Questions tagged [inductive-effect]
The inductive-effect tag has no usage guidance.
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How To Decide Hyperconjugative (+H,-H), Resonance (+R,-R) And Inductive (+I,-I) Effect Of Any Group Relative To Any Other Group [on hold]
I WAS SOLVING A COUPLE OF QUESTIONS ON ACIDIC AND BASIC BEHAVIOR FROM AN ORGANIC CHEMISTRY BOOK AND WAS FACING DIFFICULTY SOLVING SOME QUESTIONS BASED ON THE AFORESAID CONCEPT.
I WOULD REALLY BE ...
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27 views
Which of the 2 structures is more stable?
As far as I know, alkenes with more number of hyperconjugating structures are more stable. Hyperconjugation has a greater stablizing effect than Inductive effect. So, (d) should be more stable as it ...
2
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1answer
36 views
Does hyperconjugation into sigma-star explain methylamine's increased basicity relative to ammonia?
The inductive effect with the polarisation of the C-N bond obviously plays a role in stabilising the positive charge of the conjugate acid. But given the similar electronegativities for C and H, CH3 ...
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1answer
93 views
Which Carbocation is most stable among the three? [closed]
According to me the answer should be (C) as that Carbocation will be stablized by resonance with Chlorine.
I have read that resonance is the biggest deciding factor about the stability of a ...
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0answers
93 views
Why is C2H5 a stronger +I group than CH3?
While reading about the basic character of amines, I came across a note which said that $\ce{CH3-CH2-NH2}$ was more stable than $\ce{CH3-NH2}$ as $\ce{C2H5}$ was a stronger +I group than $\ce{CH3}$.
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1answer
53 views
Stability order of methy benzyl cations?
I know that meta position shown no resonance effect and hyperconjugation effect . So According to the order given I guess Hyperconjugating effect is taken into account as -CH3 has no Resonance effects....
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1answer
95 views
Give the order of nucleophilic addition reaction in the following -
I am confused that whether we should take only inductive or hyperconjugation effect also into consideration while finding the order. As the answer in the book is only according to inductive effect . ...
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0answers
56 views
Mechanism of substitution for disubstituted benzene
Here, I count the individual effects of the two oppositely directing groups. I assume that the deactivation of $\ce{NO_2}$ group at ortho and meta positions is higher. While bromination, I get the ...
1
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1answer
287 views
Comparing relative negative inductive effect of substituents (dialkyl amine, amine, alkoxide, fluoride)
Which of the following is correct with respect to the negative inductive effect of the substituents?
1. $\ce{-NR2 < -OR < -F}$
2. $\ce{-NH2 < -OR < -F}$
3. $\ce{-NR2 > -OR > -F}...
