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The IUPAC definition of an intensive variable is:

Physical quantity whose magnitude is independent of the extent of the system.

Why is it defined for "a system", and not for a homogenous system, as for a heterogenous system the quantity (e.g. density, temperature) might be different for the different extents/parts of the system?

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    $\begingroup$ There's no truly "homogenous" system. $\endgroup$
    – Mithoron
    Commented Sep 21, 2017 at 16:08
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    $\begingroup$ I don't see why being heterogeneous would prevent a system from having an (average) density, temperature, etc. $\endgroup$
    – SCH
    Commented Sep 21, 2017 at 16:10
  • $\begingroup$ @S.Chevalier. But if there is a clear boundary between the substances/phases, even the average temperature, density will not remain same for different parts of the system. $\endgroup$
    – Ayushmaan
    Commented Sep 22, 2017 at 2:48

2 Answers 2

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The intensivity of a variable doesn't depend on the homogeneity of the system.

Consider system A, a metal rod of length 2 with a gradient of temperature :

Temperature across a system of length 2

This metal rod has an average temperature, which you could calculate.

Now consider system B, a metal rod of length 4 with the same gradient of temperature :

Temperature across a system of length 4

This metal rod also has an average temperature. Furthermore, it is the same temperature as system A. (if you are unsure about that try to pick a gradient (I arbitrarily chose T = exp(-x) and T = exp(-x/2) for the graphs) and do the calculations yourself)

System B is bigger (it would be twice as massive) but its temperature is the same. Ergo the temperature doesn't depend on the size of the system and is an intensive variable.

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For a homogeneous material, an intensive variable is independent of the amount of material. Even non-homogeneous materials approach homogeneity in each small local region. And in these regions, intensive variables have the same values as if you had if you had a large homogeneous region under the same local conditions.

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