We’re rewarding the question askers & reputations are being recalculated! Read more.

Questions tagged [aqueous-solution]

For questions relating to compounds dissolved in water and resulting reactions.

Filter by
Sorted by
Tagged with
3
votes
3answers
1k views

What is the procedure to create stock solutions?

Until now to execute this recipe, each time i had to count those milligrams/Liter. An enough difficult procedure. I am posting here this question to help me understand the procedure of creating ...
4
votes
1answer
36k views

Net ionic equation with only aqueous ions

When you turn a balanced equation into a net ionic equation, you ignore all the ions that are spectator ions (aqueous on one side as well as the other). You only write the solid and the aqueous ions ...
1
vote
1answer
3k views

Removing HCl from water

I have water contaminated with dissolved chlorine: $\ce{H2O + Cl2 <=>HCl + HOCl}$ During electrolysis, this is an issue. These are my products: $\ce{NaCl + H2O ->T[electrolysis] NaOH + Cl2 ...
0
votes
1answer
2k views

Why is the water column empty in ICE table

In the ICE table pure solids and liquids have a value of one in the equilibrium expression but when we create an ICE table, why is the $\ce{H_{2}O}$ column empty? Should it not have a value of one?
0
votes
2answers
215 views

Can citric acid protonation produce benzene and water

Is this reaction possible: $\ce{C6H8O7 + 12 H3O -> C6H6 + 19 H2O}$? Considering that the $\ce{H+}$ can be induced by ionization of the citric acid solution the benzene can be produced in this way?
1
vote
0answers
67 views

Identifying probable compound using its colour & reactants

This is quote from OxyChem document on Hypochlorites: Steel tanks in caustic soda service become passivated with a gray-black film forming on the metal. Thereafter, caustic soda at less than ...
1
vote
1answer
668 views

Balancing ionic equations and determining number of ions

There were two questions that I've listed below that I've had troubles on. I got an answer in both, but both of them weren't correct. For the first question, they list the answer to be D and then ...
4
votes
1answer
70 views

Boiling solutions with two salts

If you dissolve two different ionic compounds (that don't make a precipitate) in water and then boil the solution so all the water evaporates, the salts will re-crystallize. Is it possible that you ...
3
votes
1answer
332 views

In a redox reaction, why does more than one oxidation state of an element form?

Consider the reaction 100ml 10M $\ce{NaOH_{(aq)}} +$ 100ml 10M $\ce{NaHSO3_{(aq)} +}$ 100mL 0.01M $\ce{KMnO4_{(aq)}}$ In the picture posted here, the left columns give information on the Molarity of ...
1
vote
1answer
1k views

Calculating Ka values from std. state thermodynamic data

My professor showed us a sample calculation of the Ka value for a strong acid. He used standard state thermodynamic data. I have an issue with this: 1) Wouldn't this give us an understated Ka value?...
4
votes
3answers
2k views

Why are solutions electrically neutral?

I keep reading that solutions are electrically neutral, but I've never read an explanation. I've read after the fact justifications, such as one problem which asked me to calculate the force of ...
3
votes
1answer
661 views

Accuracy of pH meters in MgSO4 solution

I bought a 2 pH meters several months back from Amazon for roughly $10 a piece. I couldn't tell you how they work, but here's the link on Amazon: http://www.amazon.com/gp/product/B0087LOWIA/ref=...
2
votes
2answers
1k views

Find the color of the solution

The acid-base indicator methyl red has a $K_{a}$ = $1 \times 10^{-5}$. Its acidic form is red while its alkaline form is yellow. If methyl red is added in a colorless solution with a $pH = 7$, the ...
1
vote
0answers
175 views

Deviation from ideal solutions - activities and concentrations

What are some examples of solutions deviating significantly from ideal behavior, and, by extension, showing pHs significantly different from those predicted by usage of concentrations instead of ...
4
votes
2answers
154 views

What is the minimum pressure for existence of a liquid solution?

The minimum pressure for the existence of liquid solution is $0.6\;\mathrm{atm}$ $0.8\;\mathrm{atm}$ $0.77\;\mathrm{atm}$ $0.9\;\mathrm{atm}$ Although this seems to be an informative question, I ...
0
votes
3answers
2k views

Why does an acid exist when dissolved in water?

