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Questions tagged [aqueous-solution]

For questions relating to compounds dissolved in water and resulting reactions.

6
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2answers
649 views

Buffer solution calculation

Preface: Buffer solution (acid-base buffer). I am provided with a weak base, which I will designate B. $\mathrm{p}K_\mathrm{a}$ for B's conjugate acid--which I will designate BH--is 8.1, and its mole ...
0
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0answers
20 views

How to find the compounds in a solution/material [on hold]

I am trying to find the components (Nitrates, Magnesium, Sulphur, Calcium, Iron, etc) in my organic manure. If I mix manure in distilled water how do I measure the presence of all the elements in the ...
2
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2answers
54 views

Does adding solutes to water alter its triple point? [on hold]

Does adding solutes to water alter its triple point? If yes, how do we find the new temperature and pressure of this point?
2
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1answer
37 views

Mixing cobalt(III) hydroxide and thallium(III) hydroxide

A simple question on solutions is driving me crazy. At this point, I think the textbook's wrong. Here's the question: A saturated solution of cobalt(III) hydroxide $(K_\mathrm{sp} = \pu{1.6e-44})$ ...
7
votes
2answers
3k views

Can lead(II) oxidize tin metal in aqueous solution?

According to my textbook, element $\ce{X}$ can oxidize element $\ce{Y}$ if $\ce{X}$ was lower in the activity series. Lead is lower than Tin in the activity series table in the textbook, but the ...
1
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0answers
32 views

Over time what happens to soluble liquids with different densities

I have a case with two liquids: Water and another chemical which is miscible in water. The chemical has a density of 800 g/l so it's 20% less dense than water. Initially the chemical was mixed with ...
0
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0answers
18 views

Finding the ionic product through conductivity [on hold]

The conductivity of saturated barium sulphate solution at $\pu{25 °C}$ is $\pu{3.6e-4 S m^-1}.$ The water from which the solution was made had conductivity of $\pu{0.6e-4 S m^-1}.$ What is solubility ...
-1
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2answers
44 views

Is this balanced redox equation correct? [closed]

I'm trying to balance an equation using oxidation numbers $\ce{MnO4^- + H+ + Cl- -> Mn^2+ + Cl2 + H2O}$ my suggestion: $\ce{MnO4- + 8H+ + 5Cl- → Mn^2+ + 2.5Cl2 + 4H2O}$ the 2.5 $\ce{Cl2}$ is ...
1
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2answers
108 views

Do we consider the dissociation of water when dealing with ion concentrations of a solution?

One mole of hydrated copper(II) sulfate, $\ce{CuSO4 . 5 H2O},$ is dissolved in water. How many moles of ions does the solution contain? 1) 1 2) 2 3) 6 4) 7 The correct answer is 2. ...
0
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2answers
508 views

Which of the following is the most acidic salt?

A 0.1 M solution of which salt is most acidic? (a) Aluminum(III) nitrate $\ce{Al(NO3)3}$; (b) Magnesium(II) bromide $\ce{MgBr2}$; (c) Sodium bicarbonate $\ce{NaHCO3}$; (d) Sodium formate $\...
1
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1answer
35 views

Redox titration or iron(II)

The concentration of $\ce{Fe^2+(aq)}$ can be determined by a redox titration using A. $\ce{KBr}$ B. $\ce{SnCl2}$ C. $\ce{KMnO4}$ (basic) D. $\ce{KBrO3}$ (acidic) Can anyone please ...
6
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3answers
2k views

How much salt (or any other substance one can find in a kitchen) do I need to add to make water boil at 104 °C? [closed]

I've seen some formulas around in other questions and Google searches, but my chemistry is pretty much dead so I have no clue where to find the relevant values to calculate it myself. I just need to ...
4
votes
1answer
269 views

Can Aquatabs be used to clean swimming pool water?

