Questions tagged [concentration]
The concentration characterizes the composition of a mixture with respect to the volume of the mixture. There are mass, amount, number and volume concentrations. Related and within the scope of this tag are normality, molality, mole fraction/ratio, mass fraction/ratio.
516
questions
0
votes
1answer
543 views
Oleum concentration description
What is the meaning of "free" $\ce{SO3}$ and "combined" $\ce{SO3}$ in the oleum sample concentration description?
Also what are these maximum and minimum values of % labelling in oleum sample?
2
votes
1answer
41 views
Does simmering sparkling water change/decrease its mineral composition significantly?
I know that heating sparkling water will cause it to lose $\ce{CO2}$.
Does this have any other effects on the water that remains, such as reducing its mineral content? I understand when non-...
2
votes
0answers
42 views
How to determine concentration limits of a buffer that's limited by solubility?
I need to maintain a certain range of % of ionisation from a buffer.
For e.g. Histidine buffer. When making high concentration of this buffer at (say) pH 7.2, 25'C, [concentration] is limited to 75mM ...
2
votes
0answers
37 views
Concentration of acid when titration has reached equivalence point? [duplicate]
I'm currently working with a lab report concerning titration. One of the tasks is to calculate the concentration of the weak acid ($\ce{HOAc}$) and the strong acid ($\ce{HCl}$) at the equivalence ...
1
vote
0answers
68 views
why do solids and pure liquids have no effect on yield and equilibrium? [duplicate]
There are three parts to my question.
Part one:
Let's assume we have a reversible reaction at equilibrium as follows : Calcium carbonate (solid) goes into calcium oxide(solid) and carbon dioxide(...
0
votes
2answers
6k views
Calculating concentration of H+ Ions using Ka Value [closed]
I have this homework question that I am a bit stuck on for an answer. If anyone could help that would be great.
Question:
For a $\pu{0.2M}$ $\ce{HNO2}$ solution ($\pu{K_a= 4.5 \times 10^{-4}}$) ...
4
votes
2answers
4k views
How to convert ppm to g/m3?
I'm not very comfortable with chemistry and I need to convert $\ce{CH4}$ concentration values in $\pu{ppm}$ to $\pu{g/m3}$. Is that possible?
I've already researched a bit and realised that for water ...
1
vote
1answer
75 views
How do molecules know how to behave when a disturbance occurs in an equilibrium?
I am well aware of Le Chatelier's principle, but what causes molecules to behave in such a way, my guess is that it all has to do with rates of reactions and frequency of collisions.
When at a ...
1
vote
0answers
44 views
Volume change of solute addition to solvent
When making and manipulating high concentration stock solutions of sugar excipients, is there a way to predict the corresponding volume effect that occurs? I am asking in order to be able to create ...
-1
votes
1answer
740 views
Finding the molar concentration of reactant used
We were given this problem at my university, and I can't seem to figure out how it was solved. The question says we have $\ce{NaHCO3}$ and 100 ml of $\ce{HCl}$ react and one of their products is $\ce{...
12
votes
2answers
2k views
What is the point of using molality when we have molarity?
Molality and molarity are both concentration terms. Given molarity's popularity molality seems rather antiquated. Why is molality still discused in modern chemistry classes?
1
vote
1answer
1k views
How to correctly prepare a standard solution?
Having just spoken to my teacher about the creation of a standard solution, and she suggested one way of doing it, however a previous chemistry teacher had told us a different way of doing it. My ...
1
vote
2answers
141 views
Equilibriums and Overshooting
If we have some reaction $\ce{A(aq) + B(aq) -> AB(aq)}$ and right now we have less $\ce{A}$ and $\ce{B}$ then we would have at equilibrium, is there ever a time where the amount of $\ce{A}$ and $\...
3
votes
1answer
74 views
How do I measure out these salts using the proper method?
I'm planning on preparing a water solution using the following salts of reagent grade with approximately these concentrations:
\begin{array}{lr}
\ce{CaCl2} & \pu{10 mg/L}\\
\ce{Na2SO4} & \...
1
vote
1answer
725 views
What does “percentage by mass” mean in the context of a compound dissolved in a solution?
Copper can be recovered from low-grade ores by 'leaching' the ore with dilute $\ce{H2SO4}$, which converts the copper compounds in the ore into $\ce{CuSO4(aq)}$. In a $\pu{50 cm^3}$ leach solution, ...
-2
votes
1answer
14k views
Why is the concentration of pure water is 55.5 mol/L?
Whilst reading about pH, it is given that concentration of water is $\pu{55.5 M}$. Let water be of $\pu{1 mol}$ at $\pu{297 K}$ and $\pu{1 atm}$ pressure. Then the concentration is
$$c =\frac{n}{v} = ...
1
vote
1answer
4k views
Molar Absorptivity of Copper(II) Sulfate
What is the molar absorptivity of copper sulfate? I am trying to find the molarity of copper sulfate solution by absorption in a spectrophotometer with a cuvette.
