What are the resonance structures for chlorite anion?

What are the possible resonance structures for $\ce{ClO_2^-}$? Assigning one double bond to the structure makes for formal charges of $\ce{O(-1)-Cl(0)=O(0) <-> O(-1)=Cl(0)-O(-1)}$. It appears that the same set of formal charges can be achieved with two double bonds (expanding the octet on $\ce{Cl}$ to 12 electron capacity, using the d orbital). That is, $\ce{O(0)=Cl(-1)=O(0)}$.

Is this feasible, and if not, why not?

Disclaimer
The here used methods are also only approximations and I do not claim that the provided numbers are accurate. However, they are used here to make the point, that bonding situations involving resonance are not easily explained.

Oxygen is slightly more electronegative than chlorine, therefore the bonds will always be slightly polarised towards the oxygen.

The following resonance scheme is based on an NBO analysis on the DF-BP86/def2-SVP level of theory. The percentage value gives an estimate how close the given conformation is to an idealised Lewis structure. From this you could also derive how much such a structure would contribute to a resonance situation (in terms of Valence Bond theory).
What we do see here is, that the electronic structure is better described with more formal charges. The contribution of a π bond is best described by an ionic donor-acceptor structure, rather than breaking the octet rule at chlorine.
Noteworthy is also that the doubly ionic donor-acceptor configuration is as equally good a lewis structure than any that breaks the octet rule.
The worst representation is the one with a four electron three centre bond (which is also not part of the Lewis bonding picture anyway).

Videos like the one mentioned in the Wikipedia article are easy to follow, but often they are too simplified to be correct.

• This is quite a curious answer, I had no idea calculations such as these were possible. It took me a minute to understand the bottom three structures though, because the arrows look almost like dative covalent bonds rather than electrostatic attraction between the ions. – Nicolau Saker Neto Apr 2 '15 at 12:08
• @Nicolau In principle they are dative covalent bonds. These are just representations of the same electron density. So in general all the presented structures are different viewpoints of the same situation. NBO localises and then partitions the electron density - in principle you could go about and construct valence bond configuration from that and actually calculate the mixing, but that is tedious and takes a lot of time and I cannot do it. – Martin - マーチン Apr 3 '15 at 3:16
• Then I'm not quite sure how chlorine has a positive formal charge even though it's being given electron pairs from the oxygen atoms. The bottom-right representation looks particularly strange to me. The charges seem to be calculated as if there were no covalent bond present at all, dative or otherwise. – Nicolau Saker Neto Apr 3 '15 at 3:34
• @Nicolau In the original Lewis picture there is no differentiating between bonds and in this sense only the very first structure is a true Lewis structure. The next two structures break the octet rule. The last in the first row has delocalised bonds. The dative bond does not exist in the Lewis picture, but extending this formalism, it only counts as electrons from where it originates. In the Lewis picture it does not matter if there is a bond in that case or not. – Martin - マーチン Apr 3 '15 at 8:25
• Ahh, now I see. I thought that might be it, but counting electrons from where they originate is rather unusual, at least to me. Thanks for taking the time to explain. – Nicolau Saker Neto Apr 3 '15 at 11:51

That would be like calling it Chlorine dioxide

While in chlorite ion, the ones you specified will only appear as stated here

A chlorite (compound) is a compound that contains this group, with chlorine in oxidation state +3.

• While this link may answer the question, it is better to include the essential parts of the answer here and provide the link for reference. Link-only answers can become invalid if the linked page changes. – Klaus-Dieter Warzecha Mar 27 '15 at 15:10
• @KlausWarzecha Okay. I am deleting my answers. – ChemExchange Mar 27 '15 at 15:35
• @KlausWarzecha Done! – ChemExchange Mar 27 '15 at 17:28
• Why minus ones even after editing it? – ChemExchange Mar 29 '15 at 17:40
• This does not answer the question. You have not posted a single lewis structure for the compound, not speaking of multiple structures that would explain resonance. – Martin - マーチン Mar 31 '15 at 5:09