I've seen a "2.303" term multiplied to $R$ in Van't Hoff equation several times.

Here is one example:


$$\Delta H^\circ=2.303R\frac{\log K_1-\log K_2}{\frac1{T_2}-\frac1{T_1}}$$

What is this number and where does it come from?


It is the multiplier used when converting the equation to use a base 10 log instead of a natural log.

It comes out to be the natural log of 10.


To elaborate on Burak's answer, which states that 2.303 is the multiplier, the correct converison is:

$$\ln(x) = 2.303\cdot\log_{10}(x)$$

Or as a divisor to convert the natural logarithm to a base 10 log: $$\log_{10}(x) = \frac{\ln(x)}{2.303}$$

  • $\begingroup$ Welcome to Chemistry.SE! Take the tour to get familiar with this site. Mathematical expressions and equations can be formatted using $\LaTeX$ syntax. For more information in general have a look at the help center. I have reformatted and reworded your answer in order to reflect the current situation. Please have a look and edit as needed. $\endgroup$ – Martin - マーチン Sep 6 '16 at 10:41

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