However, I can't find $\varepsilon$, ...
3
votes
0answers
70 views
Should residual sodium be considered in measuring sodium content of sweat?
I read an article, "Fully integrated wearable sensor arrays for multiplexed in situ perspiration analysis", which describes the design of a wearable band that detects various components in sweat in ...
3
votes
1answer
208 views
How to convert micromolar concentrations into molar quantities, when the volume is also known
\begin{array}{c|cccccc}
\text{Sample} & \text{Ammonia} & \text{Phosphate} & \text{Silicate} &\text{Nitrate + nitrite} & \text{Nitrite} & \text{Mn} \\
& (\pu{\mu M}) & (...
1
vote
0answers
46 views
Is it possible to extract mass concentration from DLS measurement?
DLS (dynamic light scattering) gives the particle size distribution (number percent vs. size) of particles in suspension. It also gives the count rate (cps, counts per second).
Knowing this and the ...
1
vote
0answers
38 views
What is the molarity of a solution made by dissolving 25.63 grams of naphthalene (MM = 128.17g) in 250.0 grams of benzene? [closed]
I don't really understand how to find the amount of liters with benzene in order to find the molarity.
0
votes
1answer
2k views
Can I add the molarities of multiple solutes together?
If I am calculating the molarity of a solution in which more than one solute is dissolved, can I add the total number of moles of all the solutes together and divide it by the total volume of solvent ...
1
vote
1answer
48 views
Chemistry Calculation Dilutions of Acid
I was presented with the following problem in my lecture and I am confused as to what to do.
You are required to prepare $\pu{250 cm3}$ of $\pu{0.100 mol dm-3}$ HCl by diluting $\pu{0.600 mol dm-3}...
0
votes
1answer
5k views
How to find mole fraction of solvent and solute in a vapor pressure lowering problem?
At $25$ degrees celsius, the vapor pressure of pure benzene ($\ce{ C6H6}$) is $93.9$ torr. When a non-volatile solute is dissolved in benzene, the vapor pressure of benzene is lowered to $91.5$ torr. ...
0
votes
1answer
145 views
Why doesn't hydroxide concentration equal concentration of carbonic acid and bicarbonate in a sodium bicarbonate solution?
To find the pOH of solution of $\pu{0.42 M}$ of $\ce{NaHCO3}$, given a $\ce{Kb}$ of $\pu{2.4E-8}$, my solution manual does the following steps:
Reaction is similar to : $\ce{HCO3- + H2O <=> ...
1
vote
0answers
61 views
How to know the kinetic rate of one reaction from 3 tests with different concentrations?
Recently, I've run an experiment about the effect of reducing concentration on rate of a reaction.
Here's the chemical reaction:
$\ce{10 NaHSO3 + 4 KIO3 ⇌ 5 Na2SO4 + 2 I2 + 3 H2SO4 + 2 K2SO4 + 2 H2O}...
1
vote
0answers
111 views
How to calculate the gas-liquid interaction for dissolved HNO3 in water with air?
Thanks for reading this and (maybe) helping me in advance!
I have to face the following problem:
I have got $\ce{HNO3}$ dissolved in water (roughly $\pu{50\%}$) and I want to know how much $\ce{HNO3}...
1
vote
0answers
840 views
Can water be included in an ICE table if it is not the solvent and is a product?
The question that I have is whether you will count water in a Fischer esterification equilibrium problem where the equation is
carboxylic acid + ethanol --> ethyl acetate + Water
We need to find the ...
0
votes
1answer
488 views
How to calculate volume for NaOH and drano max gel (includes dilution and pH, pOH)
I have a question on an assignment that I don't quite understand. It says:
What volume of $\pu{0.0100 mol/L}$ $\ce{NaOH(aq)}$ would have the same number of moles of hydroxide ions as $\pu{100.00 ...
0
votes
1answer
2k views
How to find volume of substance from molar concentration
The concentration of a substance dissolved in water $i$ is known in (mol/m3), so is the molar mass in (g/mol) and the density in (g/m3).
I want to find the volume of this substance in m3.
I have ...
0
votes
1answer
240 views
'Rate' in the rate law
I am slightly confused about what the rate is that is given by the rate law. Is it the rate of reaction (I.e. the rate of loss of reactant or formation of product divided by its stoichiometric ...
4
votes
2answers
6k views
How to increase the concentration of HCl
Today I have purchased some $\ce{HCl(aq)}$ on my local market with a concentration of 23%.
However, I need to obtain a concentration of 37% in order to perform an experiment. Can I use distillation ...
1
vote
1answer
3k views
How do I calculate the equilibrium constant of a reaction from two related reactions' constants?
At a certain temperature the following reactions have the constants shown:
$$\begin{align}\ce{S(s) + O2(g) &<=> SO2(g)} && K'_\mathrm{c} = 4.2\times 10^{52}\\
\ce{2S(s) + 3 O2(g)...
