Questions tagged [conductivity]

A material's ability to conduct electric current or thermal energy by any means.

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7
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1answer
221 views

How to derive the conductivity titration curve which accounts for salt formation

I derived an equation that gave me the volume of base required to get a certain $\mathrm{pH}$: In a titration between a weak acid $\ce{HA}$ and weak base $\ce{B}$ (adding base into acid solution) the ...
3
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1answer
39 views

Stritations in a discharge tube

I am reading about A cathode ray discharge tube and I still do not fully understand why that as you keep on lowering the pressure in the chamber it creates striations, Faraday's dark space and Crooke'...
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0answers
25 views

Further reading on photoconductivity of hemoglobin

I recently ran into this paper which describe experiments that confirm that hemoglobin is photoconductive. Finding this fact as incredible, I wanted to read up more on photoconductive properties of ...
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0answers
17 views

Investigating the effect of solvents on the alkaline hydrolysis of ethyl acetate

In the following reaction, I believe a polar aprotic solvent like propanone will be more favorable since the partial negative charge on the oxygen atom in propanone will attract the sodium ion from ...
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0answers
20 views

Factors that influence the electrical conductivity of metals

The electrical conductivity of metals is a physical property of these materials. Much of the theory used to explain the electrical conductivity of metals is also based on physics understanding. ...
0
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1answer
42 views

Molar conductivity of transition metal complexes solutions [closed]

Which of the following has the highest molar conductivity? (A) Diaminedichloroplatinum(I) (B) Tetraamminedichlorocobalt(III) chloride (C) Potassium hexacyanoferrate(II) (D) Hexaaquochromium(...
2
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1answer
45 views

Conductance of the mixture of two solutions with given resistance values [duplicate]

If $R_1$ and $R_2$ are the resistances of two solutions of equal volume what is the conductance of the mixture in the same conductivity cell? In general, I grasped neither the approach, nor the ...
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4answers
291 views

Is there any electronic component to water conductivity?

Answers to Decrease in temperature of a aqueous salt solution decreases conductivity indicate that the electrical conductivity of salt solutions arises from the mobility of ionic species and therefore ...
1
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1answer
32 views

Decrease in molar conductivity with increase in concentration

Why does molar conductivity $Λ$ for strong electrolytes decrease with increase in concentration? I mean, more concentration would mean higher number of solute particles present in the solution, and as ...
1
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3answers
37 views

Soil conductivity: How do I get a near equivalent between meq/100 g to mS/cm?

I have two soil reports, one that reports CEC as 45 meq/100 g and another that reports 6 mS/cm using 1:1 water soil. I can see that the two are, if not apples and oranges, they are at best tangerines ...
2
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1answer
34 views

What should be the order of specific conductance (κ) of floride, chloride and bromide ions?

The equivalent conductance order is $\ce{Br-} > \ce{Cl-} > \ce{F-}$. $$Λ = \frac{κ}{c},$$ so $Λ$ is proportional to specific conductance? But in ion chromatography we get peak area where $\ce{...
1
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1answer
31 views

Which conductivity law should I use to calculate the conductivity of a solution with high/low concentration?

I have a set of NaCl solutions with concentrations ranging from 0.05 M to 0.1 M. I have been trying to calculate the conductivity of these solutions and compare the obtained values with the ...
10
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1answer
289 views

Why are isotopically pure diamonds 50% more thermally conductive than other diamonds?

A laboratory grown type-IIa diamond (no nitrogen defects) has a lambda of $\pu{1800-2200 W/mK}$, but an isotopically pure diamond of $\ce{^{12}C}$ can have up to $\pu{3320 W/mK}$. Why are $\ce{^{12}C}...
4
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3answers
12k views

What is the difference between molar conductance and molar conductivity?

I'm learning (or at least trying to learn) about electrochemistry, but a major obstacle to that, is that different books I refer use different terms for the same symbols. So in a last ditch attempt to ...
2
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1answer
69 views

Intensive and Extensive Properties--Resistance

Is resistance an intensive quantity or an extensive one? And why? Let me present 2 scenarios. Resistance of a wire: The resistance of a wire depends on area and length. This implies it depends on the ...
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1answer
70 views

Do the salt bridge ions have to match the ions in the half-cells solutions?

