Chemistry

Questions tagged [emission]

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What type of spectroscopy can display several vibrational energy levels around the electronic transition?

My question is illustrated as the figure. As far as I know, due to the Franck-Condon principle, the absorption spectrum is related to the ground state to the excited state with the same geometry. Here ...
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How to think about absorption and emission rates and intensity for stimulated emission?

I learned Fermi's Golden Rule applied to absorption and stimulated emission and encountered the following question: Since absorption and emission rates are the same for stimulated emission, why can't ...
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Photodissociated iodine laser and population inversion

Iodine molecules ($\ce{I2}$) can absorb in the visible region and dissociate into $\ce{2 I^.}$ radicals. One of the I atoms is in ground electronic state $\mathrm{^2P_{3/2}}$ and the other I atom is ...
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Absorption and Emission at same wavelength?

Is it possible for a molecule to absorb and emit at the same wavelength? What is the reason behind it? I’m working on charged Tin porphyrins and got the excitation and emission (fluorescence) ...
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Detectable elements using flame AES

I've been looking for extra information concerning flame atomic emission spectroscopy. I need a clear overview of which elements are detectable with this technique, but I can't find anything because ...
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Thermionic Emission Conservation of Energy

I am learning about thermionic emission and how it led to the vacuum tube. It is said that thermionic emission was a way to increase the flow of electrons from a signal (e.g. in a radio receiving a ...
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Temperature dependence of emission lines from gases, for example, neon

Emission lines from Ne are frequently used as wavelength standards in spectroscopy. Reading around Wikipedia, I found about the Paschen law regarding the voltage required to start a discharge. My ...