction tend to proceed this way? What temperature and time would be needed? $\ce{Fe2SiO4 + 2H2 -> 2H2O + 2Fe + SiO2}$ There is no problem with ...
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Why can't beryllium react with hydrogen gas directly to give hydride?

I read in a textbook that all alkali metal and alkaline earth metal can react with hydrogen directly to give hydride except for beryllium. I want to know the reason why because I know that $\ce{BeH2}$ ...
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Is iron(III) carbonate stable in water?

I searched for this onsite already, and also found the following answer on Quora: In aqueous environment, iron(III) is bound by water molecules and exists as $\ce{[Fe(H2O)6]^3+}$. Due to strong ...
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Mechanism for the decomposition of HI

I've been trying to find the mechanism for the gas phase decomposition of hydrogen iodide: $$\ce{ 2 HI (g) <=> H2 (g) + I2 (g)} $$ Anyone know of sources where I can get information on this? I ...
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Is there a selective wet etch of Bi2O3 Bismuth Oxide?

I'm looking for a wet etch of Bismuth Oxide that does not etch $\ce{Bi}$ itself. There are obviously chemicals that etch $\ce{Bi2O3}$, but $\ce{Bi}$ is pretty fragile, so almost everything I've found ...
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Identifying Alkyl Ligands as Pi Donors or Pi Acceptors in Transition Metal Complexes

Just wondering if there was a systematic way to identify an alkyl ligand as a $\pi$ acceptor or $\pi$ donor in a transition metal complex? Although various sources indicate that weak field ligands ...
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Methylation of perchlorate

I am exploring (non-experimentally!) the methylation of a perchlorate precursor, either the acid or pre-existing salts, to produce the alkali methyl perchlorate. The methylating agent would be methane ...
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Isolating radium oxide

Why is radium oxide yet to be isolated when a wide range of other radium (II) compounds are known ?
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What is the most accepted explanation of aurophilicity?

Gold has a special property called aurophilicity. Inorganic chemistry by Huheey has some explanation, but that was not enough to clear the conception.
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Ligand strength - Coulombic effect and/or Electronegativities?

According to my teacher, these three Lewis bases generally decrease in strength in the following order: Ammonia Water Hydroxide ion I agree. However, he argues that their ability to act as Lewis ...
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Why is there no effective alternative to metal salts in antiperspirants?

Metal salts, especially aluminum compounds are used in antiperspirants to prevent sweating. I found out aluminum chloride hexahydrate, which is found in most antiperspirants, undergoes an acid-base ...
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What is the magnetic moment of potassium hexacyanochromate(II)?

I calculated the magnetic moment of $\ce{K4[Cr(CN)6]}$? in the following way: $\ce{Cr^{+2}}$ has $4$ d electrons. And since $\ce{CN-}$ is a strong field ligand, the electrons will pair up in the $\...
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Why is bis(1,2,2,6,6-Pentamethyl-4-Piperidinyl) Sebacate used as a “bottom coat” for a superhydrophobic coating?

According to this MSDS sheet, a compound named bis(1,2,2,6,6-Pentamethyl-4-Piperidinyl) Sebacate is used in the "bottom coat" layer before a "top coat" of superhydrophobic NeverWet coating is applied. ...
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Why isn't orthoboric acid soluble in cold water even though it has polar B-OH bonds?

This is the information I found regarding orthoboric acid's solubility: Textbook (NCERT India): Sparingly soluble in water (didn't say what temperature - presumably cold) and highly soluble in hot ...
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Wade's rules applied to metallic elements

There are many examples of metallic clusters that distort from the structure predicted by Wade's rules to a more 'spherical', closo-like arrangement. For example, $\ce{Bi8^2+}$ is a square antiprism ...
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What are the factors that affect the redox reactions?

In my work, I used $\ce{Co(OH)2}$ and $\ce{Ni(OH)2}$ as an active materials to fabricate as symmetric supercapacitors in which I used 1-butyl-1-methylpyrrolidinium dicyanamide as an electrolyte. From ...
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Cytotoxicity of Ru-complexes

I have a basic question: why are Ru(II)-complexes cytotoxic? What I know is that depending on the used ligand some of them interact with the DNA either via DNA-pi-stacking (intercalation) or binding ...
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Coordination Numbers and Hybridization schemes of anions

Draw the molecular structures of (a) the borax anion, $\ce{[B4O5(OH)4]^2-}$ (b) the peroxoborate anion, $\ce{[B2(O2)2(OH)4]^2-}$ ...
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Going from La to Ce, why is the extra electron added into the 4f orbital?

So, I am studying electronic configuration but the elements of the series of the lanthanides confused me. The electronic configuration of $\ce{La}$ is $\mathrm{6s^2\,5d^1}$ and that of cerium is $\...
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Compounds that Liberate Hydrogen from Water, Reversibly

I'm working on a paper which provides an overview of all the current methods for storing hydrogen gas as part of a renewable energy system, and I understand compressed gas and metal hydride storage ...
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On what factors does the true reaction Stoichiometry depend when there are multiple valid options?

Consider the following unbalanced reaction: $$\ce{XeF4 + H2O -> Xe + XeO2 + HF + O2}$$ There are six variables to be solved, but only four equations linking them. I solved the set of equations ...
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How do native sulfur crystals form?

