Questions tagged [atomic-radius]

For questions about the atomic radius - a measure of the size of an atom, usually the mean or typical distance from the center of the nucleus to the boundary of the surrounding "cloud" of electrons.

Filter by
Sorted by
Tagged with
1
vote
1answer
50 views

How is most probable radius in quantum mechanical model equal to Bohr's radius in hydrogen atom

Most probable radius in 1s orbital for hydrogen electron is $\pu{0.529E-10 m}$ which is Bohr radius. But energy of electron in hydrogen atom is proportional to mean radial distance in atom. In this ...
-2
votes
0answers
29 views

If most probable radius is inversely proportional to orbital quantum number, how is energy proportional to n+l

The closer an electron to the nucleus, the lesser the energy. Then why does a 3d electron have higher energy and be closer to nucleus than a 3s electron?
-2
votes
0answers
27 views

According to quantum mechanical model does radial probability distribution show a maxima for lesser values of n ( shell number )

Here is a link where probability distribution graphs varying with radius for different azimuthal quantum numbers are compared to show that most probable radius is inversely proportional to l (...
-4
votes
1answer
21 views

what is the use of finding out the radius of an atom [closed]

I happen to come across this, but what is the radius of an atom, velocity, KE, PE, etc.. actually used for? like the formula r=0.529n^2/z and so on
3
votes
1answer
84 views

Why is strontium(II) ion bigger than krypton atom?

$\ce{Sr^2+}$ is exactly the same as $\ce{Kr}$, in terms of electrons and orbitals. The only difference between the two, is that $\ce{Sr^2+}$ has a couple of extra protons in the nucleus (and probably ...
0
votes
1answer
262 views

Shielding effect of d electrons

In transition elements shielding effect is observed . Due to this zinc shows abnormality in atomic size. But at the same time we also say that gallium has same similar size as aluminium due to poor ...
1
vote
0answers
25 views

Why is the increase in covalent radius from As to Bi not as big as from N to P?

The following is the radius of Group $15$ elements: $$\begin{array}{c|c} \hline \text{Element} & \text{Covalent Radius }(\pu{pm}) \\ \hline \ce{N} &75 \\ \ce{P} &110 \\ \ce{As} &...
0
votes
0answers
41 views

Why does dissolved oxygen concentration decrease with increasing atomic number of metals?

I am looking at how metal ions ($\ce{Fe^2+}$, $\ce{Ni^2+}$, $\ce{Cu^2+}$, $\ce{Zn^2+}$, and $\ce{Ag+}$) affect the biochemical oxygen demand in water and used the Winkler's method to find out the ...
-2
votes
1answer
56 views

Distance of subshells from nucleus [closed]

Which subshell is more closer to the nucleus.4f or 6s? 6s gets filled first so does it have to be more closer to the nucleus?
12
votes
1answer
160 views

Newer ionic radii data than Shannon's 1976 compilation?

Shannon, R. D., 1976, Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides: Acta Crystallographica Section A, v. 32, p. 751–767. DOI: 10.1107/...
0
votes
1answer
57 views

Forcing atoms closer together [closed]

Is there a method in chemistry to alter the energy of atomic bonds by forcing atoms closer together in a smaller volume? Similar to how pressure squeezes atoms closer together.
0
votes
0answers
13 views

Why the melting point increase up to arsenic and then decrease down the group 16? [duplicate]

I am already google this but can't find the answer that staisfy me. I know down the group, mass and atomic size increase which result in increase in van-der-waal forces. But in group 16 the trend is ...
4
votes
1answer
3k views

What is the difference between the Bohr model and the quantum model?

Specifically, Bohrs atom model gives the radius of an atom as 0.53‎Å, while a quantum description offers a similar value. What is the difference between these?
4
votes
1answer
6k views

Why is the difference between atomic radii of Na and K greater than that of Rb and Cs?

I am aware that this question has already been asked here: Why does the "gap" between atomic radii get smaller down the periodic table?. However, I was wondering if there is a way to ...
2
votes
1answer
6k views

Finding orbit radius using the Bohr model and Rydberg equation

To start with its a homework problem, quite lengthy. A particle of mass equal to 208 times the mass of an electron moves in a circular orbit around a nucleus of charge $+3e$. Assuming the Bohr ...
5
votes
1answer
461 views

Covalent atomic radii: oxygen vs nitrogen

Many books state that $R_\ce{N} > R_\ce{O}$ which is in accordance with the general trend. However, some books say that $R_\ce{O} > R_\ce{N}$ because of repulsion caused by pairing of electrons. ...
0
votes
0answers
29 views

Reason for needing multiple radii for the same atom [duplicate]

Why do we need different types of atomic radii? Why can't there be just one radii for an atom?
2
votes
0answers
82 views

How to calculate electric force on valence electron?

