1
$\begingroup$

Sometimes I have to apply vacuum to all kind of different borosilicate glass equipment like:

  • round bottom flasks

  • liebig condensers

  • fractional distillation apparatus

  • spiral condensers

  • chromatography column

  • and so on...

While I know that a thick walled round bottom flask will pretty much stand any vacuum my vacuum pump can produce, I am not so sure for something as fragile as a spiral condenser.

Is there a kind of rule of thumb how much mBar thin walled glass equipment like spiral condensers or chromatography columns can stand without risk of implosion?

$\endgroup$
  • 5
    $\begingroup$ The risk of implosion is always here, even properly certified glassware may get a tiny crack and implode. Always assume that the risk exists. Be especially suspicious with flasks above 100 ml except for very thick-walled ones for vacuum filtering. That said, there is no much difference from 0.01 kPa and 10 kPa as the outside pressure is 99+ and 90+ kPa respectively (10% difference), so if a piece of glassware can be evacuated by water ejector to meaningful degree, it usually can withstand any vacuum within. $\endgroup$ – permeakra Jan 29 '18 at 21:14
  • 2
    $\begingroup$ That said, you should be suspicious of large flat and almost flat surfaces and sharp angles.Small tubes are fine. Glass condensers are usually meant to be used with vacuum. $\endgroup$ – permeakra Jan 29 '18 at 21:14
  • 1
    $\begingroup$ How can you use a chromatography column "in vacuum"? Are you meaning to clean/dry it? $\endgroup$ – Alchimista Jan 30 '18 at 10:18
3
$\begingroup$

The basic rule is that the stress on an evacuated glass vessel is pretty much the same at 0.01 mbar (oil pump), 1 mbar (membrane) or 25 mbar (water jet) absolute internal pressure. 0.99999, 0.999 or 0.975 bar $\Delta p$ to the outside make very little difference if the thing goes pop.

And basically everything made out of borosilicate and with no flat surface is safe. Condensors definitely, they're not delicate at all. It's basic procedure to make them oxygen-free by evacuating.

Be careful with chromatography columns and flasks in the > 1 liter range. They're principally safe to be evacuated, too, but then are also a bomb, armed and ready to drop. If it goes off, you better not stand next to it. The danger from evacuated vessels is more or less proportional to their volume.

$\endgroup$

Your Answer

By clicking “Post Your Answer”, you agree to our terms of service, privacy policy and cookie policy

Not the answer you're looking for? Browse other questions tagged or ask your own question.