Can Aquatabs be used to prepare/chlorinate water for swimming? They are used to clean water for drinking so is it safe to assume that if used in proper quantity they can also clean water for ...
0
votes
1answer
49 views

Molarity of pure water [closed]

The molarity of pure water is 55.5 M at which temprature is obtained this value? Further, you will come across that 1000 mL = 1000 g (for water only, but at which temprature?)
2
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2answers
64 views

Can I use the Henderson–Hasselbalch for calculating the pH of non-buffer systems?

Can I use the Henderson–Hasselbalch equation on reactions that are not buffers? When I read up on the derivation of the equation, I noticed that there is absolutely no assumption on the relative ...
5
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2answers
1k views

pH of a buffer made with boric acid and potassium dihydrogen borate

The Problem Calculate the pH of a buffer that is $\pu{0.200M}$ $\ce{H3BO3}$ and $\pu{0.122M}$ $\ce{KH2BO3}$. The $K_\mathrm{a}$ for $\ce{H3BO3}$ is $7.3\times10^{-10}$ What I Tried For each of ...
2
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0answers
49 views

Is it appropriate to approximate solute particles in a dilute solution as an ideal gas?

I was studying osmosis and I came across the formula for osmotic pressure. I decided to see the derivation for osmotic pressure in a dilute solution. The derivation involved an equation involving the ...
-2
votes
1answer
23 views

Can Diatomaceous Earth be added to another chemical to harden it?

I've researched plenty, but cannot find this answer. If Diatomaceous Earth is 85% Sodium Silicate, could it be added to plaster of paris, with water, to form a hard surface, with the benefit of the ...
0
votes
1answer
27 views

What is the final molar concentration (molarity) of the nitrate ions in the resulting solution?

A chemist mixes 16.3 mL of 1.23 M sodium nitrate with 6.28 mL 0.823 M solution of calcium nitrate. What is the final molar concentration (molarity) of the nitrate ions in the resulting solution? What ...
2
votes
1answer
70 views

How to find the concentration of barium ions in a mixture of barium sulfate and barium thiosulfate?

I have a hard time with selective precipitation problem. A mixture of $\ce{BaSO4}$ and $\ce{BaS2O3}$ is shaken with pure water until a saturated solution is formed. Both solids remain in excess. ...
0
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0answers
21 views

Henry's law p = kx vs m = kp

What exactly is the difference between the following equations? $$p = kx \qquad\text{and}\qquad m = kp$$ Is the $k$ in both same, because I have seen same $k$ in textbooks for both equations?
6
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2answers
502 views

How to find the mass of dissolved AgCl when placed in a solution of NaCl?

I think the following problem in my textbook is malformed: Solid $\ce{AgCl}$ is placed in $1\,\mathrm{L}$ of $0.55\,\mathrm{M}$ $\ce{NaCl}$. Find the mass of $\ce{AgCl}$ which dissolves. I know ...
0
votes
0answers
13 views

Comparing vapour pressure of 1 molar vs 1 molal solution of sodium chloride

Say, we have 1 molar solution of $\ce{NaCl}$ and 1 molal solution of $\ce{NaCl}$. Among these, which will have maximum vapour pressure? I know that vapour pressure will depend on the number of $\ce{...
33
votes
3answers
9k views

Which “exotic salt” can lower water's freezing point by 70 °C?

The Medium.com article Mars Phoenix Lander, 10 Years Later shows several remarkable images and discoveries on Mars by the Mars Phoenix Lander circa 2008. One image (shown below) shows what looks like ...
7
votes
4answers
48k views

Is HCl (l) + H2O (l) equal to HCl (aq)?

