2
$\begingroup$

Do molecular orbital diagrams exist for ionically bonded compounds and molecules?

$\endgroup$
  • 1
    $\begingroup$ The boundary between ionic ans covalent may not be as succinct as you think... $\endgroup$ – DHMO Sep 8 '16 at 23:43
  • 2
    $\begingroup$ Why is this being close voted? It is not primarily opinion-based nor is it unclear. $\endgroup$ – orthocresol Sep 9 '16 at 4:25
  • $\begingroup$ @orthocresol user34388's answer was from lisgar.net/magwood/molecular%20orbitals.htm which gives an explanation of the differences between HF and LiF molecular orbital diagrams $\endgroup$ – DavePhD Sep 9 '16 at 15:33
1
$\begingroup$

Molecular Orbital theory is a simplified approach to describe chemical bonding based on symmetries and orbital overlap. In principle, it makes no assumptions on the type of bonding, i.e., covalent, ionic, Van der Waals. This distinction is more a construct to understand the strength of the bond.

In case of a covalent bond, the electrons that make up the bond are shared by both nuclei, whereas in an ionic bond the bonding originates mostly from the Coulomb interaction, that is, the electrons are mostly located on a single nucleus. In MO theory, this can be understood in terms of the interaction strength. When the atomic orbitals that make up the bond have similar energy (and same symmetry), there will be a strong interaction and the resulting MO will have character of both AOs. In other words, the electrons will be shared more or less equally by both atoms. When there is a large difference between the AOs, the resulting bonding MO will have mostly the character of the AO which is lowest in energy and as such the electrons in this MO stay mostly around this atom. This resembles an ionic bond.

$\endgroup$

Your Answer

By clicking “Post Your Answer”, you agree to our terms of service, privacy policy and cookie policy

Not the answer you're looking for? Browse other questions tagged or ask your own question.