I have been told it that when the pH of wine is lowered the alcohol concentration will decrease because of Le Chatelier's Principle. Which states; if a equilibrium is disturbed by changing the conditions, the position of equilibrium moves to counteract the change. How can I best expand on this?
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4$\begingroup$ Possible duplicate of How does a lower pH affect the alcohol concentration of wine? $\endgroup$ – Ivan Neretin May 23 '16 at 7:27
This is a slightly broad question, but ill try to assist some. Google has a large assortment of articles describing pH, Le Chatelier's Principle, and EtOH.
Im not sure if you mean altering the pH during the fermentation process or altering the pH of the final product? It also makes a difference on the types of yeast you use. Some yeasts can handle different conditions and produce a different amount of alcohol.
Here is a great response from last year on the Stack Exchange, regarding fermentation without the addition of commercial yeast, using the change in pH as a catalyst for fermentation.
With the production of wine that uses commercial yeast for fermentation (which is most commercial wines), altering the pH too far outside of it's "designated" range will cause it to produce less alcohol. Some connoisseur winemakers will alter the pH slightly sometimes, varying on the types of grapes, to alter the terpene profile present. Different variables, equals different systems of equilibrium.
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$\begingroup$ For my chemistry EEI I decreased the pH of my varied fruit wine just before fermentation. I have quite a lot of information about Le chatterer's principle but am still unsure of how it causes the alcohol concentration to decrease if pH is increased? $\endgroup$ – Erin Blanch May 23 '16 at 8:51