The Wikipedia article about aqueous solutions claims that: An aqueous solution is a solution in which the solvent is water So basically, is writing $\ce{HCl(aq)}$ equal to: $\ce{HCl(l) + H2O(l)}$?
2
votes
1answer
41 views

Neutralisation Reaction Confusion

What will happen when $\pu{1 mol}$ of $\ce{H2SO4}$ reacts with $\pu{1 mol}$ of $\ce{NaOH}$? Will $\pu{1 mol}$ each of $\ce{NaHSO4}$ and water be formed? Or will $\pu{0.5 mol}$ of $\ce{H2SO4}$ will ...
-1
votes
0answers
43 views

Calculate correct heat output of chemical reaction

A solution with 1 mole $\ce{NaOH}$ is mixed with a solution of 1 mole $\ce{HCl}$ and the total volume is 1 L. The initial temperature is 25 °C. My question is regarding calculating the correct heat ...
1
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2answers
43 views

Heating 2% solution to get 4% solution

I have a 2% solution of Zinc sulfate in water (in heptahydrate form) that I want to turn into 4% solution instead of having to buy 4% solution separately. Would heating it to 100 degrees Celsius and ...
1
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1answer
66 views

What are the enthalpy and entropy contributions to carboxylic acids dissociating in water?

Carboxylic acids such as acetic acid do not dissociate much in the gas phase. In aqueous solution, however, they act as acids (proton donors). $$\ce{CH3COOH(aq) <=> H+(aq) + CH3COO-(aq)}$$ ...
4
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0answers
42 views

Solubility of PbSO4

The solubility of $\ce{PbSO4(s)}$ increase with the addition of $\ce{H2SO4}.$ Why? I don't quite understand this. When dissolving $\ce{PbSO4(s)}$ we get the equilibrium equation: $$\ce{PbSO4(s) <=...
0
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0answers
54 views

Trichloroacetic acid aqueous solution

I have bought some anhydride of trichloroacetic acid (TCA) and would like to prepare an acidic solution. My problem is, that I don't know how much "powder" to mix with how much water to produce an x% ...
0
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2answers
57 views

How to reduce surface tension of oil?

I would like to create tiny colored drops slowly falling down in a transparent liquid. The diameter of the droplets must be around 2mm, and their speed must be approximately 0.5 mm / sec. For that, ...
0
votes
1answer
70 views

How to make oil more heavy?

I would like to increase the density of a given oil (or anything that repels water) so that it is slightly heavier than water; to be able to precisely control how slow the oil would fall in the water. ...
0
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0answers
21 views

How addition of a soluble salt affects equilibrium involving precipitation with a base sharing the same cation?

I have the following reaction at equilibrium: $$\ce{Ba(NO3)2(aq) + KOH(aq) <=> Ba(OH)2(s) + 2 KNO3(aq)}$$ Will there be a change in the equilibrium if the salt $\ce{KCl}$ is added? Will the ...
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0answers
46 views

Calculating pH of solution

What is the $\mathrm{pH}$ when you dissolve equal amounts of $\ce{NaHCO3}$ and $\ce{Na2CO3}$ in water? When both of the compounds are dissolved, we will have equal amounts of $\ce{HCO3-}$ and $\ce{...
0
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2answers
77 views

How do I turn room temperature water into boiling water for drinking using an chemical/additive?

I am trying to create instant boiling water using a chemical of sorts, so that it can be consumed by a human. For example; someone could make tea without a kettle or any available water heating ...
0
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1answer
28 views

Adjustment of calcium, magnesium and alkalinity in drinking water?

It's been a long time since I did any molar chemistry in school and despite doing a lot of reading on the subject this week, I am making a mess of some basic calculations. I hope that someone who ...
3
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2answers
61 views

How to measure quantities at standard state when this state is a hypothetical one?

Consider the reaction $$\ce{A(g) + H2O(l) <=> B(aq) + C(g)}$$ If all gases and solutions were ideal, the standard state would be pure water, the solute B at a concentration of 1 M, the gases A ...
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1answer
71 views

Why is maximum buffer capacity for some diprotic buffers not when pH = pKa?