Acid is a substance that releases $\ce{H+}$ ions when mixed with water But if it releases $\ce{H+}$ ions the acid will ultimately not exist. For e.g we take the acid $\ce{H2SO4}$. If we add water ...
1
vote
2answers
103 views

Reconciling the units of pH calculation

As part of a simulation I am developing I have an acid in aqueous solution represented as a concentration field of mass density (units g/L) at various points in ...
0
votes
3answers
8k views

Why is a buffer solution most effective when concentrations of salt and acid are the same?

Why does a buffer work most effectively when the concentration of salt and acid is 1:1?
3
votes
2answers
3k views

Heat when dissolving solutes in water

Why do certain solutes dissolved in water release heat and other solutes absorb heat?
2
votes
1answer
5k views

How do non-ionic compounds dissolve into water? Into molecules or atoms?

I can't seem to find the answer in google, which is surprising. I'm aware that ionic compounds dissolve into electrolytes. However, when non-ionic sacarose for example dissolves in water, does the ...
0
votes
1answer
405 views

Zinc Picolinate - Positive, negative or neutral charge?

I'm going to be using a finings agent with a positive charge to remove negative trub from a solution (beer). I would like to keep some chelated zinc in the solution - ideally zinc picolinate - so ...
1
vote
2answers
418 views

HF and water miscible?

According to Wikipedia, HF is miscible with water. But isn't hydrogen fluoride a gas at RT and a sensible pressure? What would happen if you just kept adding more HF gas to some water?
3
votes
1answer
154 views

metal salt solutions g/l means hydrate or anhydrous

I want to redo an experiment. They've used Nickel chloride: 40 g/L Nickel chloride can be bought in two forms: anhydrous ($\ce{NiCl2}$) and hydrate ($\ce{NiCl2....
4
votes
1answer
175 views

Could micrograms of polonium really change the viscosity of a whole teapot?

I was reading How radioactive poison became the assassin’s weapon of choice and it opens describing how The men eventually left, and Andrade cleared the table. As he poured the remaining tea away, ...
1
vote
1answer
4k views

Electrolysis of aqueous lead nitrate

When going through one of my chemistry textbooks, I saw that the electrolysis of aqueous lead nitrate led to oxygen being formed at the anode and lead being formed at the cathode. However, in school, ...
2
votes
2answers
308 views

Does removing solution affect a supersaturated solution

Given a mixture of: a saturated solution of a solute in a solvent together with excess of the solute compound as crystalline material. If one were to change the bulk composition of the mixture by ...
2
votes
1answer
212 views

How do ligands and coordination complexes work in this case with copper (II) chloride?

What happens when Ammonia is added to an (aq) solution of copper II chloride? $\ce{CuCl2 + NH3 ->\; ?}$ I know that ligands bond with metals to form ion but I'm not sure about how they work in a ...
1
vote
1answer
1k views

Evaporation of a mixture of salts

I was wondering what happens when you boil dry a solution of several salts for example a solution of KCl and NaNO3. Since the ions dissociate I was wondering if the ions would combine randomly upon ...
6
votes
2answers
11k views

Azeotropes and separation by distillation?

I have just recently learnt the theory of fractional and normal distillations and the basics of maximum and minimum boiling azeotropes. Most books say that the components of the mixture forming an ...
6
votes
1answer
2k views

Can I synthesize iron acetate like this?

The oxidation state of the iron doesn't matter too much; I am just trying to make an attractive red-brown ink. Here are some instructions I prescribed to a friend. Here's an approximately decent ...
1
vote
1answer
50 views

Two chemistry inquiries [closed]

Here is my second question, I know 1000 grams of water is 1 liter. But does the density affect the result? What if the substance is mercury? When you add seed crystal in to a supersaturated solution, ...
6
votes
1answer
2k views

How is an aqueous Ag+ the same as [Ag(H2O)2]+?

$\ce{Ag^{+}_{(aq)}}$ can be written as $\ce{[Ag(H2O)2]+}$ but how would you know that it bonds with 2 water molecules? I don't get when ligands randomly form 6, 4, 2 bonds.
4
votes
2answers
1k views

Problems with precipitation of transition metal solution

I am trying to make a solution of "trace elements"--primarily transition metals-- for use in biological media; bacteria require elements like Cobalt, Molybdenum, iron, etc. in trace amounts. I am not ...
4
votes
1answer
663 views

Does supersaturated caffeine polymerize?

