Same as a branched alkanes and alkenes, there is less compactness (surface area exposed to the other compound); between the alkanes/alkenes, hence less van der Waals attraction between them; as compared to straight alkanes/alkenes. So, intermolecular forces of attraction is not too effective. This also applies here, having bulky groups (methyl, ethyl, propyl, …) attached to the nitrogen atom, make it more branched and less compactness (less surface area) , means less intermolecular forces, hence lower boiling point.
Guess that's the most obvious reason, because actually, the electron donating group such as methyl, ethyl and propyl, would have given more electrons to the nitrogen making it more negative, hence expecting to have a more electronegative nitrogen; which might result in stronger dipole-dipole bond, but this isn't the case. So, the only explanation that I could thought of is the one I explained above.