According to Rajkovic et al. [1]: $$β = \frac{[\ce{H+}]}{K_\mathrm{w}} + 2.303\cdot\frac{[\ce{H+}]\cdot K_\mathrm{a}\cdot c}{[\ce{H+}] + K_\mathrm{a}}$$ where $K_\mathrm{a}$ is the ...
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0answers
19 views

Concentration in a solution

If I mix up 46.29 grams of Potassium Nitrate powder (KNO3) in 1000mL of water and then take 1 ml of that solution and put it into 1 gallon of water what will the ppm of "K" and "NO3" be separately. ...
0
votes
1answer
111 views

What happens if you put a piece of copper into a solution containing Al3+ ions?

This is a question in my studies, and I am a little bit confused! I would think it happens nothing because copper is below aluminium in the reactivity series, right?
0
votes
1answer
69 views

Can tin(IV) sulfide be synthesized from tin(II) chloride via oxidation with sulfite in acidic media? [closed]

Will the following reaction occur? $$\ce{2Na2SO3 + 6SnCl2 + 12HCl → 4NaCl + 5SnCl4 + SnS2 + 6H2O}$$ I'm going to synthesizing $\ce{SnS}$ and $\ce{SnS2}$ NP's, but our supply is runned out and ...
1
vote
1answer
116 views

pH of CH3COOH + HCl solution (shouldn't be a buffer)

$\pu{0.05 L}$ of a solution containing $\pu{0.3 M}$ acetic acid $(\ce{CH3COOH}$, $K_\mathrm{a} = \pu{1.8e-5})$ are added to $\pu{75 mL}$ of a solution containing $\pu{0.02 M}$ hydrochloric acid ($\ce{...
3
votes
1answer
61 views

Using cryptands to make a negatively-charged solution?

In our discussion group, my friend mentioned that metal cations can be separated from other cations in solution using cryptands. After addition of the cryptands to the solution of the cations, ...
1
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1answer
525 views

Molality of the solution prepared from a hydrated salt

A solution is made up by dissolving $\pu{13.8 g}$ $\ce{Na2CO3 · 10 H2O}$ in $\pu{103.5 g}$ of water. What is the molality of $\ce{Na2CO3}$ in this solution? I can't solve it. I tried converting to ...
0
votes
2answers
123 views

Weight of sodium acetate required to get to certain pH

How many grams of $\ce{CH3COONa}$ we need to dissolve in $\pu{2.50 L}$ of water to get a solution with $\mathrm{pH} = 9.00$? Given $K_\mathrm{a}(\ce{CH3COOH}) = 1.75\cdot 10^{-5}$ Like solving a ...
3
votes
1answer
632 views

USNCO question - Finding pH of salt solution from pKa of its parent acid

The question from 2017 USNCO is as below: What is the $\mathrm{pH}$ of a $\pu{0.25 M}$ solution of $\ce{NaCN}$? (The $\mathrm{p}K_\mathrm{a}$ of $\ce{HCN}$ is $9.21$.) (A) $4.91$ (B) $8.61$ ...
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votes
1answer
157 views

Molarity of silver(I) nitrate solution after the reaction with magnesium [closed]

$\pu{3 g}$ of $\ce{Mg}$ are placed in $\pu{500 mL}$ of $\pu{0.625 M}$ $\ce{AgNO3}$. When the reaction is complete, what is the molarity of the $\ce{AgNO3}$ solution? I'm thinking you need to use $...
2
votes
2answers
48 views

Molarity Numerical on Mixing Solutions

If 3 L of 1 M NaOH solution is prepared by mixing properties of stock solutions of $x$ L of 2.5 M NaOH and $y$ L of 0.4 M NaOH and no water is to be used, find $x : y$. My attempt: $$3 = 2.5x + 0.4y$...
0
votes
1answer
2k views

Why are the reactants in the solubility product constant multiplied by their coefficients and raised to the power of their coefficients?

It is probably easiest for me to explain the question in an example. Consider the following chemical reaction: $\ce{MgF2(s) -> Mg^{2+} (aq) + 2F- (aq)}$ Plugging this into the formula for the ...