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Questions tagged [adsorption]

The adhesion of atoms, ions, or molecules from a gas, liquid, or dissolved solid to a surface.

24 questions with no upvoted or accepted answers
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142 views

New finding in cobalt compound that absorbs oxygen - is it really a breakthrough?

Very recently Chemical Sciences published results of the discovery of a new cobalt compound that can absorb oxygen at presumably a higher capacity than what has been achievable before. The paper is ...
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883 views

Selective sorption of toxins by polymethylsiloxane polyhydrate

Polymethylsiloxane polyhydrate (PMSPH) is used as enterosorbent for a couple of decades (nowadays under the trademark "Enterosgel"), intended for binding in the gastrointestinal tract and excretion of ...
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43 views

Pd-catalysed hydrogenation of imines

Hydrogenation of imines to amines by $\ce{H2}$ on $\ce{Pd/C}$ has been used e.g. in the synthesis of Pumiliotoxin. By contrast, carbonyl groups are rarely reduced in this way, which I though was due ...
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394 views

Difference between neutral and basic activated alumina

Sigma Aldrich sells two different types of activated alumina for column chromatography: neutral and basic. Apparently basic alumina is more active and better at adsorbing anions. Why is this the ...
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194 views

Why does the order of adsorption of hydrated alkali metals on an ion exchange resin decrease down the group?

Why does the order of adsorption of hydrated alkali metals on an ion exchange resin decrease down the group? I recently did a question on this topic and they say adsorption order is $$\ce{ Li+ > ...
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71 views

How did Zyklon hold and release HCN?

$\ce{HCN}$ is notoriously unstable: It boils at room temperature, and it tends to polymerize when concentrated in unbuffered liquid form. Yet $\ce{HCN}$ was for decades widely used as a fumigant ...
2
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0answers
265 views

Why does physisorption change to chemisorption at high temperatures?

I read in my textbook: In certain cases, physisorption changes to chemisorption as temperature is increased. Could anyone explain why it is so? I know the basics of both physisorption and ...
2
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186 views

How to develop a Reactive Force Field (ReaxFF)? (Molecular simulation)

Currently, I am working on CO2 capture on Hydrotalcites as solid adsorbents. I want to run molecular simulations to analyse the behaviour of the material under different temperatures, pressures and ...
2
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44 views

Langmuir parameters for fixed bed continous column

I have prepared a model of fixed bed adsorption column in MATLAB. I have to insert Langmuir parameter value there, so how can I calculate them in case of continuous fixed bed column. I have calculated ...
2
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0answers
55 views

Equations Used in Isothermal Titration Calorimetry

I have been attempting to understand and derive the formulas used for ITC which can be found here starting on page 310. I am particularly interested in the single set of identical sites. To first ...
2
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0answers
265 views

Why we have mass of adsorbent in Freundlich equation?

In Freundlich equation why we have $m$ the mass of adsorbent. I mean it is surface chemistry and on the surface of adsorbent the adsorption takes place so why we have mass of adsorbent in that ...
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56 views

Chemical bond of adsorbed atoms

When oxygen is adsorbed on iron metallic surface, does it create $\ce{Fe-O}$ bonds like the one in iron oxide? Can it be considered as a monolayer of iron oxide on the surface? If not, how is the ...
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Is it possible to reduce the desorption temperature of an adsorption/desorption reaction by changing (decreasing) the pressure?

I am studying about zeolite/water adsorption beds and need to see if there is a way to tune the desorption temperature. Ideally, I need to reduce the desorption temperature. Is it possible to do this ...
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30 views

Application of BET to micropore

'application of the BET equation should be restricted to the range where the term n(1 – p/p0) continuously increases with p/p0'see 5.2.2 in the reference This is one of the criterias IUPAC proposes ...
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81 views

Can negative adsorption be considered equal to sorption?

In my book it was written sorption is basically when the substance gets uniformly distributed into the bulk of the solid but at the same time its concentration is higher at the surface then in the ...
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100 views

Removing harmful gases from automobile exhaust using electrostatic precipitation

If I attach an electrostatic precipitator to a car's exhaust - and also make the smoke pass through an area containing $\ce{NaOH}$ in order to absorb sulfur dioxide - does that mean that the smoke ...
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42 views

Perovskite characterization

Does anyone know of groups working on water sorbtion testing and/or the use of inverse gas chromatography for characterizing Perovskites (as a class of materials)? Especially with regard to ...
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127 views

Any references for adsorption of ions to metal surfaces?

I'm specifically interested in ions that would adsorb to gold surfaces, however I would be incredibly appreciative if someone could direct me to a textbook reference or something more expansive, that ...
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34 views

Preparation of Copper (II) Sulfate Pentahydrate Solution

how would you make a solution of Copper (II) Sulfate Pentahydrate to achieve 150, 200, 250 and 300 mgL−1 concentration of copper? I do not have the anhydrous version of the solute. Also, when I ...
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60 views

Diffused Layer ion in Electrix Double Layer

When KI is added to AgNO3 soln, so AgNO3 is in excess, collidal particle is AgI:Ag+ with diffused layer of I-, Why is the diffused layer not of NO3- when the anion in excess is NO3-? If we had KI in ...
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69 views

Type of adsorption in catalysis

why type of adsorption takes place during catalysis? It can't be physisorption because it involves formation of chemical bond. It shouldn't be chemisorption too because it is characterised by ...
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1answer
302 views

What are molecular species?

I am a highschooler learning about adsorption for the first time.My school textbook says-- "The accumulation of molecular species at the surface rather than in the bulk of a solid or liquid is ...
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1answer
218 views

Aren't “lack of specificity” and “nature of adsorbate” contradictory factors in physisorption?

It was mentioned in my course book under "Characteristics of physisorption" that: Lack of specificity: An adsorbent does not show any preference for a particular gas as the van der Waal's ...
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23 views

Order of reaction in adsorption process

(1) $\ce{PH3(g) <=>[W]PH3(adsorption)->[W]P(s) + 3/2 H2(g)}$ The decomposition of phosphine on tungsten surface at low pressure is a pseudo first order reaction. This is because the rate of ...