3
$\begingroup$

Given the standard enthalpy of formation of $\ce{AgNO3(aq)} = \pu{-99 kJ/mol}$ and the standard enthalpy of formation of $\ce{Ag+(aq)} = \pu{+105 kJ/mol}$, what's the standard heat of formation of $\ce{NO3-(aq)}$?

How can I know this if the standard enthalpy of reaction is not known? This is self test 10.1 in Atkins, PC.

$\endgroup$
0

1 Answer 1

2
$\begingroup$

Silver nitrate, $\ce{AgNO3}$ is a strong electrolyte. Based on the information given, I expect you are meant to assume that it dissociates completely when dissolved in water:

$$\ce{AgNO3(aq) -> Ag+(aq) + NO3- (aq)}$$

Thus, we can make the assumption that $$\ce{AgNO3(aq)} \equiv \ce{Ag+(aq) + NO3- (aq)}$$

Then, we can state:

$$\Delta_\mathrm{f} H (\ce{AgNO3(aq)}) = \Delta_\mathrm{f} H (\ce{Ag+(aq)})+\Delta_\mathrm{f} H (\ce{NO3- (aq)})$$

$$\implies \pu{-99kJ/mol} = \pu{+105kJ/mol} +\Delta_\mathrm{f} H (\ce{NO3- (aq)})$$

Thus $$\Delta_\mathrm{f} H (\ce{NO3- (aq)})=\pu{-204kJ/mol}$$

$\endgroup$

Your Answer

By clicking “Post Your Answer”, you agree to our terms of service and acknowledge you have read our privacy policy.

Not the answer you're looking for? Browse other questions tagged or ask your own question.