# Why is carbonic acid a weaker acid than acetic acid?

Is it because the $\ce{OH}$ group next to $\ce{COOH}$ in carbonic acid donates electron density to the $\ce{COO-}$ by resonance, making it a stronger base, compared to a weaker electron donating inductive effect of $\ce{CH3}$ and thus its conjugate acid is weaker?

What does the resonance contribution look like in this case?

What makes resonance a stronger factor than induction?

Carbonic acid is not weaker than acetic. In fact, it is stronger, just as one might expect by looking at that extra electron-withdrawing substituent. The trouble is, carbonic acid is also pretty unstable. At any given moment, most of it exists as $\ce{CO2}$. This leads to much lower apparent acidity.

Think of it this way: you add some acetic acid to a carbonate salt. An equilibrium sets in, much closer to the starting compounds than to the products. In other words, you'll have just a very tiny amount of $\ce{H2CO3}$. But as soon as you have it, it starts decomposing, thus shifting the equilibrium more and more to the right.

3.6 ($\rm pK_{a1}$ for $\ce{H2CO3}$ only), 6.3 ($\rm pK_{a1}$ including $\ce{CO2(aq)}$)...
The conjugate base of acetic acid is more stronger than carbonic acid because carbonate has $$\ce{-OH}$$ which shows +R effect but acetate has $$\ce{-CH3}$$ which shows +I effect.