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If we have a metal in gas phase. Suppose lets say aluminium. aluminium has delocalised electrons. There is Al cation -electron attraction in it. Its easier to visualize Al atomic structure in solid form. But if its in gas phase will delocalised electrons return to the atom itself or there is going to be electrons and cations mixture (electrons floating around?). So can aluminium (or any other metal) vapours conduct electricity and what would be its conductance compared to its solid form?

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  • $\begingroup$ You need to be more specific: do you mean an isolated, electrically neutral Al atom? An Al ion of some kind? A cluster of Al atoms? A cluster of variously ionized Al atoms? A dispersed gas of Al atoms? A dispersed gas of Al ions? Etc. The answer depends somewhat on which specific system you're asking about. $\endgroup$ – hBy2Py Mar 29 '15 at 22:00
  • $\begingroup$ no,i am talking about cluster of atoms. $\endgroup$ – Irtiza Mar 29 '15 at 22:05
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Metal vapors do conduct electricity, as in the mercury vapor lamp (also used in fluorescent lamps), but, since the atoms are isolated or in small (molecular) clusters, conduction is ionic, not metallic. Since electrons are far less massive (and therefore more mobile) than the heavy ions, they are responsible for the majority of the conducted current.

Electrons are forcibly ripped away from the mercury atom (well, raised to higher levels) -- the first ionization potential is 10.39V, and its second is 18.65V, so in a mercury vapor lamp or mercury vapor rectifier, the potential drop of at least 20 volts implies more than one of the outer electrons are lost from many of the atoms.

Note that ionized gases are much less conductive than solid or liquid metals. Consider a 70 watt sodium vapor lamp, with an arc length of perhaps 10 cm and a potential drop of ~18 volts. The finest commercially available wire, 40 gauge, would have a potential drop of just ~1.3 volts for metallic copper wire, or ~4 volts for sodium, which has 1/3 the conductivity of metallic copper (if they made fine sodium wire), at the same length and current (~3 A). See the useful chart explaining sodium-vapor ionization .

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