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The geometry of aluminium carbide is attached. Why isn't it completely linear (in accordance to VSEPR), but bent on the Al atoms?

enter image description here

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  • $\begingroup$ @Marko Where did you get such a structure? Aluminium carbide isn't molecular and in its structure there are no multiple bonds. $\endgroup$ – Mithoron Feb 1 '15 at 11:56
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    $\begingroup$ That structure (originally from ChemSpider) is incorrect. $\endgroup$ – Fred Senese Feb 1 '15 at 12:44
  • $\begingroup$ It was from ChemSpider, I am not so imaginative. $\endgroup$ – RBW Feb 1 '15 at 16:13
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That structure is incorrect. Several online chemical distributors have similar structures posted in their entries for aluminum carbide; so does PubChem! Some sources show the structure as linear; some show it as bent.

That structure basically assumes that aluminum forms primarily covalent bonds with an "incomplete octet" in VSEPR structures, rather like boron. But aluminum atoms are a lot larger and more metallic than boron atoms, and its compounds will have comparatively more ionic character. $\rm Al_4C_3$ isn't a molecular compound.

Cotton & Wilkinson's Advanced Inorganic Chemistry says that aluminum carbide "reacts instantly with water to produce methane, and X-ray studies have shown it to contain discrete carbon atoms (C-C = 3.16 Å); for these reasons it is sometimes considered to be a "methanide", that is, a salt containing $\rm C^{4-}$, but this is probably an oversimplification."

This is the structure that's posted on Wikipedia:

enter image description here

It says that "Aluminium carbide has an unusual crystal structure that consists of two types of layers. It is based on AlC$_4$ tetrahedra of two types and thus two types of carbon atoms. One is surrounded by a deformed octahedron of 6 Al atoms at a distance of 217 pm. The other is surrounded by 4 Al atoms at 190–194 pm and a fifth Al atom at 221 pm." This is attributed to Greenwood's Chemistry of the Elements, but I don't see it in the edition I have.

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