0
votes
2answers
5k views
Lugol's iodine 5 % aqueous solution
There is Lugol's 5 % solution with 5 g of pure iodine and 7.5 g of potassium iodide.
In one ml there should be 12.5 mg of iodine in sum.
But there are suggestions telling that two drops of this ...
1
vote
1answer
17k views
How to create a 3 M solution of ammonia from 25% ammonia
We have ammonia $25\%$. We also know $\rho_{\text{ammonia}} = \pu{0.86 \frac{g}{cm^3}}$, $\pu{25 ^\circ C}$. We want to produce $\pu{3 M}$, $\pu{0.5dm^3}$ ammonia.
This means that there are some ...
2
votes
1answer
413 views
How do you calculate the heat of a reaction given a table of heat of formation values?
So I've been trying to answer this question, and as far as I've learned it's $\Delta H^0_{\mathrm f}$(products)-$\Delta H^0_{\mathrm f}$(reactants), multiplying each by number of moles and such.
...
1
vote
1answer
123 views
Finding the concentration of ferrous thiocyanate in calibration solutions
Concentration of $\ce{Fe(SCN)^{2+}}$ in calibration solutions
Recall that the concentration of $\ce{Fe(SCN)^{2+}}$ in the calibration solutions is essentially the concentration of the $\ce{SCN-}$ ...
0
votes
2answers
5k views
how to calculate mols Ag from AgNO3 solution
Sorry for the very basic question but its been a very long time since I've taken chemistry and I'm having difficulty solving this problem.
If I titrate something with 1 molar AgNO3, adding 50 ml of ...
1
vote
0answers
432 views
Will the reaction shift left or right?
The picture shows the correct answer.
At Eq., I have:
3 Mol of A
1 Mol of B
12 Mol of C
I was looking at each answer in terms of ratio of reactants to products, but its clearly not correct since I ...
1
vote
1answer
1k views
How to calculate concentration of unknown saturated stock solution from diluted solution whose concentration is known?
I want to measure the solubility of a compound. I prepared a saturated stock solution of my compound in 100ml of water by dissolving it in excess and filtering out the undissolved sample.
Then I ...
-1
votes
1answer
2k views
Calculate [Cr^3+] in equilibrium with Cr(OH4)- when 0.010 mol of Cr(NO3)3 is dissolved in a liter of solution buffered at pH 10.0
I tried setting up a RICE chart with the initial conditions being:
$$\begin{array}{c|c} \hline
\text{Species} & \text{Concentration / M} \\
\hline
\ce{Cr^3+} & 0.010 \\
\ce{OH-} & 10^{-4....
2
votes
0answers
91 views
Chile 2017, One of the Largest Fires in South America: Wood Ash Derivates for Industrial Applications [closed]
Hi: We're a group of people who wants to help people, domestic animals and wildlife recovering from this fire.
Summary:
We're having in Chile one of the largest fires in South American history.
More ...
0
votes
1answer
14k views
How to use C1V1=C2V2 How do the units work?
I am trying to do a dilution where I know I have 0.749 g/ mL and I want to use this concentration to calculate the grams of aspirin in each 100 mL solution. I am specifically worried about the units. ...
4
votes
1answer
657 views
Titration to determine the amount of hydrogen peroxide
I have a mixture of sodium carbonate, sodium bicarbonate, ammonium carbonate, copper (II) sulfate, hydrogen peroxide, and sulfuric acid. I'm titrating potassium permanganate against this mixture to ...
0
votes
1answer
941 views
Dilution question, “70 wt. % in H2O”? [closed]
If I have a solid and want to make an aqueous solution of 70%, how much water do I need? Is it as simple as weighing out 70 $\mathrm{g}$ of solid and adding water until I have 100 $\mathrm{mL}$? Will ...
0
votes
2answers
75 views
Volume in decimetres cubed dimensional analysis
In chemistry class, we were learning about concentration, which is the number of moles of a substance per decimeter cubed of water, expressed as $\mathrm{mol} \cdot \mathrm{dm}^{-3}$.
However, I was ...
0
votes
1answer
429 views
How does dissolving a hydrate affect concentration?
Say I have 0.72 grams of calcium chloride dihydrate. If I dissolve it in water, the 2 water molecules attached onto it dissociates just like the $\ce{Ca^{2+}}$ and $\ce{Cl-}$, right?
And if so, ...
5
votes
3answers
6k views
Why is Ka constant when volume is increased?
The following graph shows $\ce{Ka}$ vs ${V}$ (Volume) at constant temperature, as ethanoic acid is diluted:
However, I thought it would instead produce the following graph (see below).
$\ce{Ka=[...
1
vote
2answers
191 views
Increasing available area of a solid will increase effective concentration?
If I say that making a solid reactant into a powder will increase the yield of the product, because it increases the available area of the solid, hence increasing its effective concentration. Is this ...
2
votes
0answers
79 views
le chateliers principle
One of le chateliers principle is effect of concentration change :
When the concentration of any of the reactants or products in a reaction at equilibrium is changed , the composition of ...