1
$\begingroup$

While going through a textbook, I came across the following line:

$\ce{R3C-}$ is pyramidal while $\ce{(CN)3C-}$ is planar due to lack of back bonding from the lone pair of carbon atom into the $\pi^*$ orbital of the $\ce{CN}$ group.

I am having trouble understanding how exactly back-bonding occurs in the first species and how it causes the structure to be pyramidal while the latter is planar.

$\endgroup$
2

0

Your Answer

By clicking “Post Your Answer”, you agree to our terms of service and acknowledge that you have read and understand our privacy policy and code of conduct.