I was visiting an elements exhibition in the Ulster Museum (Northern Ireland) and there were these native sulfur crystals on display. My question is how do sulfur crystals like these form in nature? ...
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I found transition states (TS), but calculations aren't supported by experiment. Do I look for more TSs or somewhere else?

I'm using Gaussian to investigate a catalyst system. Experimental evidence showed that one of three analogues (R = phenyl, Ph), yielded a benzosultam when treated with 2,4,6-...
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Can compounds found in concrete leach into soil against gravity?

I spent a while trying to figure out which stackexchange site in which to post this question, forgive me if I got it wrong. A number of scholarly articles indicate that concrete can leach calcium ...
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Combustion of halo-organic compound

My question is based on the Preparatory Problem Set for the 47th IChO Problem 26 - Holy War against Four Horsemen of the Apocalypse (it is on page 36). It is written that cooling of Y combustion ...
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How to rationalise the trend in the covalent radii of the transition metals?

Why do the covalent radii of transition series decrease at the start rapidly, then become almost constant and at the end of series begin to increase from left to right in periodic table?
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How many lumens from 1 gram of flash powder

Does somebody know how many lumens we get from lighting 1 gram of flash powder in pure oxygen (or normal) environment? I'm thinking about $\ce{KClO_4} $ (60%) + $\ce{Al}$ (40%) flash powder and quite ...
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Compound of fluorine and tellurium

As an exercise I have to predict the formula of the compounds that fluorine and tellurium can build using group properties. My idea was to use the octet rule and therefore the formula would be $\ce{...
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An unknown glassware piece from our cupboard

We have multiple of these. It is a small glass funnel with splits into 3 spouts from it. Now, we are thinking it might be similar to a cow receiver, however, I have never seen one this small or ...
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Unknown possibly handmade glassware- description in information below

Okay, Another random item from the cupboard (unknown users or discipline of life sciences unknown) could be anything up to 40 years old.... This appears to be a 2 neck quickfit adapter (B19 and B14) ...
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Solubility of PbSO4

The solubility of $\ce{PbSO4(s)}$ increase with the addition of $\ce{H2SO4}.$ Why? I don't quite understand this. When dissolving $\ce{PbSO4(s)}$ we get the equilibrium equation: $$\ce{PbSO4(s) <=...
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Changing of UV-Vis peak absorption after heating Ni(en)2(NO2)2

(c) The trans-isomer of $\ce{Ni(en)2(NO2)2}$ D is red $(λ_\mathrm{max} = \pu{500 nm}).$ It can be heated to give a new trans-isomer E, which is violet $(λ_\mathrm{max} = \pu{560 nm}).$ Assume that, ...
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Gap in ionic radii

The above picture was shown in a presentation by my prof in inorganic chem as we were discussing ionic radii more in depth (all in pm). These are all isoelectronic radii. Notice the sudden leap in ...
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Analytics of a paramagnetic complexes

I am working with salophene iron[III] complexes. Unfortunately, my 5th ligand cannot be determined via MS. I performed a 1H-NMR in methanol, but it's not a suitable method for a paramagnetic compound. ...
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Why is gunpowder urinated on in Blood Meridian?

An interesting section of Blood Meridian (1985) by Cormac McCarthy has the gang of "Indian fighters" surrounded and out of powder, so one of them manages to make it from scratch, making charcoal from ...
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Does the wavelength of light absorbed by a complex depend upon extent of splitting or stability?

Background: we were doing Crystal Field Theory in school when this question popped up. Specifically we were talking about stability obtained due to the chelate effect and if the extra stability in a ...
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What's the hybridization in diphosphorus molecule?

I read that diphosphorus has 2 phosphorus atoms joined by a triple bond (ie) it has one sigma bond and 2 pi bonds with 2 lone pairs ( 1 lone pair on each atom). I'm confused about the hybridization of ...
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Which reagents can directly oxidize ammonium ion into gaseous dinitrogen?

I have a simple question. I've looked on the internet and the only thing I found was the Anammox process - Anaerobic Ammonium Oxidation. Wikipedia lists the reaction as: $$\ce{NH4+} +\ce{NO2-}\...
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Sense of radii quotient to determine coordination number in crystals?

Every common textbook explains the method of the radii quotient between the cation and anion of a selected salt to determine to coordination number(s) in that salt. For example deduce "Inorganic ...
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Can someone help me finish this reaction?

This question revolves around sodium percarbonate (https://en.m.wikipedia.org/wiki/Sodium_percarbonate) and its reaction with sulfuric acid. I didn't find anything, so I tried assembling it myself. ...
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Briggs-Rauscher numerical model

I want to use the Briggs-Rauscher experiment to demonstrate oscillating reactions, and then explain it using a numerical model. How much is known about this reaction? Is it possible to write down a ...
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What will happen if ligand orientation is changed?

How we came to know ligand should approach from t2g orbitals in d5 configuration for tetrahedral complexes? What will be the difference in energy if ligand approach from eg? As far as I can think, ...
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Can the decompistion of one carbonate inhibt the decomposition of another carbonate?

If two different carbonates of Group II, are mixed in equal amounts and then heated could one of the carbonates decomposition inhibt the other ones decomposition? I don't understand how it would ...
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Trends in pi backbonding for main group elements across a period

Recently, I have been re-reading some undergraduate notes and found that there's a period trend in pi backbonding of main group elements (i.e. no transition metals involved) but no explanation were ...