# General Questions on "Elephant Toothpaste"

## Equations:

1)$\ce{~2H2O2(aq)->2H2O(l) + O2(g)}$

## Context:

I have a few questions on the reaction commonly referred to as "Elephant Toothpaste". You see, I am doing a basic demonstration of chemistry to little kids. I certainly don't think I am qualified to perform this, (Well, I can, but I want to know the details behind this, which is why I am asking for help.) but I have no choice. So Here we go!

## Procedure:

1. Pour ~$\pu{50 mL}$ of hydrogen peroxide1 into graduated cylinder.
2. A "Squirt" (Not my wording) of Dish Soap into the graduated cylinder.
3. ~$\pu{10 mL}$ of potassium iodide ($\ce{KI}$) Solution into Graduated Cylinder.

The result is...Foam, and lots of it.
130% concentration

## So, here is my question:

• What happens to the potassium iodide?
• @Riggycat: What is the concentration of potassium iodide in your experiment? Apr 20, 2017 at 23:37
• en.m.wikipedia.org/wiki/Elephant%27s_toothpaste. Potassium iodide just act as catalyst. Apr 21, 2017 at 4:24

## 1 Answer

The potassium iodide serves as a catalyst for the decomposition of the hydrogen peroxide by facilitating oxygen removal from the solution so the reaction is carried to completion. The rapid decomposition allows you generate a lot of gas quickly and the long cylindrical shape of the graduated cylinder directs the momentum of the gas in a vertical direction to achieve the gushing effect. Since potassium iodide is a catalyst in the reaction, it is not consumed in the process of making the foam, but exists as the ions that come from dissolving the salt in the hydrogen peroxide solution.

Reaction mechanism on wikipedia

P.S. This reaction is exothermic, so if you go really large scale, expect your vessels and the foam to be hot to the touch.