# Can glass be made with anorthite?

The lunar highlands are made mostly of anorthosite (90% anorthite, the rest oxides of magnesium, iron, a little titanium, and traces of others), and pretty pure anorthite ($\ce{CaAl2Si2O8}$) is common. No minerals that are more than about half silica are known. The use of typical batch reactions to purify chemicals is (mostly) not practical on the Moon, as there is no water*, no halogens, and no carbon, nitrogen, or hydrogen.

Human habitats are going to need clear glass, the more the better. If the Moon was being settled, a way to make clear glass locally would be a priority. There are of course many things to be considered about the proper use of glass, but that is a separate issue. This question is about an advanced colony, not the first few habitats. You can assume the infrastructure for an involved process is available.

Could anorthite be processed into decent clear glass? How much impurity could it have? How can I look into the properties it might have and things to consider about the process?

Below is a table from the Lunar Sourcebook, Ch. 5 pg 129, showing percentages of pure anorthite in various minerals mixed in igneous rocks from the highlands:

*Actually there is a lot of frozen water and other volatiles at the poles, but getting it in quantity is a big challenge, and it isn't found anywhere else.

• Clear glass? No. // Most such techniques I've read discuss sintering the lunar soil into "bricks." The brick structures would have to be fairly thick for radiation shielding and thus they would be reasonably air tight as well. – MaxW Jan 30 '17 at 22:08
• Once you get a good lunar smelter set up anorthite seems like a possibility at least. The keys are what wavelength of light you need for it to pass, required physical characteristic (hardness, flexibility, etc.). Is it for habitat windows or solar cells, etc. In other words all I have to offer are more questions and complications. But honestly, given your statement about assuming there is an established civilization already there trying to do this, I wouldn't write it off. Sorry, those are really the only thoughts I can offer. – airhuff Jan 30 '17 at 23:28
• I guess i know too little about this to frame it in a sufficiently narrow fashion. I'm trying to establish the best way to portray the manufacture of glass for the beginnings of industry on the Moon. My chief interest is glass that can be used for windows and other glazing. Loong said in chat probably it would be better to work with olivine, though that requires finding and excavating pure ore, while anorthite is common on the surface. I'll try to look into it more and come back to the question. Reading suggestions are also welcome, in that case. – kim holder Jan 31 '17 at 3:41
• @kimholder, incredibly interesting work! I do think that since the anorthosite is 90% anorthite which can be made into clear, transparent forms, I might start with a focus on anorthite. Again, it depends on what technological resources have been made available to the colonists. Best of luck! – airhuff Jan 31 '17 at 22:43

In theory, yes it is possible. In practice, not really.

First of all, the anorthite on the moon is never pure anorthite ($\ce{CaAl2Si2O8}$) but rather an anorthite-albite ($\ce{NaAlSi3O8}$) solid solution. That is, the single crystal contains both components. The diagram you added there, where it says "mole %"? The other stuff is albite.

Now, back to glass making. Just about any crystallite solid silicate can be made into a glass. The process is simple: heat it up above the melting point, and then cool it down fast enough so it quenches to glass instead of crystallising. Let's look at these points in details.

Melting the stuff: Anorthite has a very high melting point: 1553 °C. Forsterite (the Mg-rich end member of the olivine group) has an even higher melting point: 1890 °C. To melt the stuff you're going to need a furnace that can go that high, and your energy bill is going to be extremely high. Here's a liquidus phase diagram of the $\ce{CaAl2Si2O8-Mg2SiO4-CaMgSiO6}$ system so you can get an idea of the temperatures required:

Luckily, your material is not pure anorthite. It also has albite! That's good because it takes the melting point down:

However, 1100 °C is still pretty high. The glasses that are commonly used in industry today have melting points of below 1000 °C. This is achieved by having high contents of sodium in the glass, which is perfect in taking the melting point of the material down. However, materials on the lunar surface are not that rich in sodium, and that's a problem.

Adding iron to forsterite (i.e. the fayalite component of the olivine group) will take the melting point of it down, but pure fayalite melts at around 1200 °C which is no good, and the iron will colour the glass green to dark brown (seen as black if thick enough), depending on how much oxygen is around. More about iron later.

Cooling the stuff down: Silicate glasses that we know and love contain abundant silica, commonly above 70%. This makes the glass very viscous because of Si-O polymerisation. A viscous glass can be easily left to cool in air (by the way - not readily available on the moon) and it will remain glass. Cooling a non-viscous glass that has below ~50% silica in air will cause crystals to form in it (anorthite in your case) and it will not be perfectly clear anymore. Therefore, you need to cool it very rapidly, by quenching in water. The problem now is that the glass is very brittle and will most likely crack during cooling or very soon after (this is from my own personal experience in trying to make glasses of these compositions).

So far we have two problems: melting it, and cooling it. There are other problems. You were worried about impurities and rightfully so. Iron is your biggest enemy. Even trace amounts of iron (< 1%) can make your glass dark green or brown. Not only that, if there is oxygen around you might even have magnetite crystals in your glass and it's going to be completely opaque. You need a way to get rid of the iron. Nickel is also a minor problem. As for other "impurities", such as Al, Na, K, Ca, Mg, that's not a problem. They don't give any colour to the glass. It's the transition elements that you should fear.

Yet another problem is that you are not going to get pure minerals. The lunar surface does not contain blocks of anorthite or forsterite or anything else. The regolith is a powder made by weathering down of the minerals, and it contains a horrible mixture of everything. If you want to separate the anorthite or transition-metal-free stuff, you will need to figure out a way to do it.

• This provides almost all the information I need. The melting issue is less problematic than it seems - if the furnace is open the vacuum lowers the melting point, usually by more than 200 K, while also reducing heat loss as there is less conduction and no convection. During the day strong constant sun is also quite plentiful. The cooling process I currently lean towards is an enclosure with a very thin, chilled nitrogen atmosphere. Complex infrastructure, but this is a long-term approach. The site has many large anorthosite boulders as it is a large young crater. – kim holder Mar 2 '17 at 17:01