# Iodine color change in different complexes

Why does the color of iodine differ when it forms a charge transfer complex with benzene (pi donor) - pink and ethanol (electron pair donor) - brown? Does the HOMO-LUMO energy differ, if so how?

The formation of charge transfer complexes between iodine and aromatic hydrocarbons according to

$\ce{Ar + I2 <=> Ar\cdot I2}$ is a long known phenomenon and has been described by Benesi and Hildebrand in A Spectrophotometric Investigation of the Interaction of Iodine with Aromatic Hydrocarbons. The following data for the absorption maxima of iodine in the VIS and UV range (wavelength in nm) in different solvents are taken from that article.

\begin{array}{lrrr} \mathbf{solvent} & \lambda_{max}(\textrm{VIS}) & \lambda_{max}(\textrm{UV})\\ \hline \textrm{benzene} & 500 & 297\\ \textrm{toluene} & 497 & 306\\ \textrm{p-xylene} & 495 & 315\\ \textrm{mesitylene} & 490 & 333\\ \hline \textrm{trifluormethylbenzene} & 512\\ \textrm{n-heptane} & 520 & \\ \end{array}

Note that the effect is stronger in the UV than in the VIS range and the shift correlates with the (combined) $+I$ effects of the methyl groups, while a $\ce{CF3}$ substituent disfavours then formation of a charge transfer complex.

Ethanol, on the other hand, is a protic and polar solvent, nice to stabilize charged species.

One might argue that under these conditions, other species than in the case of aromatic solvents exist - the solvation of triiodide $\ce{I3-}$ is certainly possible here.

In addition to the coordination of iodine by ethanol - we cannot exclude interaction with several molecules of ethanol:

$\ce{n\ EtOH +I2 <=> I2\cdot(EtOH)_{n}}$

it is conceivable that disproportionation of iodine and solvation of the resulting charged species might play a role here:

$$\ce{ I2\cdot(EtOH)_{n} + I2 <=>[\ce{EtOH}] I+\cdot(EtOH)_{n} + I3-}$$

• So, the triodide causes the brown color in ethanol. Would the situation be the same with a different electorn pair donor? – RBW Mar 21 '15 at 13:49

There are very many charge transfer complexes and not just involving iodine. They have been know for at least 100 years. In normal (photon) absorption to form an excited state and so give a solution a colour, an electron is promoted from a bonding to non-bonding orbital in the chromophore molecule.

In charge transfer complexes two species are involved, D & A and are close to one another, effectively touching, say benzene and tetracyanoethylene. The lowest excited state now is one in which an electron is transferred from one of the pair to the other during the absorption process. Thus the lowest state above the ground state is the pair D$^+$A$^-$. The charge transfer absorption is the colour produced in this transition.