Which it is the oxidation state of indium and phosphorus? [closed]

I would like to know what the oxidation state of indium and phosphorus in a structure type rock salt. It could be +1 and -1? Yes or not? and why?

Thanks

• You don't need oxidation states of +1 and -1 to make a rock salt structure. Magnesium oxide does it with +2 and -2. In any event indium phosphide actually does not have the rock salt structure (en.wikipedia.org/wiki/Indium_phosphide). – Oscar Lanzi Oct 3 '16 at 1:02
• Under pression there is a phase transition from zinc blende to rock salt for this system. – Fernando Cisneros Oct 3 '16 at 1:15

I've estimated net atomic charges in rocksalt type InP by simple HF calculation in CRYSTAL06 in random basis. Lattice parameter of 5.54 A is taken from:

K Kabita et al. First principle study on pressure-induced electronic structure and elastic properties of indium phosphide (InP). Indian J. Phys. (2015), DOI 10.1007/s12648-015-0701-0.

Results: http://pastebin.com/zdb8js8Z

Total atomic charges are 47.2861139, 16.7138861, so partial charges are:

In: +1.71
P: -1.71


Given that oxidation state is an hypothetical charge that an atom would have if all bonds to atoms of different elements were 100% ionic, the answer is probably better estimated as +2/-2, not 1.