Does the salt bridge in a galvanic cell have to have the same ions as the ones in the solutions? E.g. does it need to have nitrate ions if the half-cells contain copper nitrate and zinc nitrate, or ...
0
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1answer
56 views

How to measure the electrical conductivity of a substance? [closed]

Suppose you are given these substances: $\ce{NaOH(aq)}$ $\ce{HCl(aq) }$ $\ce{C6H12O6(aq) }$ $\ce{NH3(l)}$ Are there rules to figure out how conductive each compound is? Is it based on ...
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2answers
342 views

Decrease in temperature of a aqueous salt solution decreases conductivity

Why does the conductivity of a water solution drop as the temperature decreases? How are these two related?
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1answer
28 views

Silver in defect chemistry

When talking about conductivity in combination with lattice defects you can often see that AgX is taken as an example for a Frenkel defect where the $\ce{Ag^+}$ moves to intersticial voids. I remember ...
2
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2answers
19k views

Graphene Vs Copper?

I was wondering about the amazing conductive properties of graphene, lets assume a large copper bar that is 10 kg, current of 1kA and probably more can flow in it, what about graphene? It certainly ...
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2answers
12k views

Why is copper a better conductor than iron?

So metals are good conductors as the electron in their outer shell is loose and can plunge out of the atom with the application of the slightest force(voltage). Silver is the best metallic conductor, ...
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0answers
230 views

Reduced Graphene Oxide (RGO) Conductivity vs Everything Else

Reduced Graphene Oxide (RGO), is the reduced version of Graphene Oxide (GO). Both RGO & GO are easily manufactured when compared to the complex process used to manufacture the 'atom-thick' ...
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2answers
8k views

Why is fullerene 60 an insulator while graphite is a conductor?

Graphite is good conductor of electricity because one carbon atom is bonded only three carbon atoms, which enables the presence of free electrons. In fullerene 60 the carbon atoms are also bonded to ...
2
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1answer
73 views

Why do metallic elements have a very small band gap while nonmetallic elements have a large band gap?

I recently was going over solid state bonding and conductivity. I was wondering why metallic elements (such as sodium, iron, etc.) have a small band gap / no band gap (as conductors that have the ...
6
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1answer
106 views

If liquid hydrogen fluoride autoionises, how can it be an insulator?

According to Wikipedia, one of the last major hurdles in the isolation of elemental fluorine was the need to mix hydrogen fluoride with another substance in order for its electrolysis to be possible (...
3
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1answer
897 views

Why does Ga improve conductivity of Ge? [closed]

This is for my AP Chemistry course and the question is: Which of the following elements is important in the semiconductor industry to improve the conductivity of Ge? K Ga Al Mg ...
2
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1answer
135 views

Conductivity of Wüstite

"Wüstite is often represented as $\ce{Fe_{1-x}O}$, where $x$ is some small fraction less than unity. In this nonstoichiometric $\ce{Fe_{1-x}O}$ material conduction is electronic and the material ...
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0answers
89 views

NiO and ZnO electrical conductivity with oxygen pressure

NiO is a Mott-Hubbard insulator and increasing oxygen concentration leads to anion excess and oxidation of Nickel so electron hopping is more favourable so electron repulsion is reduced and it becomes ...
20
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3answers
3k views

Choice of doping elements in semiconductors

In a typical semiconducting material, we start with silicon (group IV) and introduce atoms of group V or group III depending on whether we are constructing an n- or p-type semiconductor respectively. ...
2
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1answer
419 views

Why are silicon and germanium used as semiconductors but not other metalloids?

The semiconductor materials are either elementary such as silicon and germanium or compound such as gallium arsenide. Silicon is the most used semiconductor for discrete devices and integrated ...
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1answer
67 views

Is the electrical conductivity only measurable in aqueous solutions? [closed]

I have been looking for other ways to measure it, but all I've found is through aqueous solutions. So I want to know if there's another way to do it, or why it isn't possible through other means.
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4answers
4k views

Does an electrically conductive gas exist at room conditions?

As I know, the gases are insulators, because their particles are mainly electrically neutral, and thus there is no movable charges in them. But maybe it shouldn't be always so, for example if a gas ...
0
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1answer
71 views

The Conductivity of Electrolytes based on structure of Ionic Crystal [closed]

Background I want to run an experiment to test the conductivity of various ionic compounds dissolved in water. I was hoping to see some sort of trend in the increase/decrease of conductivity based ...
3
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2answers
702 views

Are there compounds more conductive than Silver (Ag)?

