Why the concentration of a solution expressed in gram equivalent weights of solute per litre of solution is termed as "normality" ?
Does it have anything to do with the word "normal" ?
Why the concentration of a solution expressed in gram equivalent weights of solute per litre of solution is termed as "normality" ?
Does it have anything to do with the word "normal" ?
The term "normality" stems from the older German term for equivalent concentration (die Äquivalentkonzentration), namely die Normalität, which was coined by Karl Friedrich Mohr. According to German Wikipedia which also refers to Straube's Der historische Weg der Chemie [1, p. 220], Mohr introduced the concept of normal solution and normality (as it's known in the modern world) in the first edition of his Lehrbuch der chemisch-analytischen Titrirmethode [2], e.g. the preface contained the following definitions among others:
Die Normaltemperatur der Flüssigkeiten ist 14° R. = 17,5° Cent.
[…]
Normalflüssigkeit bedeutet eine Lösung, welche 1 Atom Substanz, in Grammen ausgedrückt, in 1 Litre enthält.
Zehend-Normalflüssigkeit bedeutet eine Lösung, welche $1/10$ Atom Substanz, in Grammen ausgedrückt, auf 1 Litre enthält oder mit $1/10$ Atom eines darin enthaltenen Körpers (z. B. Sauerstoff) wirkt.
The book also lists numerous "normal" definitions not really in a sense of "adequacy", but rather in a a sense of "standard": Mohr basically invented standardized quantitative analysis and proposed numerous analytical tools and techniques. Among these definitions there are:
At the same time, normality was used to describe the normal ratio between stoichiometry of the elements (esp. C, O, N) and the number of found equivalents in complex compounds such as proteins or drugs [3].