Have an hypothetical equilibrium reaction:

$$\ce{2 A (s) + x B (g) <=> 3 C (g)}$$

With the constants

\begin{align} K_\mathrm{p} &= 0.0105 \\ K_\mathrm{c} &= 0.45 \end{align}

both at $\pu{250 ^\circ C}$. What is the value of $x$?

Since $\ce{A}$ is solid, I guess we can ignore it, right?

$$\ce{x B(g) <=> 3 C (g)}$$

Using $K_\mathrm{c}$:

$$0.0105 = \frac{\left[\ce{C}\right]^3}{\left[\ce{B}\right]^x}$$


$$\left[\ce{B}\right]^x = \frac{\left[\ce{C}\right]^3}{0.0105}$$

But to solve this, I need the concentration of $\ce{C}$. How can I find it out?


1 Answer 1


Using the relation of $K_\mathrm{p}$ to $K_\mathrm{c}$:

$$\frac{K_\mathrm{p}}{K_\mathrm{c}} = (RT)^{\Delta n}$$

where $\Delta n$ is the change in the number of moles of gas in the reaction (here, $\Delta n = 3 - x$). Plugging in (using $R = \pu{0.0821 L atm mol-1 K-1}$ and $T = \pu{523.15 K}$) we get:

$$\frac{0.0105}{0.45} = 0.0233 = 42.950615^{(3-x)}$$

To solve we take the natural logarithm of both sides:

$$\ln{(0.0233)} = (3-x) \ln{(42.950615)}$$ $$\frac{\ln{(0.0233)}}{\ln{(42.950615)}} = -1 = (3 - x) \implies x = 4$$

And so $x = 4$. We can check to see if our answer is correct by plugging the calculated value for $x$ into the second expression from the top of this post:

$$0.0233 \buildrel{?}\over{=} 42.950615^{-1}$$

which does turn out to be correct.


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