5
$\begingroup$

I'm conducting electrolysis of water with a 0.25M KOH solution in water (about 14 on my pH meter) using graphite electrodes, and I was wondering if the O2 would be safe to inhale, as in an oxygen bar?

$\endgroup$
4
$\begingroup$

No. Untreated and unpurified, the gas coming directly out of your reaction vessel would be unsafe to inhale. It is likely that water vapour containing traces of KOH would be present, and this poses a significant safety risk to the person breathing this vapour. You could test this yourself by measuring the pH of the headspace above your reaction vessel. Hold a piece of indicator paper here for a period, and it will slowly show a change.

$\endgroup$
  • 4
    $\begingroup$ Technically, it's rather tiny droplets than vapor that poses as issue. $\endgroup$ – Ivan Neretin May 2 '16 at 6:30
  • 2
    $\begingroup$ @IvanNeretin I can confirm. $\endgroup$ – ringo May 2 '16 at 8:45
  • $\begingroup$ @IvanNeretin Point taken - you are absolutely right. $\endgroup$ – long May 2 '16 at 11:54
  • $\begingroup$ So how can I make the oxygen safe to inhale? I guess drying the O2 would work, maybe passing it through a fine filter. Would a carbon fiber filter work? Are there other electrolytes I could use that wouldn't require filtering? $\endgroup$ – wordsforthewise May 2 '16 at 17:13
  • $\begingroup$ You have a couple of new questions that should be asked separately. Without knowing your experience handling chemicals, I wouldn't advise inhaling any gas generated from this setup, regardless of post-filtration. $\endgroup$ – long May 2 '16 at 22:25
2
$\begingroup$

The only thing in the gas phase at the anode will be pure oxygen, but when these small oxygen bubbles break the surface they create a fine mist of the electrolyte. This can be eliminated as an issue by running the resulting gas through a wad of cotton wool or a wash in water. There is, however, a different reason to be cautious.

Oxygen toxicity.

At high enough partial pressures, oxygen becomes toxic to humans (really all life, but to different degrees). This becomes a major problem for deep scuba dives, divers have to reduce their oxygen to inert gas ratio beyond a certain depth.

For short exposure times, O2 partial pressures well above one atmosphere (~101.3 kPa) can be tolerated by humans, but on longer exposure times even O2 partial pressures as low as 30 kPa (about 30% O2 at sea-level pressure) have been known to cause issues for some individuals.

Because of this, I strongly advise against breathing pure O2 from any source for an extended period of time.

$\endgroup$
  • $\begingroup$ +1 for the scrubber. No points for the scaremongering. There are lots of people who are on extra oxygen for long periods. An O2 bar does not imply inhalation of 100% O2 indefinitely. I would get a used O2 concentrator for as they are designed for the purpose. $\endgroup$ – KalleMP Feb 2 '18 at 8:53

Your Answer

By clicking “Post Your Answer”, you agree to our terms of service, privacy policy and cookie policy

Not the answer you're looking for? Browse other questions tagged or ask your own question.