In order to understand the periodic trends more fully, I wanted to calculate the net force exerted on the electron (with the highest principal quantum number and azimuthal quantum number) of an atom. ...
2
votes
1answer
14k views

Regular decrease in the atomic radius of 3d series

While comparing atomic radius, two factors are important: A. Decrease in size due to increase in effective nuclear charge B. Increase in size due to increase in shielding effect I was surprised to ...
0
votes
2answers
264 views

How to compare size of subshells?

For the same principal quantum number, on increasing the value of the azimuthal quantum number does the average radius of the subshell increase or decrease? In other words, which out of, say, 3s, 3p, ...
4
votes
1answer
385 views

Why is platinum denser than gold?

The atomic masses of gold and platinum are 196.96657 u and 195.084 u respectively, meaning that (on average) an individual gold atom is heavier than an individual platinum atom. At the same time, the ...
0
votes
1answer
103 views

In the gold foil experiment why didn't thallium form? [closed]

When alpha particles hit the gold nucleus shouldn't they form thallium. More over shouldn't it also ionize the gold or any atom it hits how does it remain unchanged unionized?
1
vote
0answers
136 views

Why doesn't core charge increase down a group? [closed]

Atomic radius increases down a group because the electrons feel a lesser attraction to the positive nucleus (due to shielding from inner shells). Why then, doesn't core charge decrease seeing as core ...
-2
votes
1answer
27 views
1
vote
0answers
392 views

Why is the strontium ion smaller than the potassium ion? [closed]

The ionic radius of the $\ce{Sr^2+}$ ion is $\mathrm{132\,pm}$, while the ionic radius of the $\ce{K^+}$ ion is $\mathrm{152\,pm}$. Why is this the case? I would have thought that since $\ce{K^+}$ has ...
0
votes
1answer
69 views

True muonium energy levels [closed]

In a true muniom(muon-antimuon atom) do the energy levels match with that of the hydrogen's? The core is lighter for about 100 times but the muon is 100 times heavier than the electron so it would ...
2
votes
1answer
70 views

Shielding effects and atomic size [closed]

The atomic size on going from aluminum to gallium decreases because of poor shielding effect of the $(n-1)d$ electrons, but on going from copper to zinc, the size increases due to the same shielding ...
1
vote
1answer
5k views

Niobium has a density of 8.57 g/cm3 and crystallizes with the body-centered cubic unit cell. Calculate the radius of a niobium atom

Here is my question Niobium has a density of $8.57 \pu{g/cm^3}$ and crystallizes with the body-centered cubic unit cell. Calculate the radius of a niobium atom. Here is my solution
4
votes
2answers
1k views

Why is there a discrepancy among sources on the atomic radius of some elements?

My book says the atomic radius of gallium is less than that of aluminium, but I found out different atomic sizes on different sites. For example, this says gallium is 136 pm and aluminium is 118 pm, ...
4
votes
2answers
10k views

Does electron shielding increase or stay constant moving LEFT to RIGHT across a period?

Does electron shielding increase or stay constant moving left to right across a period? I have read about both, and I just want to know which one is right. I believe that electron shielding remains ...
6
votes
3answers
19k views

Why the atomic (metallic) radius of gallium is less than that of aluminium?

It is a well known fact that on moving down the group of p-block elements, the atomic radius is expected to increase. However, gallium is an exception. The atomic radius i.e., the metallic radius of ...
0
votes
1answer
3k views

Comparison between van der Waals radius and metallic radius

I was reading about different types of atomic radius. It was written that if any atom can possess all the three types of radius, then van der Waals radius will be greater than metallic radius. However ...
0
votes
1answer
99 views

Size of atomic shells

Is the distance of some $n^{th}$ shell ($n$ $\neq$ outermost shell) from the nucleus of an atom different for different elements? If so, then how much is the difference or how could we calculate it?
-1
votes
1answer
170 views

Bohr's postulate of quantisation of angular momentum

The Bohr's postulate of quantisation of angular momentum can be written in a formula as $mvr = nh/(2π)$ where $m$ is mass of electron $v$ is its velocity $r$ is the radius of that shell $h$ is ...
2
votes
1answer
7k views

Variation in atomic radii of elements in different blocks?

