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Questions tagged [inorganic-chemistry]

Inorganic compounds generally do not have C-H bonds, while organic compounds do have such bonds. The distinction between inorganic and organic chemistry, however, is far from absolute.

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144 views

Manganates (II)

I want to ask about character of manganese(II) compounds. I read that $\ce{MnO}$ is basic, just like $\ce{Mn(OH)2}$. I started doing research and I read ions like $\ce{MnO2^{2-}}$ and $\ce{HMnO2^-}$ ...
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45 views

Is atom-clean aluminum active enough to react with alkali salts?

Thermally evaportated $\ce{Al}$ under high vacuum is free of oxidized species and highly active. But is it active enough to even substitute the alkali cationic metal in alkali salts, like $\ce{LiOH, ...
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628 views

Why triiodide ion does not form ionic bond with cation having +2 charge?

In general, I found that triiodide ion generally forms ionic bond with cations having +1 charge like $\ce{NH4+I3-}$, $\ce{K+I3-}$, $\ce{Tl+I3-}$. But, I have never seen triiodide ion forming ionic ...
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Primitive Technology - Extract Silica and Sulfur from ash

Given some plant ash containing silica and sulfur, we need to find a way to extract the silica and sulfur using only resources available to a primitive person stuck on an island, with access to a ...
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37k views

Is H2CO3 (carbonic acid) soluble or insoluble in water?

I am asking this because I know that acids are normally aqueous but according to the solubility rules, all carbonates are insoluble.
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Why is LiOH a weaker base than NaOH [closed]

Why do LiOH is weak base as compared to NaOH even though it's hydration enthalpy is greater than Na?
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1answer
94 views

Why can some ions have different valence?

Like $\ce{Fe}$, it can be $\ce{Fe^{2+}}$ or $\ce{Fe^{3+}}$, same with $\ce{Ni}$ and $\ce{Co}$, what determines whether the ionic compound will be $\ce{Fe^{2+}}$ or $\ce{Fe^{3+}}$?
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51 views

Oxidation state of iron ions in a unit cell

Consider UC (unit cell) for a cubic ionic lattice containing 4 oxide ions - what is the avg oxidation state for Fe ions in this lattice? The four oxide ions create a -8 charge that must be ...
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889 views

Why does copper(II) sulfate react with ammonia?

We've done preparation of Tetraamminecopper(II) sulphate $\ce{[Cu(NH_3)_4(H_2O)_n]SO_4}$ using copper sulphate and 50% ammonia solution. Initially, a pale blue color of $\ce{Cu(OH)_2}$ appeared with ...
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2k views

How to prepare iron(II) carbonate from iron(III) chloride?

Now, this is an awkward reaction first of all. I know how to prepare $\ce{Fe2(CO3)3}$ from $\ce{FeCl3}$: $$\ce{2FeCl3 + 3Na2CO3 -> 6NaCl + Fe2(CO3)3}$$ But the question is asking for $\ce{FeCO3}$....
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Do acids without hydrogen taste sour?

I have heard that acids taste sour because of hydrogen (I don't really know exactly). According to the definition of acids: An acid (from the Latin acidus/acēre meaning sour) is a chemical ...
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544 views

Hydrates In Aqueous Solutions

Say you had copper(II) sulfate pentahydrate as a solid. In an aqueous solution, is it still referred to by its hydrated form? Is it still called copper(II) sulfate pentahydrate (aqueous) or simply ...
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Why is AlCl₃ is known as aluminium chloride while PCl₃ is known as phosphorus trichloride? [duplicate]

Why is $\ce{AlCl3}$ is known as aluminium chloride while $\ce{PCl3}$ is known as phosphorus trichloride? I think it is due to variable valency if phosphorus. Is it true?
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242 views

Can I convert elemental nitrogen to nitrous oxide?

Can I convert nitrogen to $\ce{N2O}$, to conduct barking dog reaction, where it's needed as oxidizer?
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300 views

What does Pb(NO₃)₂ + KI form? [closed]

What does $\ce{Pb(NO3)2 + KI}$ form?
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Structure of the bifluoride anion [duplicate]

I came across this structure of $\ce{HF2-}$ and realized that the bond shown between H and F is a hydrogen bond. $$\Large\ce{[F-H-F]-}$$ HF hydrogen bond are the strongest hydrogen bonds we know, ...
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461 views

Why magnesium has the lowest melting and boiling point in its group? [duplicate]

It is written in the third point ( shown in the picture) that presence of d orbitals results in stronger metallic bond. 1) We check the strength of metallic bonding to compare the melting and boiling ...
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131 views

What is the structure of Cl₂O₆?