Silver is the most electrically conductive element on the Periodic Table. However, I am interested in knowing if there are any compounds (combinations of elements) that would be more conductive than ...
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1answer
2k views

Difference between equivalent conductance and equivalent conductivity [closed]

I find questions in my book which ask for the equivalent conductivity and sometimes for the equivalent conductance. And then when I look at the solution, they've used the same formula for both. This ...
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0answers
241 views

Which is more conducting - molten sodium chloride or molten magnesium chloride? [closed]

Which is more conducting - molten sodium chloride or molten magnesium chloride? I'm pretty sure I know the answer to this but my problem is putting into words. Magnesium is more conductive due to its ...
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1answer
3k views

Why is AC current used rather than DC current for calculating the conductance of a solution(see body)? [closed]

I was reading the answer of the above question from a book. it said that while using DC current, electrolysis occurs. Hence it affects the conductance of the solution. But if any gaseous product is ...
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1answer
65 views

A chemical compound with these conditions? [closed]

I am searching for a chemical compound which meets these five conditions: slightly soluble in water layered strutcture ionic conductor thermochromism lead must be a part of it.
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1answer
134 views

Proper definitions of resistivity of conductivity

Is resistivity the same as specific electrical resistance? And conductivity is same as specific conductance when I am dealing with electrical properties ?
-1
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2answers
375 views

Does titanium(II) oxide conduct electricity? [duplicate]

In my book, it is given that $\ce{TiO(s)}$ is an electrical conductor. But I'd think that since $\ce{TiO(s)}$ is ionic and in solid state, it shouldn't conduct electricity. So, why does it conduct ...
1
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1answer
706 views

How is solid titanium(II) oxide an electrical conductor?

Most salts in the solid state are electrical insulators, since the ions are not mobile (e.g. sodium chloride). However, solid titanium(II) oxide, $\ce{TiO (s)}$, is a conductor. How is this so?
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60 views

Conductivity variation on Caustic (NaOH) Dilution System

I am reading the drawing for an automatic caustic dilution system where 50% NaOH is diluted down to 20%. I was expecting to see a density sensor on the outlet to provide feedback to the dilution ...
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0answers
643 views

Does ethanol conduct electricity? [duplicate]

I am trying to find out about methylated spirts/denatured alcohol. As far as I can fine, methylated spirits is roughly 95% ethanol. Will it conduct electricity? I have done some research, but I have ...
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2answers
6k views

Conductometric titration of Strong Acid And Strong base

Consider conductometric titration of Strong Acid with strong base say HCl + NaOH. My question is why initially the conductance decreases. If H+ of HCl is consumed by OH- of NaOH, forming water and ...
-1
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1answer
144 views

Which solution is more conductive

Which of the following solutions is more conductive: 1) 0.1 M sodium hydroxide and 0.1 M hydrochloric acid mixture (effectively NaCl?) 2) 0.1 M sodium hydroxide and 0.1 M acetic acid mixture (...
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0answers
1k views

Mathematical Expression for Limiting Molar Conductivity

I have been fiddling around with the theory of electrolytes, specifically molar conductivity, and ways of calculating limiting molar conductivity $\Lambda^0$. I was able to come up with the ...
2
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1answer
947 views

What is the difference between λ and Λ with regard to molar conductivity?

I came across these equations (boxed in red) in a book: $$ \begin{align} &\therefore & t_\mathrm{c} &= \frac{u_\mathrm{c}}{u_\mathrm{c} + u_\mathrm{a}}\\ &\text{and} & t_\mathrm{...
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1answer
6k views

Can solutions of polar covalent compounds conduct electricity?

I learned in class that solutions of polar covalent compounds are weakly conductive, while ionic solutions are strongly conductive. But I'm getting different answers online. According to this lecture,...
19
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4answers
9k views

Why is it that the least reactive metals are the best electrical conductors?

Silver, Gold and Platinum are amongst the best conductors of electricity, but also the amongst the most unreactive. Since electrical conductivity depends on the number of delocalized electrons (along ...
-1
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1answer
208 views

Relation of conductivity with electrode distance [closed]

Conductivity is defined as the conduction of ions when the distance between the electrodes is 1 cm and length is 1 cm. Say for instance we have a solution where the distance between the electrodes is ...