6
$\begingroup$

In the picture below a proportionality equation is shown:

$$\omega \propto \nu \exp\left(\frac{-\Delta G_m}{RT}\right)\propto \dots$$

While $\Delta G_m$ is the Gibbs free energy, $R$ is the gas constant, and $T$ is the temperature, what are the parameters $\omega$ and $\nu$ exactly?

enter image description here

You can see the context on the picture: Yttria-stabilized-zircona.

$\endgroup$
1
  • 1
    $\begingroup$ Looks like $\omega$ is ionic conductivity and $\nu$ is a frequency factor, but I'm reluctant to provide this as an answer without more information - can you provide more information from the text/publication photo, above? $\endgroup$ Jul 31, 2015 at 14:01

1 Answer 1

3
$\begingroup$

$\Delta G_m$ is the free energy barrier for the motion of atom from one site to another. The equation overall looks like a transition state approach to this activated process, and thus $\nu$ is the frequency at which this motion is attempted, i.e. a $\nu$ is a characteristic lattice frequency. In such models, it is often assumed to equal the Debye frequency.

Finally, $\omega$ is the rate of transition from one site to another, or something proportional to it (because the proportionality symbol is used rather than an equality). $\omega$ can be thus be the ionic conductivity, or a diffusion constant.

You can find the same expression and graph in this chapter of undergrad lecture notes, for confirmation.

$\endgroup$

Your Answer

By clicking “Post Your Answer”, you agree to our terms of service and acknowledge that you have read and understand our privacy policy and code of conduct.

Not the answer you're looking for? Browse other questions tagged or ask your own question.