In A Very Short Introduction: Earth System Science by Tim Lenton, the author discusses the composition of atmosphere:
the first observations from land-based telescopes showed that Mars had an atmosphere dominated by carbon dioxide, just as would be expected in the absence of life. So too does Venus. But the Earth has a remarkable atmosphere, containing a chemical cocktail of highly reactive gases, sustained by life.
Oxygen is the prime anomaly—at just over a fifth of Earth’s atmosphere it is essential for our existence as mobile, thinking animals, but without photosynthesis to create it, oxygen would be a very rare trace gas. Mixed in with oxygen are gases like methane that react eagerly with it—so much so that they are on the verge of combusting together.
Why is oxygen an anomaly in this context?