If we look at the values for the atomic radii (look at the table here), we can see that they rapidly decrease across the period initially. Looking at the second period, The graph is pretty steep ...
9
votes
2answers
6k views

Na+ or Ca2+ . Which ion has the larger radius?

Which ion has the larger radius? Some sites say $r(\ce{Na+}) > r(\ce{Ca^2+})$. Any explanation would be appreciated.
1
vote
1answer
5k views

Calculate the radius of an Ag atom

The question I have been given is: Silver atoms in a metallic lattice only fill up $88\,\%$ of the space ($12\,\%$ is empty). The density of silver is $10.5\ \mathrm{g\cdot cm^{-3}}$. Assuming that ...
-1
votes
1answer
1k views

Do K+ and F- ions have the same ionic radii? [closed]

Since fluorine and potassium form ions to gain the electronic configuration of neon and argon respectively, then shouldn’t $\ce{K+}$ have a greater radius, as argon is larger than neon? Also which ...
0
votes
1answer
485 views

H and H- atomic and ionic radius [closed]

A hydrogen anion has a bigger radius than neutral H . Why is this happening ? I mean both electrons exist at the same shell so this is not it. Both H- and H have 1 proton so this is not it as well . ...
1
vote
1answer
67 views

Do external electronic shells influence internal ones?

There is a well-known electron shielding effect: negatively-charged internal electronic shell screens external shells from positive nuclei, thus increasing their radii. Thus, 2S orbital radius of Li ...
1
vote
0answers
112 views

What will happen if electron as a wave undergo destructive interference while travelling in its Orbit?

Today I came across a justification of Bohr's angular momentum quantization using the De- Broglie's hypothesis. The justification said that since the electrons are having wave nature also then while ...
2
votes
0answers
77 views

Why are atomic radii calculations all over the map? [closed]

If you look up an element on Wikipedia, it will list covalent, ionic, Van Der Waals, high-and-low -spin, and finally 'empirical atomic radius'. Then, on the page for atomic radius, the chart of '...
1
vote
1answer
73 views

Do magnesium and tin have the same volume?

Having the same atomic radii of 145 pm, should one mole of tin and one mole of magnesium take up the same volume? Since tin is much heavier, that means tin is much denser than magnesium. Is this true, ...
1
vote
0answers
310 views

Relationship between electronegativity and atomic radius [closed]

Would someone please explain in detail the relationship between the two? I understand that atomic radius is related to ionisation energy but I can't see how atomic radius may be related to ...
4
votes
0answers
63 views

Gap in ionic radii

The above picture was shown in a presentation by my prof in inorganic chem as we were discussing ionic radii more in depth (all in pm). These are all isoelectronic radii. Notice the sudden leap in ...
2
votes
1answer
329 views

Lanthanoid Contraction

Why is the radius of Europium so unusually high and out of the general trend ? Moreover, at different sources I am getting different values of radii. In some (e.g., Wikipedia) the radii are following ...
0
votes
1answer
246 views

Radius with Bohr model [closed]

$$r_n = \left(\frac{h^2}{4\pi^2me^2}\right)\times\frac{n^2}{Z} $$ Would I be able to calculate the radius of sodium ion ($\ce{Na+}$) with the help of the above Bohr atomic model formula?
6
votes
1answer
1k views

Why does the beryllium 2+ ion have a larger radius than a helium atom?

$\ce{Be^2+}$ has an ionic radius of $\pu{45 pm}$, while $\ce{He}$ has a radius of only $\pu{31 pm}$. If they are isoelectronic (they both have two elections in the $\mathrm{1p}$ orbital), and $\ce{Be}$...
3
votes
0answers
235 views

Why are the Covalent Radii of Ruthenium and Osmium So Similar?

Osmium and Ruthenium have covalent radii 144 and 146 respectively (according to Wikipedia). How are these values so similar when Osmium has 32 more electrons, with another filled p, s, and f orbital ...
2
votes
1answer
484 views

How to get ionic radii for coordination number 12?

I am studying $\ce{ABX3}$ perovskites, and I would like to calculate Goldschmidt tolerance factors for them. The $\ce{A}$ sites in these materials have a coordination number $12$. The Shannon's ...