# Why do the boiling and melting points decrease as you go down group 1 and vice versa for group 7?

I used to think that because an alkali metal needs to lose one electron to complete its outer shell, when the atom increases in size (atomic radius), the electron would be easier to lose as the attraction between it and the nucleus would be lower, resulting in increased reactivity as you go down the group (the opposite being true for halogens as they need one more electron and so need to retain their electrons).

Now the trouble I am having is that why would the melting point also increase, what does the ability to lose an electron have to do with the intermolecular forces between several atoms?

## 1 Answer

The group 1 elements are the so-called alkali-metals. The bonding between the atoms is caused by the interaction of the nuclei with the delocalized electrons. With increasing number of electrons and protons, the atomic radii get bigger and hence this interaction becomes weaker as the average distance between nuclei and electrons increases as you go down in group 1.

The group 7 elements are the so-called halogens. They exist under normal circumstances in their molecular form ($\ce{F2}$, $\ce{CL2}$ and so on). In contrast to the group 1 elements, the dominant intramolecular force is here London dispersion (or van der Waals forces if you prefer). This attraction is caused by the correlated motion of electrons. With increasing amount of electrons, there can be more correlated motion and hence there is a stronger interaction between the molecules and an increasing melting / boiling point when you go down in group 7.

• Thanks, I think I get it. So for what you are saying is that for group 1 elements, the forces between the electrons and the atoms influence the intermolecular forces (forces between individual molecules), thus resulting in varying boiling/melting points (due to energy needed to overcome forces etc)? – Vedbot Jan 1 '16 at 16:09
• Elements can condense to form a solid or a liquid because there is an attractive force between them. For the group 1 elements, the dominant force is here the interaction between the nuclei and the electrons. When more and more heat is put into these systems, these intermolecular forces can no longer keep the elements together and the system undergoes a phase change. – Ivo Filot Jan 1 '16 at 19:01