# Would the lone pair be in the equatorial plane or the axial plane for bromine pentafluoride? [duplicate]

I've been learning chemical bonding and I'm confused about the structure of $\ce{BrF5}$. It has a square bipyramidal geometry but a square pyramidal shape - I got that. I don't get why the lone pair gets placed at the top perpendicular to the equatorial plane instead of the equatorial plane, where it's more stable. And why does the angle change a lot from 90 degrees to 84 degrees? Similarly for $\ce{ICl4-}$- why do the lone pairs go to the axial plane?

• There are no axial and equatorial positions here. Mar 1, 2018 at 4:33
• Oh! It didn’t show that way, now raajsuriya fixed it i suppose. But wait is there a square biphramidal geometry known? Or is it equivalent to octahedral? Mar 1, 2018 at 6:33
• Square bipyramidal geometry means octahedral geometry. All the vertices of an octahedron are equivalent. Mar 1, 2018 at 7:57
• @MollyCooL Yes, a square bipyramidal geometry is called an octahedral geometry because of its eight sides! Mar 1, 2018 at 7:59
• Okay thank you! Just got a bit confused between the two. Mar 1, 2018 at 8:00

As @IvanNeretin said in the comments, "There are no axial and equatorial positions here". This is a symmetric 3-D structure. Think of this structure as two planes cutting each other perpendicularly and you can rotate it any way you want. This is well reprsented by this image. Again in the case for $\ce{ICl4-}$ there is no axial or equatorial plane. Here's a diagram that should be helpful: 