1) Know your surroundings. Do you have running water? What can you dispose of onsite, either in a sink or trash? Will you have a cart? Where will the demo materials go when they are not being use? How well will the audience be able to see the demo? How loud can you be? Is ventilation an issue?
2) Mentally and physically rehearse and troubleshoot logistics. A demo might seem great at home or on paper, but when you do it, or mentally rehearse it while visualizing your audience and surroundings you may realize that there are logistical issues that you didn't think of. They can be as simple as not having a place to set something. REALLY rehearse onsite if possible. Trying to perform steps of a demo and at the same time to teach requires practice.
3) Proceed slowly and thoughfully. It will seem slower to you than to the audience. Slow down to do "little" things like put caps on bottles before proceeding with the next step of the demo, or move liquid containing vessels to where they can't be knocked over.
4) Have a fairly simple, straightforward learning objective for each demo. Have the kids repeat it and explain what it means. Don't try to overload a given demo with trivial points that may detract from the ability of your target audience to learn a key point. That doesn't mean that you can't make 2-3 points during a demo. For primary grades you might want 1-2 key points.
5) Have a method of illustrating things on a molecular level. You should either have a white board, projector OR models that you can move. Models can be as simple as large circles of construction paper or card stock with letters written on them. For example, you can have a circle covered in aluminum foil to represent aluminum or other metal atoms, and others to represent two atoms in a compound. Neon colors work well.
You are responsible for assessing the safety and feasibility of the demo. Generally, demos with flammables, corrosives, and the potential for pressure to build up may REQUIRE safety glasses, shields, ventilation, eyewashes. You also need to know if you will be producing a waste material that requires special disposal.
Examples:
I personally am comfortable making hydrogen gas from calcium metal and ice water in a thick walled jar, but you end up with a vat of strong base.
I am OK with filling a balloon with $\ce{H2}$ in certain settings, and igniting it, but it will be loud, and could trip a fire alarm, and might violate local ordinances, and there are subtle issues with the procedure that you only appreciate with experience. The whoosh bottle with alcohol is similar though you need to decide if you want to use materials that your audience may have easy access to.
You can combine Lead Nitrate with Sodium Iodide to make a bright yellow precipitate, but you now have lead based paint to dispose of.
Here are some possible demos.
Make a large density column in a cylindrical vase using corn syrup, water, oil and alcohol. You can add food coloring to the water, corn syrup and alcohol (red, green, blue). You can also have things for kids to come up and drop into it and talk about how far down they will stop.
Use hydrogen peroxide and yeast enzymes to make oxygen gas in an inverted, submerged bottle. Then place a taper inside and see how bright it gets. You can talk about how enzymes can break apart hydrogen peroxide, or how the candle burns faster with more oxygen, and that the air we breath is not mostly oxygen.
Solutions of $\ce{KSCN (clear) + FeCl3 (yellow)}$ will combine to make a blood red/brown product. Color change can be a sign of a chemical reaction. You can dip a strip of paper towel in to pull up some of the solution.
PVA will polymerize in the presence of sodium borate to make slime.
$\ce{CuCl2}$ can be dissolved to make a solution which will react with aluminum cans or foil. You can show that salts contain metals as the copper gets replaced by the aluminum. $\ce{CuCl2}$ is caustic and toxic but you will end up with aluminum chloride in the solution. (There are health concerns with aluminum chloride. You could use zinc.)
If you drop alka seltzer in vinegar with a pH indicator you can watch it neutralize acid. Again, a large vase may be cheapest, but will crack easily if you tip it over and also produce sharper shards than lab grade glassware.
You can show flame colors from salts with different metals. https://www.youtube.com/watch?v=jJvS4uc4TbU It looks like he may have dissolved salts in a mostly alcohol and lit the alcohol. This method would not require a gas burner.
You can also have kids to paper chromatography using coffee filters and magic markers. All they need is a filter, a few markers and a cup of water.
There are chemical hand warmer reactions where kids can mix chemicals in a plastic bag and feel it get warmer.
Something as simple as having 4 solutions is large flasks, 1 M HCl, vinegar, water and 1 M NaOH and placing a few drops of universal indicator in each one.