I tried preparing a supersaturated solution of caffeine by mixing anhydrous caffeine powder with water in a thin Turkish tea glass and heating it up over a candle (desperate times...). This worked ...
2
votes
1answer
249 views

Solution containing Iodine

The question is:- Iodine dissolves in a variety of solvents forming solutions that are purple, brown or any intermediate shade. This property is due to:- Hydrolysis of iodine ...
2
votes
1answer
1k views

Calculating approximate pH of polyprotic acids

When I took up ionic equilibria and titrations after a long break, I found it hard to solve the questions regarding pH calculations of polyprotic acds. Consider these two questions as examples:- ...
1
vote
1answer
6k views

Are these the correct and complete net ionic equations?

So I have several descriptions of reactions and I have to give the net ionic equation. Are these just the equations or are they the proper net ionic ones? Solid calcium is added to warm water. $$\ce{...
0
votes
1answer
23k views

How to calculate molality, molarity and mole fraction given density (g/mole)?

Calculate the molality, molarity and mole fraction of a $\ce{CuSO4}$ in a 17% m/m aqueous solution (density of the solution is 1.367 g/mole) I did .17 * 1.367 to find grams of $\ce{CuSO4}$ and .83 * ...
3
votes
1answer
137 views

Isoelectric pH of colloids?

How did we derive the relation between the isoelectric pH and the dissociation constants for the amino and carboxyl groups on zwitterionic amino acids. $$pI=\frac {pK_{a1}+pK_{a2}}{2}$$ where $$\ce{...
3
votes
1answer
2k views

Notation “5% solution”

What does 5% aqueous solution of glucose mean? Note that it's just 5% and not 5%w/w. Do we assume it to be w/w? The question is If the osmotic pressure of 5% aqueous soultion of glucose is $\pi_1$...
5
votes
1answer
388 views

Thermodynamics behind Deliquescence?

The phenomenon of deliquescence wherein a water soluble substance absorbs water from atmosphere and dissolve in it forming a saturated solution, has thermodynamic roots. I have read the fact that the ...
0
votes
0answers
6k views

Why Add Salt to Vinegar to Clean Pennies? [duplicate]

One common cure for dirty pennies is to put them in vinegar and salt. The vinegar should react with the copper oxide on the penny in the following way: $\ce{2CH3COOH + CuO -> (CH3COO)2Cu + H2O}$ ...
2
votes
1answer
838 views

Crystallization of solutions and liquids

The process of crystallization of a liquid or any solute occurs when its concentration exceeds the maximum concentration which the solvent can carry or when the temperature drops below the freezing ...
4
votes
1answer
487 views

Why do aqueous solutions always have to be electrically neutral?

I was reviewing some analytical chemistry and stumbled upon a section that explained the imperfection of using a salt bridge. It said that the using dissimilar ions is a problem because in, for ...
4
votes
1answer
2k views

How is hydration free energy of a solute measured experimentally?

I am reading a paper (Shirts, M. R.; and Pitera, J. W. and Swope, W. C. and Pande, V. S. J. Chem. Phys. 2003, 119, 5740-5761). Near the beginning of the paper (page 5745), the authors state: ...
3
votes
1answer
82 views

What commonly availible salts are strong dessicants?

I'm looking into building an absorption chiller as a decidedly non-professional DIY project. For safety reasons and because temps. > 0°C are sufficient, I won't be using ammonia but some saline ...
3
votes
2answers
495 views

How might one reduce the concentration of bubbles in their ice, from ice cube trays?

So I have been freezing ice a lot recently, and I will come out and say it, as it turns out it is, albeit unlikely, it is sometimes possible for ice to "explode." I was not so aware of this before, ...
6
votes
1answer
15k views

Is there a way to calculate how fast water will cool?

Is there a way to calculate how fast water will cool if you know the water's starting temperature and temperature of the environment that you put it in, such as a freezer?
3
votes
1answer
5k views

Hypochlorous acid mechanism

When hypochlorous acid is dissolved in water, is it the chlorine atom or the oxygen that serves as the anti microbial agent?
3
votes
1answer
747 views

Why is my NaCl solution seemingly saturated, when I followed the recipe for an isotonic solution?

I prepared an isotonic solution of table salt in water following this recipe: 1 leveled coffee spoon of salt in 0,5L of water. 9g/L would be an isotonic solution, a leveled coffee spoon is commonly ...