# What types of ultraviolet light will ignite hydrogen?

I saw a reaction between hydrogen and chlorine ignite in the presence of UV light. I was wondering if the same thing would happen with something like near-ultraviolet light (around 400 nm). What kinds of UV light (if any) would start a reaction of stoichiometric amounts of hydrogen and oxygen gas in something like a balloon?

• I guess that for a liquid mixture of hydrogen and oxygen read light would suffice (formation of singlet oxygen), whereas in the gaseous phase light with wavelengths < 240nm (formation of oxygen atoms) would be required. – aventurin May 6 '17 at 18:07
• "Read light" = "red light" maybe? – Oscar Lanzi May 7 '17 at 14:15

Hydrogen/chlorine needs only visible light to ignite. You can use a normal security light to do this because chlorine can be dissociated by visible light, $\lt 490$ nm which is of a bluish/greenish colour. The reaction is a radical chain reaction initiated by chlorine atoms.
If you want to do the same with hydrogen/oxygen, which is also a radical chain reaction, you will definitely need UV light as the dissociation energy of both is now far larger, oxygen $\lt 244$ nm, hydrogen $\lt 276$ nm. It probably won't work so well in a balloon as the rubber will absorb a lot of UV. (Also, UV light of this wavelength is dangerous to the eyes and skin).