This linear polyatomic ion containing three atoms of carbon has a negative four charge and is only found bonded with lithium and magnesium.

Could anyone identify this for me? It's from a quiz bowl clue that doesn't have the answer with it.



A quick Google search suggests that $\ce{Li4C3}$ is a real compound, but based on what I saw in the links, it probably is not ionic in the same way that lithium acetylide $\ce{Li2C2}$ is.

$\ce{Mg2C3}$ appears to be the formula for magnesium carbide, or at least a magnesium carbide.

A carbide is a binary compound of carbon and a less electronegative element, usually a metal or metalloid. Carbide is also a generic name for mono- and polyatomic anions containing only carbon. The following ions would all carbide ions: $\ce{C^{4-}, C2^2-, C2^{4-}, C2^{6-}, C3^{4-}, C3^{6-1}, C3^{8-}}$, etc.

The special name of three of these carbide ions are:

  • $\ce{C^{4-}}$ - Methide
  • $\ce{C2^{2-}}$ - Acetylide
  • $\ce{C3^{4-}}$ - Sesquicarbide

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