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3 questions
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Why does the factor of ⅔ come in when we calculate net flux due to diffusion for an ideal gas
As per Atkins' Physical Chemistry (11E) Pg:694. We arrive at a crude estimate for the net flux through an imaginary flux plane. We find it to be $$J_{z}=-\frac{1}{2}v_{mean}\lambda(\frac{d\mathcal{N}}{...
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Relation of temperature to effusion and diffusion [duplicate]
We were studying Graham's Law today and its dependence on Temperature, Pressure, Area, etc.
However, our teacher said that, for diffusion: $$R \propto \sqrt T$$ and for effusion:$$R\propto1/\sqrt T$$ ...
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If Graham's law doesn't apply to the ammonia and hydrogen chloride diffusion in a glass tube demonstration, is there a law that does?
A comment below What exactly are "white fumes" and why does holding a bottle of ammonia (conc) next to a bottle of HCl (conc) make them? links to The
Royal Society Of Chemistry video ...