I couldn't find which of these is correct and even someone I asked said there's no general covincement on it, but I'm unsure whether he's correct? I reproduced the second structure a little wrong ...
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How can I neutralise H2 gas without burning it? [closed]

I was thinking of maybe making it bubble into a solution containing something that would react with H2 yielding either a dissolved substance or a precipitate from the reaction. Maybe a solution with ...
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3k views

How does aqueous ammonia react with hypochlorous acid in water?

Here is what I have so far: $$\ce{NH3 + HOCl -> NH2Cl + H2O}$$ Since ammonia reacts with hypochlorous acid to form the chloramine $\ce{NH2Cl}$. But I don't know if this is correct.
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81 views

What compound is formed in this case?

I read from a source that the aqueous solution of ferrous sulfate ($\ce{FeSO4}$) gives an unstable brown compound on treating with $\ce{NaNO2}$ and dilute $\ce{HCl}$. Well, it is quite understandable ...
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452 views

Interaction between Ozone and Carbon Dioxide

We are trying to predict what will happen when carbon dioxide gas is introduced into a contact chamber that serves as an ozone contact chamber. These contact chambers presently oxidize compounds found ...
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58 views

Disproportionation of 2 KO₂ + 2 H₂O → 2 KOH + H₂O₂ + O₂

How is the following reaction a disproportionation reaction? $$\ce{2 K\overset{-1/2}{O}_2 + 2 H2\overset{-2}{O} ->2 KOH + H2\overset{-1}{O}_2 + \overset{0}{O}_2}$$ In this, the OS are $-1/2$, $-2$...
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654 views

why “amu” is used as a unit in relative atomic mass? [duplicate]

Unified atomic mass unit (amu) is defined as $1/12$ of the mass of a Carbon-12. I want to know is this amu equal to $\pu{1.99e-23 g}$ and why do we use amu which is $1/12$ the mass of carbon? Why use "...
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Calculating bond dissociation enthalpy of F-F bond

$$\ce{N2 + 3 F2 -> 2 NF3} \quad ΔH = \pu{-263 kJ mol-1}$$ The bond dissociation enthalpies of the nitrogen triple bond and nitrogen–flourine bond are $\pu{946 kJ mol-1}$ and $\pu{272 kJ mol-1}....
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Why is phosphorous acid more acidic than phosphoric acid?

Phosphoric acid has basicity of 3 i.e it can loose 3 $\ce{H+}$ while phosphorous acid has basicity of 2. Why is phosphorous acid more acidic than phosphoric acid? Acidity refers to the ability to ...
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152 views

What type of chemical reaction is this?

So far we have learned about about single displacement, double displacement, gas evolving, neutralization, synthesis, disassociation, and combustion. I was trying to solve the following chemical ...
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2k views

Heating of potash alum

I have this reaction : $$\ce{K2SO4.Al2(SO4)3.24H2O -> K2SO4 + Al2O3 + 24H2O}$$ And I notice that while $\ce{Al2(SO4)3}$ becomes $\ce{Al2O3}$ it doesn't happen so with $\ce{K2SO4}$. Why ? I guessed ...
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Question About Reversible Reactions and Batteries

So my book says that the batteries we have considered so far( Daniell cells) are low life span, because they reach equilibrium too fast. In the next paragraph, it says they are also made by ...
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131 views

Help regarding stereochemically inactive s orbital [duplicate]

Author JD Lee says in his book, Inorganic Chemistry The dipole moment of $\ce{XeF6}$ is approximately = $0$ because the lone pair is present in the stereochemically inactive s orbital. What is ...
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1answer
624 views

Reaction between silver(I) hydroxide and an alkali [closed]

I've read about this in a booklet, but I can't find its stepwise reactions or its derivation: $$\ce{AgOH + NaOH -> Ag2O}$$ And how does a base ($\ce{AgOH}$) react with another base ($\ce{NaOH}$)? ...
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300 views

Inorganic reactions related to nascent hydrogen [closed]

Nascent hydrogen is prepared by (A) $\ce{Na}$ and $\ce{C2H5OH}$ (B) $\ce{Al}$ and $\ce{NaOH}$ (C) $\ce{Zn}$ and dil. $\ce{H2SO4}$ (D) All of these My attempt I know that option (A) &...
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1k views

If copper is insoluble in excess NaOH, does it mean it is soluble in NaOH when not in excess? [closed]

I don't understand, does it mean when i add a little bit of NaOH, there will be completely no precipitate/ it will dissolve?
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11k views

How to write reaction equations for the reaction of calcium and dilute nitric acid?

Normally metals react with dilute acid to form a salt and evolve hydrogen gas but I have read that hydrogen gas is not evolved when a metal reacts with nitric acid (because Nitric acid is a strong ...